Standard

Cationic acetylacetonate palladium complexes/boron trifluoride etherate catalyst systems for polymerization of 5-methoxycarbonylnorbornene. / Suslov, D. S.; Bykov, M. V.; Kuzmin, A. V. et al.

In: Catalysis Communications, Vol. 106, 05.03.2018, p. 30-35.

Research output: Contribution to journal › Article › peer-review

Harvard

Suslov, DS, Bykov, MV, Kuzmin, AV, Abramov, PA, Kravchenko, OV, Pakhomova, MV, Rokhin, AV, Ushakov, IA & Tkach, VS 2018, 'Cationic acetylacetonate palladium complexes/boron trifluoride etherate catalyst systems for polymerization of 5-methoxycarbonylnorbornene', Catalysis Communications, vol. 106, pp. 30-35. https://doi.org/10.1016/j.catcom.2017.12.010

APA

Suslov, D. S., Bykov, M. V., Kuzmin, A. V., Abramov, P. A., Kravchenko, O. V., Pakhomova, M. V., Rokhin, A. V., Ushakov, I. A., & Tkach, V. S. (2018). Cationic acetylacetonate palladium complexes/boron trifluoride etherate catalyst systems for polymerization of 5-methoxycarbonylnorbornene. Catalysis Communications, 106, 30-35. https://doi.org/10.1016/j.catcom.2017.12.010

Vancouver

Suslov DS, Bykov MV, Kuzmin AV, Abramov PA, Kravchenko OV, Pakhomova MV et al. Cationic acetylacetonate palladium complexes/boron trifluoride etherate catalyst systems for polymerization of 5-methoxycarbonylnorbornene. Catalysis Communications. 2018 Mar 5;106:30-35. doi: 10.1016/j.catcom.2017.12.010

Author

Suslov, D. S. ; Bykov, M. V. ; Kuzmin, A. V. et al. / Cationic acetylacetonate palladium complexes/boron trifluoride etherate catalyst systems for polymerization of 5-methoxycarbonylnorbornene. In: Catalysis Communications. 2018 ; Vol. 106. pp. 30-35.

BibTeX

@article{c4ef44cdb15843e7b733de6eaa62be2a,
title = "Cationic acetylacetonate palladium complexes/boron trifluoride etherate catalyst systems for polymerization of 5-methoxycarbonylnorbornene",
abstract = "A simple protocol using cationic acetylacetonate palladium complexes with mono-/bidentate phosphine ligands activated with BF3·OEt2 as in situ-formed catalyst for polymerization of endo/exo mixture of 5-methoxycarbonylnorbornene (activity up to 1.1·104 g mol− 1 h− 1) or 5-phenylnorbornene (7.2·105 g mol− 1 h− 1), and norbornene (3.3·108 g mol− 1 h− 1) have been developed. It was observed that the ligands nature strongly influence the catalytic activity. The catalyst system Pd(II)/BF3·OEt2 was also active for the copolymerization of norbornene with 5-methoxycarbonylnorbornene. DFT calculations of isomers upon single insertion of 5-methoxycarbonylnorbornene into Pd–H bond and NMR/FTIR studies for pre-catalyst activation mechanism were performed.",
keywords = "Acetylacetonate, Norbornene, Palladium, Phosphines, Polymerization, NITROGEN BASES, KETONES, NORBORNENE, LIGANDS, METAL, HOMOPOLYMERIZATION, COPOLYMERIZATION, DERIVATIVES",
author = "Suslov, {D. S.} and Bykov, {M. V.} and Kuzmin, {A. V.} and Abramov, {P. A.} and Kravchenko, {O. V.} and Pakhomova, {M. V.} and Rokhin, {A. V.} and Ushakov, {I. A.} and Tkach, {V. S.}",
note = "Publisher Copyright: {\textcopyright} 2017 Elsevier B.V.",
year = "2018",
month = mar,
day = "5",
doi = "10.1016/j.catcom.2017.12.010",
language = "English",
volume = "106",
pages = "30--35",
journal = "Catalysis Communications",
issn = "1566-7367",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Cationic acetylacetonate palladium complexes/boron trifluoride etherate catalyst systems for polymerization of 5-methoxycarbonylnorbornene

AU - Suslov, D. S.

AU - Bykov, M. V.

AU - Kuzmin, A. V.

AU - Abramov, P. A.

AU - Kravchenko, O. V.

AU - Pakhomova, M. V.

AU - Rokhin, A. V.

AU - Ushakov, I. A.

AU - Tkach, V. S.

N1 - Publisher Copyright: © 2017 Elsevier B.V.

PY - 2018/3/5

Y1 - 2018/3/5

N2 - A simple protocol using cationic acetylacetonate palladium complexes with mono-/bidentate phosphine ligands activated with BF3·OEt2 as in situ-formed catalyst for polymerization of endo/exo mixture of 5-methoxycarbonylnorbornene (activity up to 1.1·104 g mol− 1 h− 1) or 5-phenylnorbornene (7.2·105 g mol− 1 h− 1), and norbornene (3.3·108 g mol− 1 h− 1) have been developed. It was observed that the ligands nature strongly influence the catalytic activity. The catalyst system Pd(II)/BF3·OEt2 was also active for the copolymerization of norbornene with 5-methoxycarbonylnorbornene. DFT calculations of isomers upon single insertion of 5-methoxycarbonylnorbornene into Pd–H bond and NMR/FTIR studies for pre-catalyst activation mechanism were performed.

AB - A simple protocol using cationic acetylacetonate palladium complexes with mono-/bidentate phosphine ligands activated with BF3·OEt2 as in situ-formed catalyst for polymerization of endo/exo mixture of 5-methoxycarbonylnorbornene (activity up to 1.1·104 g mol− 1 h− 1) or 5-phenylnorbornene (7.2·105 g mol− 1 h− 1), and norbornene (3.3·108 g mol− 1 h− 1) have been developed. It was observed that the ligands nature strongly influence the catalytic activity. The catalyst system Pd(II)/BF3·OEt2 was also active for the copolymerization of norbornene with 5-methoxycarbonylnorbornene. DFT calculations of isomers upon single insertion of 5-methoxycarbonylnorbornene into Pd–H bond and NMR/FTIR studies for pre-catalyst activation mechanism were performed.

KW - Acetylacetonate

KW - Norbornene

KW - Palladium

KW - Phosphines

KW - Polymerization

KW - NITROGEN BASES

KW - KETONES

KW - NORBORNENE

KW - LIGANDS

KW - METAL

KW - HOMOPOLYMERIZATION

KW - COPOLYMERIZATION

KW - DERIVATIVES

UR - http://www.scopus.com/inward/record.url?scp=85039419428&partnerID=8YFLogxK

U2 - 10.1016/j.catcom.2017.12.010

DO - 10.1016/j.catcom.2017.12.010

M3 - Article

AN - SCOPUS:85039419428

VL - 106

SP - 30

EP - 35

JO - Catalysis Communications

JF - Catalysis Communications

SN - 1566-7367

ER -

ID: 9156011