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Cationic acetylacetonate palladium complexes/boron trifluoride etherate catalyst systems for hydroamination of vinylarenes using arylamines. / Suslov, D. S.; Bykov, M. V.; Pakhomova, M. V. et al.

In: Catalysis Communications, Vol. 94, 05.05.2017, p. 69-72.

Research output: Contribution to journal › Article › peer-review

Harvard

Suslov, DS, Bykov, MV, Pakhomova, MV, Abramov, PA, Ushakov, IA & Tkach, VS 2017, 'Cationic acetylacetonate palladium complexes/boron trifluoride etherate catalyst systems for hydroamination of vinylarenes using arylamines', Catalysis Communications, vol. 94, pp. 69-72. https://doi.org/10.1016/j.catcom.2017.02.004

APA

Suslov, D. S., Bykov, M. V., Pakhomova, M. V., Abramov, P. A., Ushakov, I. A., & Tkach, V. S. (2017). Cationic acetylacetonate palladium complexes/boron trifluoride etherate catalyst systems for hydroamination of vinylarenes using arylamines. Catalysis Communications, 94, 69-72. https://doi.org/10.1016/j.catcom.2017.02.004

Vancouver

Suslov DS, Bykov MV, Pakhomova MV, Abramov PA, Ushakov IA, Tkach VS. Cationic acetylacetonate palladium complexes/boron trifluoride etherate catalyst systems for hydroamination of vinylarenes using arylamines. Catalysis Communications. 2017 May 5;94:69-72. doi: 10.1016/j.catcom.2017.02.004

Author

Suslov, D. S. ; Bykov, M. V. ; Pakhomova, M. V. et al. / Cationic acetylacetonate palladium complexes/boron trifluoride etherate catalyst systems for hydroamination of vinylarenes using arylamines. In: Catalysis Communications. 2017 ; Vol. 94. pp. 69-72.

BibTeX

@article{961b280697d64409999b45028069e31d,
title = "Cationic acetylacetonate palladium complexes/boron trifluoride etherate catalyst systems for hydroamination of vinylarenes using arylamines",
abstract = "A simple and solvent-free protocol using cationic acetylacetonate palladium complexes with mono-/bidentate phosphine ligands activated with BF3·OEt2as in situ-formed catalyst for hydroamination of vinylarenes with arylamines have been developed. Excellent catalytic activities were obtained using [Pd(acac)(PPh3)2][BF4]/BF3·OEt2/i-PrOH catalyst system with the addition of a small amount of palladium (0.2–0.05 mol%) to the reaction mixture. Furthermore, the novel unexpected diphosphine-bridged palladium complexes have been prepared and characterized: [Pd(acac)(dpppt)]2[BF4]2and [Pd(acac)(dpph)]2[BF4]2(dpppt – 1,5-bis(diphenylphosphino)pentane, dpph – 1,6-bis(diphenylphosphino)hexane)",
keywords = "Acetylacetonate, Aniline, Hydroamination, Palladium, Styrene, AMINATION, PHOSPHINE, METAL",
author = "Suslov, {D. S.} and Bykov, {M. V.} and Pakhomova, {M. V.} and Abramov, {P. A.} and Ushakov, {I. A.} and Tkach, {V. S.}",
note = "Publisher Copyright: {\textcopyright} 2017 Elsevier B.V.",
year = "2017",
month = may,
day = "5",
doi = "10.1016/j.catcom.2017.02.004",
language = "English",
volume = "94",
pages = "69--72",
journal = "Catalysis Communications",
issn = "1566-7367",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Cationic acetylacetonate palladium complexes/boron trifluoride etherate catalyst systems for hydroamination of vinylarenes using arylamines

AU - Suslov, D. S.

AU - Bykov, M. V.

AU - Pakhomova, M. V.

AU - Abramov, P. A.

AU - Ushakov, I. A.

AU - Tkach, V. S.

N1 - Publisher Copyright: © 2017 Elsevier B.V.

PY - 2017/5/5

Y1 - 2017/5/5

N2 - A simple and solvent-free protocol using cationic acetylacetonate palladium complexes with mono-/bidentate phosphine ligands activated with BF3·OEt2as in situ-formed catalyst for hydroamination of vinylarenes with arylamines have been developed. Excellent catalytic activities were obtained using [Pd(acac)(PPh3)2][BF4]/BF3·OEt2/i-PrOH catalyst system with the addition of a small amount of palladium (0.2–0.05 mol%) to the reaction mixture. Furthermore, the novel unexpected diphosphine-bridged palladium complexes have been prepared and characterized: [Pd(acac)(dpppt)]2[BF4]2and [Pd(acac)(dpph)]2[BF4]2(dpppt – 1,5-bis(diphenylphosphino)pentane, dpph – 1,6-bis(diphenylphosphino)hexane)

AB - A simple and solvent-free protocol using cationic acetylacetonate palladium complexes with mono-/bidentate phosphine ligands activated with BF3·OEt2as in situ-formed catalyst for hydroamination of vinylarenes with arylamines have been developed. Excellent catalytic activities were obtained using [Pd(acac)(PPh3)2][BF4]/BF3·OEt2/i-PrOH catalyst system with the addition of a small amount of palladium (0.2–0.05 mol%) to the reaction mixture. Furthermore, the novel unexpected diphosphine-bridged palladium complexes have been prepared and characterized: [Pd(acac)(dpppt)]2[BF4]2and [Pd(acac)(dpph)]2[BF4]2(dpppt – 1,5-bis(diphenylphosphino)pentane, dpph – 1,6-bis(diphenylphosphino)hexane)

KW - Acetylacetonate

KW - Aniline

KW - Hydroamination

KW - Palladium

KW - Styrene

KW - AMINATION

KW - PHOSPHINE

KW - METAL

UR - http://www.scopus.com/inward/record.url?scp=85014052272&partnerID=8YFLogxK

U2 - 10.1016/j.catcom.2017.02.004

DO - 10.1016/j.catcom.2017.02.004

M3 - Article

AN - SCOPUS:85014052272

VL - 94

SP - 69

EP - 72

JO - Catalysis Communications

JF - Catalysis Communications

SN - 1566-7367

ER -

ID: 10277951