Research output: Contribution to journal › Article › peer-review
Bromine-rich complexes of bismuth : Experimental and theoretical studies. / Adonin, Sergey A.; Gorokh, Igor D.; Novikov, Alexander S. et al.
In: Dalton Transactions, Vol. 47, No. 8, 28.02.2018, p. 2683-2689.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Bromine-rich complexes of bismuth
T2 - Experimental and theoretical studies
AU - Adonin, Sergey A.
AU - Gorokh, Igor D.
AU - Novikov, Alexander S.
AU - Samsonenko, Denis G.
AU - Plyusnin, Pavel E.
AU - Sokolov, Maxim N.
AU - Fedin, Vladimir P.
N1 - Publisher Copyright: © 2018 The Royal Society of Chemistry.
PY - 2018/2/28
Y1 - 2018/2/28
N2 - Three novel polybromide complexes of bismuth(iii)-(2,6-MePyH)3[BiBr5(Br3)] (1), (H2bpp){[BiBr5](Br2)} (2) and (3-ClPyH)2{[BiBr5](Br2)} (3)-were synthesized. The results of an extended screening involving a set of organic cations resulting in the formation/non-formation of Bi(iii) polybromides are presented and discussed. The nature of Br⋯Br interactions in Bi(iii) polybromides was investigated by theoretical methods, enabling the estimation of their energies.
AB - Three novel polybromide complexes of bismuth(iii)-(2,6-MePyH)3[BiBr5(Br3)] (1), (H2bpp){[BiBr5](Br2)} (2) and (3-ClPyH)2{[BiBr5](Br2)} (3)-were synthesized. The results of an extended screening involving a set of organic cations resulting in the formation/non-formation of Bi(iii) polybromides are presented and discussed. The nature of Br⋯Br interactions in Bi(iii) polybromides was investigated by theoretical methods, enabling the estimation of their energies.
KW - TEMPERATURE IONIC LIQUID
KW - ZETA BASIS-SETS
KW - CRYSTAL-STRUCTURE
KW - PHENYLTRIMETHYLAMMONIUM SALTS
KW - NONCOVALENT INTERACTIONS
KW - CENTER-DOT
KW - HALOGEN
KW - NETWORKS
KW - NONABROMOANTIMONATE(V)
KW - POLYBROMIDES
UR - http://www.scopus.com/inward/record.url?scp=85042376329&partnerID=8YFLogxK
U2 - 10.1039/c7dt04779g
DO - 10.1039/c7dt04779g
M3 - Article
C2 - 29410985
AN - SCOPUS:85042376329
VL - 47
SP - 2683
EP - 2689
JO - Dalton Transactions
JF - Dalton Transactions
SN - 1477-9226
IS - 8
ER -
ID: 10426265