Chiral guest in a chiral framework

Standard

Chiral guest in a chiral framework : X-ray diffraction study. / Zavakhina, M. S.; Khan, I. S.; Barsukova, M. O. et al.

In: Russian Chemical Bulletin, Vol. 67, No. 7, 01.07.2018, p. 1268-1272.

Research output: Contribution to journal › Article › peer-review

Harvard

Zavakhina, MS, Khan, IS, Barsukova, MO, Sapianik, AA, Samsonenko, DG , Dybtsev, DN & Fedin, VP 2018, 'Chiral guest in a chiral framework: X-ray diffraction study', Russian Chemical Bulletin, vol. 67, no. 7, pp. 1268-1272. https://doi.org/10.1007/s11172-018-2211-7

APA

Zavakhina, M. S., Khan, I. S., Barsukova, M. O., Sapianik, A. A., Samsonenko, D. G., Dybtsev, D. N., & Fedin, V. P. (2018). Chiral guest in a chiral framework: X-ray diffraction study. Russian Chemical Bulletin, 67(7), 1268-1272. https://doi.org/10.1007/s11172-018-2211-7

Vancouver

Zavakhina MS, Khan IS, Barsukova MO, Sapianik AA, Samsonenko DG , Dybtsev DN et al. Chiral guest in a chiral framework: X-ray diffraction study. Russian Chemical Bulletin. 2018 Jul 1;67(7):1268-1272. doi: 10.1007/s11172-018-2211-7

Author

Zavakhina, M. S. ; Khan, I. S. ; Barsukova, M. O. et al. / Chiral guest in a chiral framework : X-ray diffraction study. In: Russian Chemical Bulletin. 2018 ; Vol. 67, No. 7. pp. 1268-1272.

BibTeX

@article{5df545bb6ae4479cbd491a447c1e3ecc,

title = "Chiral guest in a chiral framework: X-ray diffraction study",

abstract = "The inclusion compound of zinc lactate terephthalate with R-butan-2-ol, [Zn2(R-BusOH) (bdc)(S-lac)]•(R-BusOH) (BusOH is butan-2-ol, H2bdc is terephthalic acid, S-H2lac is lactic acid), was prepared by soaking crystals of [Zn2(dmf)(bdc)(S-lac)]•DMF in pure R-butan-2-ol. The positions of chiral alcohol molecules in voids of the chiral framework and the host–guest contacts were determined by X-ray diffraction. These data provide an explanation for the origin of chiral discrimination of zinc lactate terephthalate toward the R-isomer of butan-2-ol.",

keywords = "chiral alcohols, coordination polymers, crystal structure, inclusion compounds, lactic acid, zinc complexes, CRYSTAL-STRUCTURE, MEMBRANE, ADSORPTION, INCLUSION COMPOUND, ALCOHOLS, METAL-ORGANIC FRAMEWORKS, POLYMER, ENANTIOSELECTIVE SORPTION, SEPARATION",

author = "Zavakhina, {M. S.} and Khan, {I. S.} and Barsukova, {M. O.} and Sapianik, {A. A.} and Samsonenko, {D. G.} and Dybtsev, {D. N.} and Fedin, {V. P.}",

note = "Publisher Copyright: {\textcopyright} 2018, Springer Science+Business Media, LLC, part of Springer Nature.",

year = "2018",

month = jul,

day = "1",

doi = "10.1007/s11172-018-2211-7",

language = "English",

volume = "67",

pages = "1268--1272",

journal = "Russian Chemical Bulletin",

issn = "1066-5285",

publisher = "Springer Nature",

number = "7",

}

RIS

TY - JOUR

T1 - Chiral guest in a chiral framework

T2 - X-ray diffraction study

AU - Zavakhina, M. S.

AU - Khan, I. S.

AU - Barsukova, M. O.

AU - Sapianik, A. A.

AU - Samsonenko, D. G.

AU - Dybtsev, D. N.

AU - Fedin, V. P.

PY - 2018/7/1

Y1 - 2018/7/1

N2 - The inclusion compound of zinc lactate terephthalate with R-butan-2-ol, [Zn2(R-BusOH) (bdc)(S-lac)]•(R-BusOH) (BusOH is butan-2-ol, H2bdc is terephthalic acid, S-H2lac is lactic acid), was prepared by soaking crystals of [Zn2(dmf)(bdc)(S-lac)]•DMF in pure R-butan-2-ol. The positions of chiral alcohol molecules in voids of the chiral framework and the host–guest contacts were determined by X-ray diffraction. These data provide an explanation for the origin of chiral discrimination of zinc lactate terephthalate toward the R-isomer of butan-2-ol.

AB - The inclusion compound of zinc lactate terephthalate with R-butan-2-ol, [Zn2(R-BusOH) (bdc)(S-lac)]•(R-BusOH) (BusOH is butan-2-ol, H2bdc is terephthalic acid, S-H2lac is lactic acid), was prepared by soaking crystals of [Zn2(dmf)(bdc)(S-lac)]•DMF in pure R-butan-2-ol. The positions of chiral alcohol molecules in voids of the chiral framework and the host–guest contacts were determined by X-ray diffraction. These data provide an explanation for the origin of chiral discrimination of zinc lactate terephthalate toward the R-isomer of butan-2-ol.

KW - chiral alcohols

KW - coordination polymers

KW - crystal structure

KW - inclusion compounds

KW - lactic acid

KW - zinc complexes

KW - CRYSTAL-STRUCTURE

KW - MEMBRANE

KW - ADSORPTION

KW - INCLUSION COMPOUND

KW - ALCOHOLS

KW - METAL-ORGANIC FRAMEWORKS

KW - POLYMER

KW - ENANTIOSELECTIVE SORPTION

KW - SEPARATION

UR - http://www.scopus.com/inward/record.url?scp=85054160302&partnerID=8YFLogxK

U2 - 10.1007/s11172-018-2211-7

DO - 10.1007/s11172-018-2211-7

M3 - Article

AN - SCOPUS:85054160302

VL - 67

SP - 1268

EP - 1272

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 1066-5285

IS - 7

ER -

ID: 16953675