Calibration of the goniometer equatorial circumference and the refinement of unit cell parameters of [Pt(NH3)4]MO4 (М = Cr, Mo, W)

Standard

Calibration of the goniometer equatorial circumference and the refinement of unit cell parameters of [Pt(NH₃)₄]MO₄ (М = Cr, Mo, W). / Serebrennikova, P. S.; Gromilov, S. A.

In: Journal of Structural Chemistry, Vol. 63, No. 11, 11.2022, p. 1820-1830.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{6c4fdc358f1f4286823433f156ac82f6,

title = "Calibration of the goniometer equatorial circumference and the refinement of unit cell parameters of [Pt(NH3)4]MO4 (М = Cr, Mo, W)",

abstract = "A calibration procedure for the three-circle goniometer/2D detector system is described. It is based on the construction of calibration graphs Δ2θ(2θ) from the results of processing Kα1 and Kα2 components of external reference reflections successively brought to the equatorial circumference. A Si single crystal is used as the reference. Random errors are estimated. Results of the refinement of unit cell parameters of [Pt(NH3)4]MO4 (М = Cr, Mo, W) are compared by several procedures, including the obtained calibration. The relative error of the performed measurements does not exceed 2·10–4.",

keywords = "accuracy, single crystal X-ray diffraction, unit cell parameters",

author = "Serebrennikova, {P. S.} and Gromilov, {S. A.}",

note = "Funding Information: The work was supported by the Ministry of Science and Higher Education (project No. 121031700313-8) and Priority 2030. Funding Information: The authors are thankful to V. I. Lagunova for kindly provided samples of [Pt(NH)]MO (М = Cr, Mo, W). (The work was supported by Russian Science Foundation grant No. 22-23-00672). 3 4 4 Publisher Copyright: {\textcopyright} 2022, Pleiades Publishing, Ltd.",

year = "2022",

month = nov,

doi = "10.1134/S0022476622110129",

language = "English",

volume = "63",

pages = "1820--1830",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "11",

}

RIS

TY - JOUR

T1 - Calibration of the goniometer equatorial circumference and the refinement of unit cell parameters of [Pt(NH3)4]MO4 (М = Cr, Mo, W)

AU - Serebrennikova, P. S.

AU - Gromilov, S. A.

N1 - Funding Information: The work was supported by the Ministry of Science and Higher Education (project No. 121031700313-8) and Priority 2030. Funding Information: The authors are thankful to V. I. Lagunova for kindly provided samples of [Pt(NH)]MO (М = Cr, Mo, W). (The work was supported by Russian Science Foundation grant No. 22-23-00672). 3 4 4 Publisher Copyright: © 2022, Pleiades Publishing, Ltd.

PY - 2022/11

Y1 - 2022/11

N2 - A calibration procedure for the three-circle goniometer/2D detector system is described. It is based on the construction of calibration graphs Δ2θ(2θ) from the results of processing Kα1 and Kα2 components of external reference reflections successively brought to the equatorial circumference. A Si single crystal is used as the reference. Random errors are estimated. Results of the refinement of unit cell parameters of [Pt(NH3)4]MO4 (М = Cr, Mo, W) are compared by several procedures, including the obtained calibration. The relative error of the performed measurements does not exceed 2·10–4.

AB - A calibration procedure for the three-circle goniometer/2D detector system is described. It is based on the construction of calibration graphs Δ2θ(2θ) from the results of processing Kα1 and Kα2 components of external reference reflections successively brought to the equatorial circumference. A Si single crystal is used as the reference. Random errors are estimated. Results of the refinement of unit cell parameters of [Pt(NH3)4]MO4 (М = Cr, Mo, W) are compared by several procedures, including the obtained calibration. The relative error of the performed measurements does not exceed 2·10–4.

KW - accuracy

KW - single crystal X-ray diffraction

KW - unit cell parameters

UR - http://www.scopus.com/inward/record.url?scp=85143535658&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/25fe686c-cd91-3b62-9b68-95ad158921cc/

U2 - 10.1134/S0022476622110129

DO - 10.1134/S0022476622110129

M3 - Article

AN - SCOPUS:85143535658

VL - 63

SP - 1820

EP - 1830

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 11

ER -

ID: 40503015