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Ceria–Zirconia Supported Platinum Catalysts for the Water-Gas Shift Reaction: The Influence of Support Composition. / Gorlova, A. M.; Pakharukova, V. P.; Stonkus, O. A. et al.

In: Kinetics and Catalysis, Vol. 64, No. 4, 08.2023, p. 449-457.

Research output: Contribution to journal › Article › peer-review

Harvard

Gorlova, AM, Pakharukova, VP, Stonkus, OA, Rogozhnikov, VN, Gladky, AY, Snytnikov, PV & Potemkin, DI 2023, 'Ceria–Zirconia Supported Platinum Catalysts for the Water-Gas Shift Reaction: The Influence of Support Composition', Kinetics and Catalysis, vol. 64, no. 4, pp. 449-457. https://doi.org/10.1134/S0023158423040031

APA

Gorlova, A. M., Pakharukova, V. P., Stonkus, O. A., Rogozhnikov, V. N., Gladky, A. Y., Snytnikov, P. V., & Potemkin, D. I. (2023). Ceria–Zirconia Supported Platinum Catalysts for the Water-Gas Shift Reaction: The Influence of Support Composition. Kinetics and Catalysis, 64(4), 449-457. https://doi.org/10.1134/S0023158423040031

Vancouver

Gorlova AM, Pakharukova VP, Stonkus OA, Rogozhnikov VN, Gladky AY, Snytnikov PV et al. Ceria–Zirconia Supported Platinum Catalysts for the Water-Gas Shift Reaction: The Influence of Support Composition. Kinetics and Catalysis. 2023 Aug;64(4):449-457. doi: 10.1134/S0023158423040031

Author

Gorlova, A. M. ; Pakharukova, V. P. ; Stonkus, O. A. et al. / Ceria–Zirconia Supported Platinum Catalysts for the Water-Gas Shift Reaction: The Influence of Support Composition. In: Kinetics and Catalysis. 2023 ; Vol. 64, No. 4. pp. 449-457.

BibTeX

@article{8d4644d7bdec43b49997a5f7d3581d01,
title = "Ceria–Zirconia Supported Platinum Catalysts for the Water-Gas Shift Reaction: The Influence of Support Composition",
abstract = "The study is presented on the influence of the composition of a ceria-zirconia support on the structure and the activity in water-gas shift reaction of platinum catalysts (Pt/Ce0.75Zr0.25O2 and Pt/Ce0.4Zr0.5Y0.05La0.05O2). The structure diagnostics of the samples were performed using high-resolution transmission electron microscopy, powder X-ray diffraction, CO chemisorption and X-ray atomic pair distribution function method. It was shown that the catalysts contain highly dispersed platinum particles not exceeding 2 nm in size. Platinum particles supported on Ce0.75Zr0.25O2 are smaller due to the higher specific surface area of the support. The catalysts Pt/Ce0.75Zr0.25O2 and Pt/Ce0.4Zr0.5Y0.05La0.05O2 proved to have similar efficiency while having the same platinum content. It was assumed that the catalysts supported on Ce0.4Zr0.5Y0.05La0.05O2 demonstrate a slightly higher turnover frequency per platinum surface atom, but it is likely compensated by the difference in the supported metal particle size.",
keywords = "ceria-zirconia, hydrogen purification, platinum catalyst, water-gas shift",
author = "Gorlova, {A. M.} and Pakharukova, {V. P.} and Stonkus, {O. A.} and Rogozhnikov, {V. N.} and Gladky, {A. Y.} and Snytnikov, {P. V.} and Potemkin, {D. I.}",
note = "This work was supported by Russian Science Foundation under the project no. 21-73-20075 (А.М. Gorlova, V.P. Pakharukova, О.А. Stonkus, V.N. Rogozhnikov).",
year = "2023",
month = aug,
doi = "10.1134/S0023158423040031",
language = "English",
volume = "64",
pages = "449--457",
journal = "Kinetics and Catalysis",
issn = "0023-1584",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "4",

}

RIS

TY - JOUR

T1 - Ceria–Zirconia Supported Platinum Catalysts for the Water-Gas Shift Reaction: The Influence of Support Composition

AU - Gorlova, A. M.

AU - Pakharukova, V. P.

AU - Stonkus, O. A.

AU - Rogozhnikov, V. N.

AU - Gladky, A. Y.

AU - Snytnikov, P. V.

AU - Potemkin, D. I.

N1 - This work was supported by Russian Science Foundation under the project no. 21-73-20075 (А.М. Gorlova, V.P. Pakharukova, О.А. Stonkus, V.N. Rogozhnikov).

PY - 2023/8

Y1 - 2023/8

N2 - The study is presented on the influence of the composition of a ceria-zirconia support on the structure and the activity in water-gas shift reaction of platinum catalysts (Pt/Ce0.75Zr0.25O2 and Pt/Ce0.4Zr0.5Y0.05La0.05O2). The structure diagnostics of the samples were performed using high-resolution transmission electron microscopy, powder X-ray diffraction, CO chemisorption and X-ray atomic pair distribution function method. It was shown that the catalysts contain highly dispersed platinum particles not exceeding 2 nm in size. Platinum particles supported on Ce0.75Zr0.25O2 are smaller due to the higher specific surface area of the support. The catalysts Pt/Ce0.75Zr0.25O2 and Pt/Ce0.4Zr0.5Y0.05La0.05O2 proved to have similar efficiency while having the same platinum content. It was assumed that the catalysts supported on Ce0.4Zr0.5Y0.05La0.05O2 demonstrate a slightly higher turnover frequency per platinum surface atom, but it is likely compensated by the difference in the supported metal particle size.

AB - The study is presented on the influence of the composition of a ceria-zirconia support on the structure and the activity in water-gas shift reaction of platinum catalysts (Pt/Ce0.75Zr0.25O2 and Pt/Ce0.4Zr0.5Y0.05La0.05O2). The structure diagnostics of the samples were performed using high-resolution transmission electron microscopy, powder X-ray diffraction, CO chemisorption and X-ray atomic pair distribution function method. It was shown that the catalysts contain highly dispersed platinum particles not exceeding 2 nm in size. Platinum particles supported on Ce0.75Zr0.25O2 are smaller due to the higher specific surface area of the support. The catalysts Pt/Ce0.75Zr0.25O2 and Pt/Ce0.4Zr0.5Y0.05La0.05O2 proved to have similar efficiency while having the same platinum content. It was assumed that the catalysts supported on Ce0.4Zr0.5Y0.05La0.05O2 demonstrate a slightly higher turnover frequency per platinum surface atom, but it is likely compensated by the difference in the supported metal particle size.

KW - ceria-zirconia

KW - hydrogen purification

KW - platinum catalyst

KW - water-gas shift

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85165612003&origin=inward&txGid=02efa881dfcc0973be0ded77cef3d5e1

UR - https://www.mendeley.com/catalogue/d55b85fc-9dbb-337c-858b-695602a4fe8b/

U2 - 10.1134/S0023158423040031

DO - 10.1134/S0023158423040031

M3 - Article

VL - 64

SP - 449

EP - 457

JO - Kinetics and Catalysis

JF - Kinetics and Catalysis

SN - 0023-1584

IS - 4

ER -

ID: 54072786