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Complexes of Cu(I) and Pd(II) with (+)-camphor and (–)-cavrone thiosemicarbazones : Synthesis, structure, and cytotoxicity of the Pd(II) complex. / Kokina, T. E.; Sheludyakova, L. A.; Eremina, Yu A. et al.

In: Russian Journal of General Chemistry, Vol. 87, No. 10, 01.10.2017, p. 2332-2342.

Research output: Contribution to journal › Article › peer-review

Harvard

Kokina, TE, Sheludyakova, LA, Eremina, YA, Vorontsova, EV, Glinskaya, LA, Piryazev, DA, Lider, EV, Tkachev, AV & Larionov, SV 2017, 'Complexes of Cu(I) and Pd(II) with (+)-camphor and (–)-cavrone thiosemicarbazones: Synthesis, structure, and cytotoxicity of the Pd(II) complex', Russian Journal of General Chemistry, vol. 87, no. 10, pp. 2332-2342. https://doi.org/10.1134/S1070363217100140

APA

Kokina, T. E., Sheludyakova, L. A., Eremina, Y. A., Vorontsova, E. V., Glinskaya, L. A., Piryazev, D. A., Lider, E. V., Tkachev, A. V., & Larionov, S. V. (2017). Complexes of Cu(I) and Pd(II) with (+)-camphor and (–)-cavrone thiosemicarbazones: Synthesis, structure, and cytotoxicity of the Pd(II) complex. Russian Journal of General Chemistry, 87(10), 2332-2342. https://doi.org/10.1134/S1070363217100140

Vancouver

Kokina TE, Sheludyakova LA, Eremina YA, Vorontsova EV, Glinskaya LA, Piryazev DA et al. Complexes of Cu(I) and Pd(II) with (+)-camphor and (–)-cavrone thiosemicarbazones: Synthesis, structure, and cytotoxicity of the Pd(II) complex. Russian Journal of General Chemistry. 2017 Oct 1;87(10):2332-2342. doi: 10.1134/S1070363217100140

Author

Kokina, T. E. ; Sheludyakova, L. A. ; Eremina, Yu A. et al. / Complexes of Cu(I) and Pd(II) with (+)-camphor and (–)-cavrone thiosemicarbazones : Synthesis, structure, and cytotoxicity of the Pd(II) complex. In: Russian Journal of General Chemistry. 2017 ; Vol. 87, No. 10. pp. 2332-2342.

BibTeX

@article{8f45d7d6ce5449309d2ba82e73829307,
title = "Complexes of Cu(I) and Pd(II) with (+)-camphor and (–)-cavrone thiosemicarbazones: Synthesis, structure, and cytotoxicity of the Pd(II) complex",
abstract = "CuLCl, CuL1Cl, PdLCl2, and PdL1Cl2 complexes [L and L1 being (+)-camphor and (–)-carvone thiosemicarbazones, respectively] have been synthesized. The structure of binuclear [Pd2L2 2Cl4] complex has been determined by means of X-ray diffraction. The L2 ligand (dehydrogenated (–)-carvone thiosemicarbazone) is coordinated via the bridging S atom to two Pd atoms. The complexes of Cu(I) and Pd(II) presumably have polynuclear and binuclear structure, respectively. These facts are in good agreement with IR and NMR spectroscopy as well as mass spectrometry data which indicate the coordination of L and L1 ligands via the S atom. The influence of L1 and PdL1Cl2 on viability of the Hep2 cell line has been studied. The PdL1Cl2 complex is more cytotoxic than L1 ligand.",
keywords = "Cu(I) complex, cytotoxicity, Pd(II) complex, terpene, thiosemicarbazone, COPPER-COMPLEXES, TRANSITION-METAL COMPLEXES, ANTICANCER AGENTS, ISATIN BETA-THIOSEMICARBAZONES, CRYSTAL-STRUCTURES, SPECTRA, TRENDS",
author = "Kokina, {T. E.} and Sheludyakova, {L. A.} and Eremina, {Yu A.} and Vorontsova, {E. V.} and Glinskaya, {L. A.} and Piryazev, {D. A.} and Lider, {E. V.} and Tkachev, {A. V.} and Larionov, {S. V.}",
note = "Publisher Copyright: {\textcopyright} 2017, Pleiades Publishing, Ltd.",
year = "2017",
month = oct,
day = "1",
doi = "10.1134/S1070363217100140",
language = "English",
volume = "87",
pages = "2332--2342",
journal = "Russian Journal of General Chemistry",
issn = "1070-3632",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "10",

}

RIS

TY - JOUR

T1 - Complexes of Cu(I) and Pd(II) with (+)-camphor and (–)-cavrone thiosemicarbazones

T2 - Synthesis, structure, and cytotoxicity of the Pd(II) complex

AU - Kokina, T. E.

AU - Sheludyakova, L. A.

AU - Eremina, Yu A.

AU - Vorontsova, E. V.

AU - Glinskaya, L. A.

AU - Piryazev, D. A.

AU - Lider, E. V.

AU - Tkachev, A. V.

AU - Larionov, S. V.

N1 - Publisher Copyright: © 2017, Pleiades Publishing, Ltd.

PY - 2017/10/1

Y1 - 2017/10/1

N2 - CuLCl, CuL1Cl, PdLCl2, and PdL1Cl2 complexes [L and L1 being (+)-camphor and (–)-carvone thiosemicarbazones, respectively] have been synthesized. The structure of binuclear [Pd2L2 2Cl4] complex has been determined by means of X-ray diffraction. The L2 ligand (dehydrogenated (–)-carvone thiosemicarbazone) is coordinated via the bridging S atom to two Pd atoms. The complexes of Cu(I) and Pd(II) presumably have polynuclear and binuclear structure, respectively. These facts are in good agreement with IR and NMR spectroscopy as well as mass spectrometry data which indicate the coordination of L and L1 ligands via the S atom. The influence of L1 and PdL1Cl2 on viability of the Hep2 cell line has been studied. The PdL1Cl2 complex is more cytotoxic than L1 ligand.

AB - CuLCl, CuL1Cl, PdLCl2, and PdL1Cl2 complexes [L and L1 being (+)-camphor and (–)-carvone thiosemicarbazones, respectively] have been synthesized. The structure of binuclear [Pd2L2 2Cl4] complex has been determined by means of X-ray diffraction. The L2 ligand (dehydrogenated (–)-carvone thiosemicarbazone) is coordinated via the bridging S atom to two Pd atoms. The complexes of Cu(I) and Pd(II) presumably have polynuclear and binuclear structure, respectively. These facts are in good agreement with IR and NMR spectroscopy as well as mass spectrometry data which indicate the coordination of L and L1 ligands via the S atom. The influence of L1 and PdL1Cl2 on viability of the Hep2 cell line has been studied. The PdL1Cl2 complex is more cytotoxic than L1 ligand.

KW - Cu(I) complex

KW - cytotoxicity

KW - Pd(II) complex

KW - terpene

KW - thiosemicarbazone

KW - COPPER-COMPLEXES

KW - TRANSITION-METAL COMPLEXES

KW - ANTICANCER AGENTS

KW - ISATIN BETA-THIOSEMICARBAZONES

KW - CRYSTAL-STRUCTURES

KW - SPECTRA

KW - TRENDS

UR - http://www.scopus.com/inward/record.url?scp=85034572552&partnerID=8YFLogxK

U2 - 10.1134/S1070363217100140

DO - 10.1134/S1070363217100140

M3 - Article

AN - SCOPUS:85034572552

VL - 87

SP - 2332

EP - 2342

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 10

ER -

ID: 9674021