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Capture of nitrogen dioxide and conversion to nitric acid in a porous metal–organic framework. / Li, Jiangnan; Han, Xue; Zhang, Xinran et al.

In: Nature Chemistry, Vol. 11, No. 12, 01.12.2019, p. 1085-1090.

Research output: Contribution to journal › Article › peer-review

Harvard

Li, J, Han, X, Zhang, X, Sheveleva, AM, Cheng, Y, Tuna, F, McInnes, EJL, McCormick McPherson, LJ, Teat, SJ, Daemen, LL, Ramirez-Cuesta, AJ, Schröder, M & Yang, S 2019, 'Capture of nitrogen dioxide and conversion to nitric acid in a porous metal–organic framework', Nature Chemistry, vol. 11, no. 12, pp. 1085-1090. https://doi.org/10.1038/s41557-019-0356-0

APA

Li, J., Han, X., Zhang, X., Sheveleva, A. M., Cheng, Y., Tuna, F., McInnes, E. J. L., McCormick McPherson, L. J., Teat, S. J., Daemen, L. L., Ramirez-Cuesta, A. J., Schröder, M., & Yang, S. (2019). Capture of nitrogen dioxide and conversion to nitric acid in a porous metal–organic framework. Nature Chemistry, 11(12), 1085-1090. https://doi.org/10.1038/s41557-019-0356-0

Vancouver

Li J, Han X, Zhang X, Sheveleva AM, Cheng Y, Tuna F et al. Capture of nitrogen dioxide and conversion to nitric acid in a porous metal–organic framework. Nature Chemistry. 2019 Dec 1;11(12):1085-1090. doi: 10.1038/s41557-019-0356-0

Author

Li, Jiangnan ; Han, Xue ; Zhang, Xinran et al. / Capture of nitrogen dioxide and conversion to nitric acid in a porous metal–organic framework. In: Nature Chemistry. 2019 ; Vol. 11, No. 12. pp. 1085-1090.

BibTeX

@article{c385645e1ec94f69a9c95287a5752113,
title = "Capture of nitrogen dioxide and conversion to nitric acid in a porous metal–organic framework",
abstract = "Air pollution by nitrogen oxides, NOx, is a major problem, and new capture and abatement technologies are urgently required. Here, we report a metal–organic framework (Manchester Framework Material 520 (MFM-520)) that can efficiently confine dimers of NO2, which results in a high adsorption capacity of 4.2 mmol g–1 (298 K, 0.01 bar) with full reversibility and no loss of capacity over 125 cycles. Treatment of NO2@MFM-520 with water in air leads to a quantitative conversion of the captured NO2 into HNO3, an important feedstock for fertilizer production, and fully regenerates MFM-520. The confinement of N2O4 inside nanopores was established at a molecular level, and the dynamic breakthrough experiments using both dry and humid NO2 gas streams verify the excellent stability and selectivity of MFM-520 and confirm its potential for precious-metal-free deNOx technologies.",
author = "Jiangnan Li and Xue Han and Xinran Zhang and Sheveleva, {Alena M.} and Yongqiang Cheng and Floriana Tuna and McInnes, {Eric J.L.} and {McCormick McPherson}, {Laura J.} and Teat, {Simon J.} and Daemen, {Luke L.} and Ramirez-Cuesta, {Anibal J.} and Martin Schr{\"o}der and Sihai Yang",
year = "2019",
month = dec,
day = "1",
doi = "10.1038/s41557-019-0356-0",
language = "English",
volume = "11",
pages = "1085--1090",
journal = "Nature Chemistry",
issn = "1755-4330",
publisher = "Nature Publishing Group",
number = "12",

}

RIS

TY - JOUR

T1 - Capture of nitrogen dioxide and conversion to nitric acid in a porous metal–organic framework

AU - Li, Jiangnan

AU - Han, Xue

AU - Zhang, Xinran

AU - Sheveleva, Alena M.

AU - Cheng, Yongqiang

AU - Tuna, Floriana

AU - McInnes, Eric J.L.

AU - McCormick McPherson, Laura J.

AU - Teat, Simon J.

AU - Daemen, Luke L.

AU - Ramirez-Cuesta, Anibal J.

AU - Schröder, Martin

AU - Yang, Sihai

PY - 2019/12/1

Y1 - 2019/12/1

N2 - Air pollution by nitrogen oxides, NOx, is a major problem, and new capture and abatement technologies are urgently required. Here, we report a metal–organic framework (Manchester Framework Material 520 (MFM-520)) that can efficiently confine dimers of NO2, which results in a high adsorption capacity of 4.2 mmol g–1 (298 K, 0.01 bar) with full reversibility and no loss of capacity over 125 cycles. Treatment of NO2@MFM-520 with water in air leads to a quantitative conversion of the captured NO2 into HNO3, an important feedstock for fertilizer production, and fully regenerates MFM-520. The confinement of N2O4 inside nanopores was established at a molecular level, and the dynamic breakthrough experiments using both dry and humid NO2 gas streams verify the excellent stability and selectivity of MFM-520 and confirm its potential for precious-metal-free deNOx technologies.

AB - Air pollution by nitrogen oxides, NOx, is a major problem, and new capture and abatement technologies are urgently required. Here, we report a metal–organic framework (Manchester Framework Material 520 (MFM-520)) that can efficiently confine dimers of NO2, which results in a high adsorption capacity of 4.2 mmol g–1 (298 K, 0.01 bar) with full reversibility and no loss of capacity over 125 cycles. Treatment of NO2@MFM-520 with water in air leads to a quantitative conversion of the captured NO2 into HNO3, an important feedstock for fertilizer production, and fully regenerates MFM-520. The confinement of N2O4 inside nanopores was established at a molecular level, and the dynamic breakthrough experiments using both dry and humid NO2 gas streams verify the excellent stability and selectivity of MFM-520 and confirm its potential for precious-metal-free deNOx technologies.

UR - http://www.scopus.com/inward/record.url?scp=85075512193&partnerID=8YFLogxK

U2 - 10.1038/s41557-019-0356-0

DO - 10.1038/s41557-019-0356-0

M3 - Article

C2 - 31758160

AN - SCOPUS:85075512193

VL - 11

SP - 1085

EP - 1090

JO - Nature Chemistry

JF - Nature Chemistry

SN - 1755-4330

IS - 12

ER -

ID: 22404453