Research output: Contribution to journal › Article › peer-review
Copper(II), cobalt(II), manganese(II) and nickel(II) bis(hexafluoroacetylacetonate) complexes with N-vinylimidazole. / Smirnov, Vladimir I.; Sinegovskaya, Lidiya M.; Parshina, Lidiya N. et al.
In: Mendeleev Communications, Vol. 30, No. 2, 01.03.2020, p. 246-248.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Copper(II), cobalt(II), manganese(II) and nickel(II) bis(hexafluoroacetylacetonate) complexes with N-vinylimidazole
AU - Smirnov, Vladimir I.
AU - Sinegovskaya, Lidiya M.
AU - Parshina, Lidiya N.
AU - Artem'ev, Alexander V.
AU - Sterkhova, Irina V.
PY - 2020/3/1
Y1 - 2020/3/1
N2 - Two new manganese(II) and nickel(II) bis(hexafluoroacetylacetonate) complexes with N-vinylimidazole were synthesized and characterized by single crystal X-ray diffraction analysis, UV-VIS and IR spectroscopy. Their structures were compared with those of related copper(II) and cobalt(II) complexes. In the case of copper complex, the coordination site formed by hexafluoroacetylacetonate at the Cu2+ ion and nitrogen atoms of the two vinylimidazole cycles is slightly distorted, while in all the other considered complexes, this distortion is insignificant.
AB - Two new manganese(II) and nickel(II) bis(hexafluoroacetylacetonate) complexes with N-vinylimidazole were synthesized and characterized by single crystal X-ray diffraction analysis, UV-VIS and IR spectroscopy. Their structures were compared with those of related copper(II) and cobalt(II) complexes. In the case of copper complex, the coordination site formed by hexafluoroacetylacetonate at the Cu2+ ion and nitrogen atoms of the two vinylimidazole cycles is slightly distorted, while in all the other considered complexes, this distortion is insignificant.
KW - crystal structure
KW - hexafluoroacetylacetonates
KW - metal complexes
KW - UV-VIS spectra
KW - X-ray
UR - http://www.scopus.com/inward/record.url?scp=85085025425&partnerID=8YFLogxK
U2 - 10.1016/j.mencom.2020.03.040
DO - 10.1016/j.mencom.2020.03.040
M3 - Article
AN - SCOPUS:85085025425
VL - 30
SP - 246
EP - 248
JO - Mendeleev Communications
JF - Mendeleev Communications
SN - 0959-9436
IS - 2
ER -
ID: 24396317