Research output: Contribution to journal › Article › peer-review
Coordination polymers with adjustable dimensionality based on CuII and bis-imidazolyl bridging ligand. / Barsukova, M. O.; Samsonenko, D. G.; Goncharova, T. V. et al.
In: Russian Chemical Bulletin, Vol. 65, No. 12, 01.12.2016, p. 2914-2919.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Coordination polymers with adjustable dimensionality based on CuII and bis-imidazolyl bridging ligand
AU - Barsukova, M. O.
AU - Samsonenko, D. G.
AU - Goncharova, T. V.
AU - Potapov, A. S.
AU - Sapchenko, S. A.
AU - Dybtsev, D. N.
AU - Fedin, V. P.
PY - 2016/12/1
Y1 - 2016/12/1
N2 - 1,4-Bis(imidazol-1-yl)butane was synthesized from imidazole and 1,4-dibromobutane in an alkaline medium. A variation of the molar ratio of reagents in the system copper(II) chloride dihydrate and 1,4-bis(imidazol-1-yl)butane (bImB) upon heating in N,N-dimethylformamide resulted in the synthesis of two new coordination polymers [Cu(bImB)Cl2] (1) and [Cu(bImB)2Cl2] (2), which were structurally characterized. Product 1 was found to possess a chain structure, while structure 2 is built of neutral layers, with the dimensionality of the extended coordination structures being determined by the reaction conditions. The new compounds were characterized by IR spectroscopy, elemental analysis, and powder X-ray diffraction data.
AB - 1,4-Bis(imidazol-1-yl)butane was synthesized from imidazole and 1,4-dibromobutane in an alkaline medium. A variation of the molar ratio of reagents in the system copper(II) chloride dihydrate and 1,4-bis(imidazol-1-yl)butane (bImB) upon heating in N,N-dimethylformamide resulted in the synthesis of two new coordination polymers [Cu(bImB)Cl2] (1) and [Cu(bImB)2Cl2] (2), which were structurally characterized. Product 1 was found to possess a chain structure, while structure 2 is built of neutral layers, with the dimensionality of the extended coordination structures being determined by the reaction conditions. The new compounds were characterized by IR spectroscopy, elemental analysis, and powder X-ray diffraction data.
KW - bis(imidazolyl)alkanes
KW - coordination polymer
KW - copper
KW - X-ray diffraction
UR - http://www.scopus.com/inward/record.url?scp=85019754128&partnerID=8YFLogxK
U2 - 10.1007/s11172-016-1677-4
DO - 10.1007/s11172-016-1677-4
M3 - Article
AN - SCOPUS:85019754128
VL - 65
SP - 2914
EP - 2919
JO - Russian Chemical Bulletin
JF - Russian Chemical Bulletin
SN - 1066-5285
IS - 12
ER -
ID: 25398140