Research output: Contribution to journal › Article › peer-review
Composite Sorbents Based on Carbon Nanotubes and K 2 CO 3 for CO 2 Capture from Ambient Air. / Derevschikov, V. S.; Kuznetsov, V. L.; Veselovskaya, J. V. et al.
In: Industrial & Engineering Chemistry Research, Vol. 62, No. 47, 29.11.2023, p. 20340–20351.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Composite Sorbents Based on Carbon Nanotubes and K 2 CO 3 for CO 2 Capture from Ambient Air
AU - Derevschikov, V. S.
AU - Kuznetsov, V. L.
AU - Veselovskaya, J. V.
AU - Moseenkov, S. I.
AU - Yatsenko, D. A.
AU - Suknev, A. P.
AU - Leonova, A. A.
AU - Makolkin, N. V.
AU - Ruvinskiy, P. S.
N1 - This work was supported by the Ministry of Science and Higher Education of the Russian Federation within the governmental order for Boreskov Institute of Catalysis.
PY - 2023/11/29
Y1 - 2023/11/29
N2 - K2CO3-containing sorbents supported on carbon nanotubes (CNT) were prepared via one-pot extrusion molding and heat treatment. The porous CNTs were mixed with a water-isopropyl alcohol solution of potassium acetate (CH3COOK) and extruded by a plunger extruder. After drying in air, extrudates were calcined at 500 °C in argon to obtain the sorbents with a K2CO3 weight content in a range of 13.1-44.8 wt %. Samples were characterized using various techniques (scanning electron microscopy (SEM), X-ray diffraction (XRD), and low-temperature nitrogen adsorption) and were tested in the process of carbon dioxide capture from ambient air. The sorbent with 44.8 wt % K2CO3 demonstrated the promising dynamic CO2-sorption capacity (up to 8.9 wt %) under temperature-swing adsorption (TSA) cycle conditions. Taking into account that the sorbents need a relatively low temperature for regeneration (150 °C) while demonstrating high CO2-sorption capacity in the sequence of TSA cycles, these sorbents may be of interest for direct air capture applications.
AB - K2CO3-containing sorbents supported on carbon nanotubes (CNT) were prepared via one-pot extrusion molding and heat treatment. The porous CNTs were mixed with a water-isopropyl alcohol solution of potassium acetate (CH3COOK) and extruded by a plunger extruder. After drying in air, extrudates were calcined at 500 °C in argon to obtain the sorbents with a K2CO3 weight content in a range of 13.1-44.8 wt %. Samples were characterized using various techniques (scanning electron microscopy (SEM), X-ray diffraction (XRD), and low-temperature nitrogen adsorption) and were tested in the process of carbon dioxide capture from ambient air. The sorbent with 44.8 wt % K2CO3 demonstrated the promising dynamic CO2-sorption capacity (up to 8.9 wt %) under temperature-swing adsorption (TSA) cycle conditions. Taking into account that the sorbents need a relatively low temperature for regeneration (150 °C) while demonstrating high CO2-sorption capacity in the sequence of TSA cycles, these sorbents may be of interest for direct air capture applications.
UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85179048390&origin=inward&txGid=8bd58235d34afe2e699d3c95b2193190
UR - https://www.mendeley.com/catalogue/51bc203b-92c7-3d12-be0a-acc1f0b60fbf/
U2 - 10.1021/acs.iecr.3c02055
DO - 10.1021/acs.iecr.3c02055
M3 - Article
VL - 62
SP - 20340
EP - 20351
JO - Industrial & Engineering Chemistry Research
JF - Industrial & Engineering Chemistry Research
SN - 0888-5885
IS - 47
ER -
ID: 59347569