Research output: Contribution to journal › Article › peer-review
Ceramic matrix composites prepared from CoAl powders. / Tikhov, S. F.; Andreev, A. S.; Salanov, A. N. et al.
In: Journal of Materials Science, Vol. 51, No. 23, 01.12.2016, p. 10487-10498.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Ceramic matrix composites prepared from CoAl powders
AU - Tikhov, S. F.
AU - Andreev, A. S.
AU - Salanov, A. N.
AU - Cherepanova, S. V.
AU - Lapina, O. B.
AU - Sadykov, V. A.
AU - Tanashev, Yu Yu
AU - Bolotov, V. A.
PY - 2016/12/1
Y1 - 2016/12/1
N2 - Multiscale structure of two CoxAlyOz cermets was examined by a combination of XRD, SEM coupled with EDX, NMR (59Co; 27Al), and textural measurements. A strong CoAlO/CoAl cermet monolith prepared by mechanical alloying of Co and Al powders followed by hydrothermal treatment and calcination in air comprised two parts: the metal core consisting of Co and a Co–Al alloy, and the outer oxide matrix including a mixture of CoxAl3–xO4 spinel and cobalt oxides. The two parts were separated by the alumina interface protecting the metal core against the oxidation. Al2O3/CoAlO/CoAl cermet prepared by mixing the Co–Al mechanically alloyed product and pure aluminum hydroxide with subsequent hydrothermal treatment and calcination in air consisted of three main parts: (i) large cobalt-free porous alumina (ii) surrounded by CoxAl3–xO4 spinel oxides, and (iii) the inner core containing pure Co metal particles covered with the Co–Al alloy. A random distribution of metal particles in the oxide matrix provided an enhanced microwave absorption. A developed porosity ensured a high activity of the catalyst prepared from the porous cermet in the hexane dehydrogenation under microwave heating.
AB - Multiscale structure of two CoxAlyOz cermets was examined by a combination of XRD, SEM coupled with EDX, NMR (59Co; 27Al), and textural measurements. A strong CoAlO/CoAl cermet monolith prepared by mechanical alloying of Co and Al powders followed by hydrothermal treatment and calcination in air comprised two parts: the metal core consisting of Co and a Co–Al alloy, and the outer oxide matrix including a mixture of CoxAl3–xO4 spinel and cobalt oxides. The two parts were separated by the alumina interface protecting the metal core against the oxidation. Al2O3/CoAlO/CoAl cermet prepared by mixing the Co–Al mechanically alloyed product and pure aluminum hydroxide with subsequent hydrothermal treatment and calcination in air consisted of three main parts: (i) large cobalt-free porous alumina (ii) surrounded by CoxAl3–xO4 spinel oxides, and (iii) the inner core containing pure Co metal particles covered with the Co–Al alloy. A random distribution of metal particles in the oxide matrix provided an enhanced microwave absorption. A developed porosity ensured a high activity of the catalyst prepared from the porous cermet in the hexane dehydrogenation under microwave heating.
UR - http://www.scopus.com/inward/record.url?scp=84982993390&partnerID=8YFLogxK
U2 - 10.1007/s10853-016-0268-y
DO - 10.1007/s10853-016-0268-y
M3 - Article
AN - SCOPUS:84982993390
VL - 51
SP - 10487
EP - 10498
JO - Journal of Materials Science
JF - Journal of Materials Science
SN - 0022-2461
IS - 23
ER -
ID: 25394819