Cadmium coordination compounds with flexible ligand 1,3-bis(1,2,4-triazol-1-yl)propane: Synthesis, structure and luminescent properties

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Cadmium coordination compounds with flexible ligand 1,3-bis(1,2,4-triazol-1-yl)propane: Synthesis, structure and luminescent properties. / Smirnova, Ksenia S.; Lider, Elizaveta V.; Sukhikh, Taisiya S. et al.

In: Polyhedron, Vol. 177, 114286, 01.02.2020.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{581b3453c0284f3dac6ffbe49d4a89b7,

title = "Cadmium coordination compounds with flexible ligand 1,3-bis(1,2,4-triazol-1-yl)propane: Synthesis, structure and luminescent properties",

abstract = "Six new cadmium coordination compounds with flexible 1,3-bis(1,2,4-triazol-1-yl)propane (btrp) ligand, [Cd(btrp)(H2O)2(NO3)2]n (1), [Cd(btrp)2(NO3)2]·H2O (2), [Cd(btrp)Hal2] (3–5) (Hal = Cl, Br, I) and [Cd2(btrp)2(DMF)2(μ2-Br)2Br2] (6) were synthesized. The crystal structures of the complexes 1 and 6 were determined. 1 has 1D polymeric structure while 6 is binuclear. The latter reveals rare gauche–gauche conformation of btrp ligand. Luminescent properties of 1–6 in the solid state were studied in comparison with free btrp. The emission of the compounds corresponds to intraligand transitions, while the bands exhibit complicated shape that can be described by two Gauss functions.",

keywords = "1,3-Bis(1,2,4-triazol-1-yl)propane, Binuclear compound, Cadmium complexes, Coordination polymer, Multidentate N-donor ligand, Photoluminescence, POLYMERS, 1,2,4-TRIAZOLE COMPLEXES, CD(II), CU(II), CRYSTAL-STRUCTURES, CHAIN, PHOTOLUMINESCENT, FLUORESCENT PROPERTIES, MAGNETIC-PROPERTIES, METAL-COMPLEXES",

author = "Smirnova, {Ksenia S.} and Lider, {Elizaveta V.} and Sukhikh, {Taisiya S.} and Berezin, {Alexey S.} and Potapov, {Andrei S.}",

note = "Funding Information: This work was supported by the Russian Science Foundation (Project № 18-73-00294 ). The authors thank to workers from Nikolaev Institute of Inorganic Chemistry, namely Anna P. Zubareva and Valentina V. Ankudovich for the elemental analysis, Nina I. Alferova and Liliya A. Sheludyakova for the IR spectroscopy data, Ilya V. Korolkov for the X-ray phase analysis data and wish to express our gratitude to Svetlana V. Makarova from Institute of Solid State Chemistry and Mechanochemistry for scanning electron microscope data. Appendix A Publisher Copyright: {\textcopyright} 2019 Elsevier Ltd",

year = "2020",

month = feb,

day = "1",

doi = "10.1016/j.poly.2019.114286",

language = "English",

volume = "177",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Cadmium coordination compounds with flexible ligand 1,3-bis(1,2,4-triazol-1-yl)propane: Synthesis, structure and luminescent properties

AU - Smirnova, Ksenia S.

AU - Lider, Elizaveta V.

AU - Sukhikh, Taisiya S.

AU - Berezin, Alexey S.

AU - Potapov, Andrei S.

N1 - Funding Information: This work was supported by the Russian Science Foundation (Project № 18-73-00294 ). The authors thank to workers from Nikolaev Institute of Inorganic Chemistry, namely Anna P. Zubareva and Valentina V. Ankudovich for the elemental analysis, Nina I. Alferova and Liliya A. Sheludyakova for the IR spectroscopy data, Ilya V. Korolkov for the X-ray phase analysis data and wish to express our gratitude to Svetlana V. Makarova from Institute of Solid State Chemistry and Mechanochemistry for scanning electron microscope data. Appendix A Publisher Copyright: © 2019 Elsevier Ltd

PY - 2020/2/1

Y1 - 2020/2/1

N2 - Six new cadmium coordination compounds with flexible 1,3-bis(1,2,4-triazol-1-yl)propane (btrp) ligand, [Cd(btrp)(H2O)2(NO3)2]n (1), [Cd(btrp)2(NO3)2]·H2O (2), [Cd(btrp)Hal2] (3–5) (Hal = Cl, Br, I) and [Cd2(btrp)2(DMF)2(μ2-Br)2Br2] (6) were synthesized. The crystal structures of the complexes 1 and 6 were determined. 1 has 1D polymeric structure while 6 is binuclear. The latter reveals rare gauche–gauche conformation of btrp ligand. Luminescent properties of 1–6 in the solid state were studied in comparison with free btrp. The emission of the compounds corresponds to intraligand transitions, while the bands exhibit complicated shape that can be described by two Gauss functions.

AB - Six new cadmium coordination compounds with flexible 1,3-bis(1,2,4-triazol-1-yl)propane (btrp) ligand, [Cd(btrp)(H2O)2(NO3)2]n (1), [Cd(btrp)2(NO3)2]·H2O (2), [Cd(btrp)Hal2] (3–5) (Hal = Cl, Br, I) and [Cd2(btrp)2(DMF)2(μ2-Br)2Br2] (6) were synthesized. The crystal structures of the complexes 1 and 6 were determined. 1 has 1D polymeric structure while 6 is binuclear. The latter reveals rare gauche–gauche conformation of btrp ligand. Luminescent properties of 1–6 in the solid state were studied in comparison with free btrp. The emission of the compounds corresponds to intraligand transitions, while the bands exhibit complicated shape that can be described by two Gauss functions.

KW - 1,3-Bis(1,2,4-triazol-1-yl)propane

KW - Binuclear compound

KW - Cadmium complexes

KW - Coordination polymer

KW - Multidentate N-donor ligand

KW - Photoluminescence

KW - POLYMERS

KW - 1,2,4-TRIAZOLE COMPLEXES

KW - CD(II)

KW - CU(II)

KW - CRYSTAL-STRUCTURES

KW - CHAIN

KW - PHOTOLUMINESCENT

KW - FLUORESCENT PROPERTIES

KW - MAGNETIC-PROPERTIES

KW - METAL-COMPLEXES

UR - http://www.scopus.com/inward/record.url?scp=85076928970&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2019.114286

DO - 10.1016/j.poly.2019.114286

M3 - Article

AN - SCOPUS:85076928970

VL - 177

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

M1 - 114286

ER -

ID: 22992799