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Complexes PdCl2 with optically active hybrid ligands built of α-pinene and β-alanine molecules. / Kokina, T. E.; Glinskaya, L. A.; Marenin, K. S. et al.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 43, No. 4, 01.04.2017, p. 213-222.

Research output: Contribution to journal › Article › peer-review

Harvard

Kokina, TE, Glinskaya, LA, Marenin, KS, Korol’kov, IV, Naumov, DY, Tkachev, AV & Larionov, SV 2017, 'Complexes PdCl2 with optically active hybrid ligands built of α-pinene and β-alanine molecules', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 43, no. 4, pp. 213-222. https://doi.org/10.1134/S1070328417030034

APA

Kokina, T. E., Glinskaya, L. A., Marenin, K. S., Korol’kov, I. V., Naumov, D. Y., Tkachev, A. V., & Larionov, S. V. (2017). Complexes PdCl2 with optically active hybrid ligands built of α-pinene and β-alanine molecules. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 43(4), 213-222. https://doi.org/10.1134/S1070328417030034

Vancouver

Kokina TE, Glinskaya LA, Marenin KS, Korol’kov IV, Naumov DY, Tkachev AV et al. Complexes PdCl2 with optically active hybrid ligands built of α-pinene and β-alanine molecules. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2017 Apr 1;43(4):213-222. doi: 10.1134/S1070328417030034

Author

Kokina, T. E. ; Glinskaya, L. A. ; Marenin, K. S. et al. / Complexes PdCl2 with optically active hybrid ligands built of α-pinene and β-alanine molecules. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2017 ; Vol. 43, No. 4. pp. 213-222.

BibTeX

@article{db0906589107474fbed09def9c1fa1d5,
title = "Complexes PdCl2 with optically active hybrid ligands built of α-pinene and β-alanine molecules",
abstract = "Complexes Pd(LH)Cl2 (LH is the N-derivative of β-alanine based on (–)-α-pinene) and PdLEtCl2 (LEt is ethyl ester of LH) are synthesized. The X-ray diffraction analysis (СIF file ССDC no. 1471432) shows that the single crystals of the [PdLEtCl2] complex belong to the racemate. The crystal structure contains (+)- and (–)-enantiomeric molecules of the mononuclear complex. Ligand LEt is bidentate chelating. The coordination PdCl2N2 core is a distorted square. The contacts Pd…Cl and hydrogen bonds N–H…Cl between molecules of the (+)- and (–)-enantiomers result in the formation of dimeric ensembles, which are joined into chains due to the C–H…Cl hydrogen bonds. According to the X-ray powder diffraction data, the products of the synthesis of complex [PdLEtCl2] contain both the racemate and (+)-enantiomer. The (+)-enantiomer is isolated by the recrystallization of the synthesis product. Complex Pd(LH)Cl2 is an optically active right-handed compound. According to the NMR data, complex PdLEtCl2 does not dissociate in a CDCl3 solution. The results of IR and NMR spectroscopy indicate that the molecular structure of complex Pd(LH)Cl2 is similar to that of [PdLEtCl2].",
keywords = "hybrid ligands, optical activity, Pd complexes, pinene, structure, HYDROCARBONS, COPPER(II), CRYSTAL, COORDINATION-COMPOUNDS, (+)-3-CARENE, OXIMES, CHIRAL PYRIDINE, NITROSO CHLORIDES",
author = "Kokina, {T. E.} and Glinskaya, {L. A.} and Marenin, {K. S.} and Korol{\textquoteright}kov, {I. V.} and Naumov, {D. Yu} and Tkachev, {A. V.} and Larionov, {S. V.}",
year = "2017",
month = apr,
day = "1",
doi = "10.1134/S1070328417030034",
language = "English",
volume = "43",
pages = "213--222",
journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",
issn = "1070-3284",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "4",

}

RIS

TY - JOUR

T1 - Complexes PdCl2 with optically active hybrid ligands built of α-pinene and β-alanine molecules

AU - Kokina, T. E.

AU - Glinskaya, L. A.

AU - Marenin, K. S.

AU - Korol’kov, I. V.

AU - Naumov, D. Yu

AU - Tkachev, A. V.

AU - Larionov, S. V.

PY - 2017/4/1

Y1 - 2017/4/1

N2 - Complexes Pd(LH)Cl2 (LH is the N-derivative of β-alanine based on (–)-α-pinene) and PdLEtCl2 (LEt is ethyl ester of LH) are synthesized. The X-ray diffraction analysis (СIF file ССDC no. 1471432) shows that the single crystals of the [PdLEtCl2] complex belong to the racemate. The crystal structure contains (+)- and (–)-enantiomeric molecules of the mononuclear complex. Ligand LEt is bidentate chelating. The coordination PdCl2N2 core is a distorted square. The contacts Pd…Cl and hydrogen bonds N–H…Cl between molecules of the (+)- and (–)-enantiomers result in the formation of dimeric ensembles, which are joined into chains due to the C–H…Cl hydrogen bonds. According to the X-ray powder diffraction data, the products of the synthesis of complex [PdLEtCl2] contain both the racemate and (+)-enantiomer. The (+)-enantiomer is isolated by the recrystallization of the synthesis product. Complex Pd(LH)Cl2 is an optically active right-handed compound. According to the NMR data, complex PdLEtCl2 does not dissociate in a CDCl3 solution. The results of IR and NMR spectroscopy indicate that the molecular structure of complex Pd(LH)Cl2 is similar to that of [PdLEtCl2].

AB - Complexes Pd(LH)Cl2 (LH is the N-derivative of β-alanine based on (–)-α-pinene) and PdLEtCl2 (LEt is ethyl ester of LH) are synthesized. The X-ray diffraction analysis (СIF file ССDC no. 1471432) shows that the single crystals of the [PdLEtCl2] complex belong to the racemate. The crystal structure contains (+)- and (–)-enantiomeric molecules of the mononuclear complex. Ligand LEt is bidentate chelating. The coordination PdCl2N2 core is a distorted square. The contacts Pd…Cl and hydrogen bonds N–H…Cl between molecules of the (+)- and (–)-enantiomers result in the formation of dimeric ensembles, which are joined into chains due to the C–H…Cl hydrogen bonds. According to the X-ray powder diffraction data, the products of the synthesis of complex [PdLEtCl2] contain both the racemate and (+)-enantiomer. The (+)-enantiomer is isolated by the recrystallization of the synthesis product. Complex Pd(LH)Cl2 is an optically active right-handed compound. According to the NMR data, complex PdLEtCl2 does not dissociate in a CDCl3 solution. The results of IR and NMR spectroscopy indicate that the molecular structure of complex Pd(LH)Cl2 is similar to that of [PdLEtCl2].

KW - hybrid ligands

KW - optical activity

KW - Pd complexes

KW - pinene

KW - structure

KW - HYDROCARBONS

KW - COPPER(II)

KW - CRYSTAL

KW - COORDINATION-COMPOUNDS

KW - (+)-3-CARENE

KW - OXIMES

KW - CHIRAL PYRIDINE

KW - NITROSO CHLORIDES

UR - http://www.scopus.com/inward/record.url?scp=85018515332&partnerID=8YFLogxK

U2 - 10.1134/S1070328417030034

DO - 10.1134/S1070328417030034

M3 - Article

AN - SCOPUS:85018515332

VL - 43

SP - 213

EP - 222

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 4

ER -

ID: 10040717