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Complexes of Zn(II) and Сu(II) with the Amino Derivatives of Deoxycholic Acid : Syntheses, Structures, and Properties. / Kokina, T. E.; Salomatina, O. V.; Popadyuk, I. I. et al.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 45, No. 7, 01.07.2019, p. 505-511.

Research output: Contribution to journal › Article › peer-review

Harvard

Kokina, TE, Salomatina, OV, Popadyuk, II, Glinskaya, LA, Korol’kov, IV, Sheludyakova, LA, Rakhmanova, MI & Salakhutdinov, NF 2019, 'Complexes of Zn(II) and Сu(II) with the Amino Derivatives of Deoxycholic Acid: Syntheses, Structures, and Properties', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 45, no. 7, pp. 505-511. https://doi.org/10.1134/S1070328419070030

APA

Kokina, T. E., Salomatina, O. V., Popadyuk, I. I., Glinskaya, L. A., Korol’kov, I. V., Sheludyakova, L. A., Rakhmanova, M. I., & Salakhutdinov, N. F. (2019). Complexes of Zn(II) and Сu(II) with the Amino Derivatives of Deoxycholic Acid: Syntheses, Structures, and Properties. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 45(7), 505-511. https://doi.org/10.1134/S1070328419070030

Vancouver

Kokina TE, Salomatina OV, Popadyuk II, Glinskaya LA, Korol’kov IV, Sheludyakova LA et al. Complexes of Zn(II) and Сu(II) with the Amino Derivatives of Deoxycholic Acid: Syntheses, Structures, and Properties. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2019 Jul 1;45(7):505-511. doi: 10.1134/S1070328419070030

Author

Kokina, T. E. ; Salomatina, O. V. ; Popadyuk, I. I. et al. / Complexes of Zn(II) and Сu(II) with the Amino Derivatives of Deoxycholic Acid : Syntheses, Structures, and Properties. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2019 ; Vol. 45, No. 7. pp. 505-511.

BibTeX

@article{b37ecc425dcd4f668ec1e9854e870003,
title = "Complexes of Zn(II) and Сu(II) with the Amino Derivatives of Deoxycholic Acid: Syntheses, Structures, and Properties",
abstract = "Abstract: Complexes [Zn(L)Cl2] (I), Cu(L)Cl2 ∙ H2O (II), Zn(L1)Cl2 ∙ 0.5H2O (III), and Cu(L1)Cl2 ∙ 0.5H2O (IV) (where L and L1 are the diaminopropylene and diaminoethylene derivatives of deoxycholic acid, respectively) are synthesized. The structure of mononuclear complex I is determined by X-ray structure analysis (CIF file CCDC no. 1875305). The coordination polyhedron of the Zn atom (Cl2N2) is a distorted tetrahedron. According to the X-ray diffraction data, the crystals of compounds III and IV are isostructural. It is shown by IR spectroscopy that the structures of complexes II–IV are similar to that of complex I. In the solid phase, compounds L and L1 possess photoluminescence in the visible spectral range (λmax = 440 and 415 nm, respectively). Complex formation with Zn2+ ions does not change the photoluminescence properties of L and L1.",
keywords = "complexes, copper, crystal structure, deoxycholic acid, synthesis, zinc, LIGANDS, SPECTROSCOPIC PROPERTIES, CRYSTAL, BILE-ACIDS",
author = "Kokina, {T. E.} and Salomatina, {O. V.} and Popadyuk, {I. I.} and Glinskaya, {L. A.} and Korol{\textquoteright}kov, {I. V.} and Sheludyakova, {L. A.} and Rakhmanova, {M. I.} and Salakhutdinov, {N. F.}",
note = "Publisher Copyright: {\textcopyright} 2019, Pleiades Publishing, Ltd.",
year = "2019",
month = jul,
day = "1",
doi = "10.1134/S1070328419070030",
language = "English",
volume = "45",
pages = "505--511",
journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",
issn = "1070-3284",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "7",

}

RIS

TY - JOUR

T1 - Complexes of Zn(II) and Сu(II) with the Amino Derivatives of Deoxycholic Acid

T2 - Syntheses, Structures, and Properties

AU - Kokina, T. E.

AU - Salomatina, O. V.

AU - Popadyuk, I. I.

AU - Glinskaya, L. A.

AU - Korol’kov, I. V.

AU - Sheludyakova, L. A.

AU - Rakhmanova, M. I.

AU - Salakhutdinov, N. F.

N1 - Publisher Copyright: © 2019, Pleiades Publishing, Ltd.

PY - 2019/7/1

Y1 - 2019/7/1

N2 - Abstract: Complexes [Zn(L)Cl2] (I), Cu(L)Cl2 ∙ H2O (II), Zn(L1)Cl2 ∙ 0.5H2O (III), and Cu(L1)Cl2 ∙ 0.5H2O (IV) (where L and L1 are the diaminopropylene and diaminoethylene derivatives of deoxycholic acid, respectively) are synthesized. The structure of mononuclear complex I is determined by X-ray structure analysis (CIF file CCDC no. 1875305). The coordination polyhedron of the Zn atom (Cl2N2) is a distorted tetrahedron. According to the X-ray diffraction data, the crystals of compounds III and IV are isostructural. It is shown by IR spectroscopy that the structures of complexes II–IV are similar to that of complex I. In the solid phase, compounds L and L1 possess photoluminescence in the visible spectral range (λmax = 440 and 415 nm, respectively). Complex formation with Zn2+ ions does not change the photoluminescence properties of L and L1.

AB - Abstract: Complexes [Zn(L)Cl2] (I), Cu(L)Cl2 ∙ H2O (II), Zn(L1)Cl2 ∙ 0.5H2O (III), and Cu(L1)Cl2 ∙ 0.5H2O (IV) (where L and L1 are the diaminopropylene and diaminoethylene derivatives of deoxycholic acid, respectively) are synthesized. The structure of mononuclear complex I is determined by X-ray structure analysis (CIF file CCDC no. 1875305). The coordination polyhedron of the Zn atom (Cl2N2) is a distorted tetrahedron. According to the X-ray diffraction data, the crystals of compounds III and IV are isostructural. It is shown by IR spectroscopy that the structures of complexes II–IV are similar to that of complex I. In the solid phase, compounds L and L1 possess photoluminescence in the visible spectral range (λmax = 440 and 415 nm, respectively). Complex formation with Zn2+ ions does not change the photoluminescence properties of L and L1.

KW - complexes

KW - copper

KW - crystal structure

KW - deoxycholic acid

KW - synthesis

KW - zinc

KW - LIGANDS

KW - SPECTROSCOPIC PROPERTIES

KW - CRYSTAL

KW - BILE-ACIDS

UR - http://www.scopus.com/inward/record.url?scp=85068783617&partnerID=8YFLogxK

U2 - 10.1134/S1070328419070030

DO - 10.1134/S1070328419070030

M3 - Article

AN - SCOPUS:85068783617

VL - 45

SP - 505

EP - 511

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 7

ER -

ID: 20838658