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Chemistry of [PW11NbO40]4− : Structural rearrangement and metal coordination. / Bushmeleva, Ekaterina P.; Kompankov, Nikolay B.; Shiriyazdanov, Rishat R. et al.

In: Inorganic Chemistry Communications, Vol. 98, 01.12.2018, p. 180-183.

Research output: Contribution to journal › Article › peer-review

Harvard

Bushmeleva, EP, Kompankov, NB, Shiriyazdanov, RR, Karimova, AR, Abramov, PA & Sokolov, MN 2018, 'Chemistry of [PW11NbO40]4−: Structural rearrangement and metal coordination', Inorganic Chemistry Communications, vol. 98, pp. 180-183. https://doi.org/10.1016/j.inoche.2018.10.026

APA

Bushmeleva, E. P., Kompankov, N. B., Shiriyazdanov, R. R., Karimova, A. R., Abramov, P. A., & Sokolov, M. N. (2018). Chemistry of [PW11NbO40]4−: Structural rearrangement and metal coordination. Inorganic Chemistry Communications, 98, 180-183. https://doi.org/10.1016/j.inoche.2018.10.026

Vancouver

Bushmeleva EP, Kompankov NB, Shiriyazdanov RR, Karimova AR, Abramov PA, Sokolov MN. Chemistry of [PW11NbO40]4−: Structural rearrangement and metal coordination. Inorganic Chemistry Communications. 2018 Dec 1;98:180-183. doi: 10.1016/j.inoche.2018.10.026

Author

Bushmeleva, Ekaterina P. ; Kompankov, Nikolay B. ; Shiriyazdanov, Rishat R. et al. / Chemistry of [PW11NbO40]4− : Structural rearrangement and metal coordination. In: Inorganic Chemistry Communications. 2018 ; Vol. 98. pp. 180-183.

BibTeX

@article{c2a18c51dee045f48a421c1a4b86d5ca,
title = "Chemistry of [PW11NbO40]4−: Structural rearrangement and metal coordination",
abstract = "Treatment of Cs4[PW11NbO40]·12H2O with boiling water results in slow degradation of the [PW11NbO40]4− Keggin anion into the trilacunary [A-PW9O34]9− following by aggregation of the latter around three {M[dbnd]O} (M[dbnd]Nb, W) fragments, producing [(A-PW9O34)2(MO)3]8− Herve-type anion. The product was isolated as Cs8[(PW9O34)2(WO)(NbO)2]·17.5H2O (1) and characterized with XRD, XRPD, IR and 31P MAS NMR. Diffusion of diethyl ether into the solution of (TBA)4[PW11NbO40] and Pb(NO3)2 in N,N-dimethylformamide (DMF) leads to the crystallization of [Pb2(μ2-DMF)3(DMF)8][PW11NbO40]·DMF (2) with polymeric nature, where the {Pb2} cationic dimers and [PW11NbO40]4− anions form infinite linear chains via Pb–O[dbnd]M coordination. Complex (2) was characterized with XRD, IR and 31P MAS NMR.",
keywords = "TUNGSTOPHOSPHATE, CATALYSTS, KEGGIN",
author = "Bushmeleva, {Ekaterina P.} and Kompankov, {Nikolay B.} and Shiriyazdanov, {Rishat R.} and Karimova, {Albina R.} and Abramov, {Pavel A.} and Sokolov, {Maxim N.}",
note = "Publisher Copyright: {\textcopyright} 2018 Elsevier B.V.",
year = "2018",
month = dec,
day = "1",
doi = "10.1016/j.inoche.2018.10.026",
language = "English",
volume = "98",
pages = "180--183",
journal = "Inorganic Chemistry Communication",
issn = "1387-7003",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Chemistry of [PW11NbO40]4−

T2 - Structural rearrangement and metal coordination

AU - Bushmeleva, Ekaterina P.

AU - Kompankov, Nikolay B.

AU - Shiriyazdanov, Rishat R.

AU - Karimova, Albina R.

AU - Abramov, Pavel A.

AU - Sokolov, Maxim N.

N1 - Publisher Copyright: © 2018 Elsevier B.V.

PY - 2018/12/1

Y1 - 2018/12/1

N2 - Treatment of Cs4[PW11NbO40]·12H2O with boiling water results in slow degradation of the [PW11NbO40]4− Keggin anion into the trilacunary [A-PW9O34]9− following by aggregation of the latter around three {M[dbnd]O} (M[dbnd]Nb, W) fragments, producing [(A-PW9O34)2(MO)3]8− Herve-type anion. The product was isolated as Cs8[(PW9O34)2(WO)(NbO)2]·17.5H2O (1) and characterized with XRD, XRPD, IR and 31P MAS NMR. Diffusion of diethyl ether into the solution of (TBA)4[PW11NbO40] and Pb(NO3)2 in N,N-dimethylformamide (DMF) leads to the crystallization of [Pb2(μ2-DMF)3(DMF)8][PW11NbO40]·DMF (2) with polymeric nature, where the {Pb2} cationic dimers and [PW11NbO40]4− anions form infinite linear chains via Pb–O[dbnd]M coordination. Complex (2) was characterized with XRD, IR and 31P MAS NMR.

AB - Treatment of Cs4[PW11NbO40]·12H2O with boiling water results in slow degradation of the [PW11NbO40]4− Keggin anion into the trilacunary [A-PW9O34]9− following by aggregation of the latter around three {M[dbnd]O} (M[dbnd]Nb, W) fragments, producing [(A-PW9O34)2(MO)3]8− Herve-type anion. The product was isolated as Cs8[(PW9O34)2(WO)(NbO)2]·17.5H2O (1) and characterized with XRD, XRPD, IR and 31P MAS NMR. Diffusion of diethyl ether into the solution of (TBA)4[PW11NbO40] and Pb(NO3)2 in N,N-dimethylformamide (DMF) leads to the crystallization of [Pb2(μ2-DMF)3(DMF)8][PW11NbO40]·DMF (2) with polymeric nature, where the {Pb2} cationic dimers and [PW11NbO40]4− anions form infinite linear chains via Pb–O[dbnd]M coordination. Complex (2) was characterized with XRD, IR and 31P MAS NMR.

KW - TUNGSTOPHOSPHATE

KW - CATALYSTS

KW - KEGGIN

UR - http://www.scopus.com/inward/record.url?scp=85055674079&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2018.10.026

DO - 10.1016/j.inoche.2018.10.026

M3 - Article

AN - SCOPUS:85055674079

VL - 98

SP - 180

EP - 183

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

SN - 1387-7003

ER -

ID: 17232939