Comparison of analytical performances of inductively coupled plasma mass spectrometry and inductively coupled plasma atomic emission spectrometry for trace analysis of bismuth and bismuth oxide

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Comparison of analytical performances of inductively coupled plasma mass spectrometry and inductively coupled plasma atomic emission spectrometry for trace analysis of bismuth and bismuth oxide. / Medvedev, Nickolay S.; Shaverina, Anastasiya V.; Tsygankova, Alphiya R. et al.

In: Spectrochimica Acta - Part B Atomic Spectroscopy, Vol. 142, 01.04.2018, p. 23-28.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{fa63d1878dab494baad8666a4cb830d1,

title = "Comparison of analytical performances of inductively coupled plasma mass spectrometry and inductively coupled plasma atomic emission spectrometry for trace analysis of bismuth and bismuth oxide",

abstract = "The paper presents а comparison of analytical performances of inductively coupled plasma mass spectrometry (ICP-MS) and inductively coupled plasma atomic emission spectrometry (ICP-AES) for trace analysis of high purity bismuth and bismuth oxide. Matrix effects in the ICP-MS and ICP-AES methods were studied as a function of Bi concentration, ICP power and nebulizer flow rate. For ICP-MS the strong dependence of the matrix effects versus the atomic mass of analytes was observed. For ICP-AES the minimal matrix effects were achieved for spectral lines of analytes with low excitation potentials. The optimum degree of sample dilution providing minimum values of the limits of detection (LODs) was chosen. Both methods let us to reach LODs from n·10−7 to n·10−4 wt% for more than 50 trace elements. For most elements the LODs of ICP-MS were lower in comparison to ICP-AES. Validation of accuracy of the developed techniques was performed by “added-found” experiments and by comparison of the results of ICP-MS and ICP-AES analysis of high-purity bismuth oxide.",

keywords = "Bismuth, Bismuth oxide, ICP-AES, ICP-MS, Matrix interferences, BI4GE3O12, ABSORPTION-SPECTROMETRY, CONCOMITANT ELEMENTS, OPERATING-CONDITIONS, INTERFERENCES",

author = "Medvedev, {Nickolay S.} and Shaverina, {Anastasiya V.} and Tsygankova, {Alphiya R.} and Saprykin, {Anatoly I.}",

year = "2018",

month = apr,

day = "1",

doi = "10.1016/j.sab.2018.01.017",

language = "English",

volume = "142",

pages = "23--28",

journal = "Spectrochimica Acta, Part B: Atomic Spectroscopy",

issn = "0584-8547",

publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Comparison of analytical performances of inductively coupled plasma mass spectrometry and inductively coupled plasma atomic emission spectrometry for trace analysis of bismuth and bismuth oxide

AU - Medvedev, Nickolay S.

AU - Shaverina, Anastasiya V.

AU - Tsygankova, Alphiya R.

AU - Saprykin, Anatoly I.

PY - 2018/4/1

Y1 - 2018/4/1

N2 - The paper presents а comparison of analytical performances of inductively coupled plasma mass spectrometry (ICP-MS) and inductively coupled plasma atomic emission spectrometry (ICP-AES) for trace analysis of high purity bismuth and bismuth oxide. Matrix effects in the ICP-MS and ICP-AES methods were studied as a function of Bi concentration, ICP power and nebulizer flow rate. For ICP-MS the strong dependence of the matrix effects versus the atomic mass of analytes was observed. For ICP-AES the minimal matrix effects were achieved for spectral lines of analytes with low excitation potentials. The optimum degree of sample dilution providing minimum values of the limits of detection (LODs) was chosen. Both methods let us to reach LODs from n·10−7 to n·10−4 wt% for more than 50 trace elements. For most elements the LODs of ICP-MS were lower in comparison to ICP-AES. Validation of accuracy of the developed techniques was performed by “added-found” experiments and by comparison of the results of ICP-MS and ICP-AES analysis of high-purity bismuth oxide.

AB - The paper presents а comparison of analytical performances of inductively coupled plasma mass spectrometry (ICP-MS) and inductively coupled plasma atomic emission spectrometry (ICP-AES) for trace analysis of high purity bismuth and bismuth oxide. Matrix effects in the ICP-MS and ICP-AES methods were studied as a function of Bi concentration, ICP power and nebulizer flow rate. For ICP-MS the strong dependence of the matrix effects versus the atomic mass of analytes was observed. For ICP-AES the minimal matrix effects were achieved for spectral lines of analytes with low excitation potentials. The optimum degree of sample dilution providing minimum values of the limits of detection (LODs) was chosen. Both methods let us to reach LODs from n·10−7 to n·10−4 wt% for more than 50 trace elements. For most elements the LODs of ICP-MS were lower in comparison to ICP-AES. Validation of accuracy of the developed techniques was performed by “added-found” experiments and by comparison of the results of ICP-MS and ICP-AES analysis of high-purity bismuth oxide.

KW - Bismuth

KW - Bismuth oxide

KW - ICP-AES

KW - ICP-MS

KW - Matrix interferences

KW - BI4GE3O12

KW - ABSORPTION-SPECTROMETRY

KW - CONCOMITANT ELEMENTS

KW - OPERATING-CONDITIONS

KW - INTERFERENCES

UR - http://www.scopus.com/inward/record.url?scp=85041536162&partnerID=8YFLogxK

U2 - 10.1016/j.sab.2018.01.017

DO - 10.1016/j.sab.2018.01.017

M3 - Article

AN - SCOPUS:85041536162

VL - 142

SP - 23

EP - 28

JO - Spectrochimica Acta, Part B: Atomic Spectroscopy

JF - Spectrochimica Acta, Part B: Atomic Spectroscopy

SN - 0584-8547

ER -

ID: 10452836