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Blocking {RhCl}2+ disorder in the crystal structure of a [SiW11O39{RhCl}]6− salt : Direct localization of the heterometal in a monosubstituted Keggin anion. / Mukhacheva, Anna A.; Volchek, Victoria V.; Abramov, Pavel A. et al.

In: Inorganic Chemistry Communications, Vol. 89, 01.03.2018, p. 10-12.

Research output: Contribution to journal › Article › peer-review

Harvard

Mukhacheva, AA, Volchek, VV, Abramov, PA & Sokolov, MN 2018, 'Blocking {RhCl}2+ disorder in the crystal structure of a [SiW11O39{RhCl}]6− salt: Direct localization of the heterometal in a monosubstituted Keggin anion', Inorganic Chemistry Communications, vol. 89, pp. 10-12. https://doi.org/10.1016/j.inoche.2018.01.001

APA

Mukhacheva, A. A., Volchek, V. V., Abramov, P. A., & Sokolov, M. N. (2018). Blocking {RhCl}2+ disorder in the crystal structure of a [SiW11O39{RhCl}]6− salt: Direct localization of the heterometal in a monosubstituted Keggin anion. Inorganic Chemistry Communications, 89, 10-12. https://doi.org/10.1016/j.inoche.2018.01.001

Vancouver

Mukhacheva AA, Volchek VV, Abramov PA, Sokolov MN. Blocking {RhCl}2+ disorder in the crystal structure of a [SiW11O39{RhCl}]6− salt: Direct localization of the heterometal in a monosubstituted Keggin anion. Inorganic Chemistry Communications. 2018 Mar 1;89:10-12. doi: 10.1016/j.inoche.2018.01.001

Author

Mukhacheva, Anna A. ; Volchek, Victoria V. ; Abramov, Pavel A. et al. / Blocking {RhCl}2+ disorder in the crystal structure of a [SiW11O39{RhCl}]6− salt : Direct localization of the heterometal in a monosubstituted Keggin anion. In: Inorganic Chemistry Communications. 2018 ; Vol. 89. pp. 10-12.

BibTeX

@article{3044d70b0fef421b850b129169693c85,
title = "Blocking {RhCl}2+ disorder in the crystal structure of a [SiW11O39{RhCl}]6− salt: Direct localization of the heterometal in a monosubstituted Keggin anion",
abstract = "Heating [γ-SiW10O36]8− with rhodium (II) acetate at 60 °C results in the formation of [SiW11O39{RhCl}]6−, isolated as K8[SiW11O39{RhCl}][Rh2(CH3COO)4Cl2]·8H2O (1). Unique feature of the crystal structure of 1 is fully ordered Keggin anion, allowing localization of the {RhCl}2+ fragment directly from X-ray diffraction data (Rh-Cl 2.212(5) {\AA} Rh-O 1.96–2.13 {\AA}). The product was also characterized by XRPD, IR and elemental analysis. According to coupled HPLC-ICP-AES technique the [SiW11O39{RhCl}]6− anion selectively forms in the reaction.",
keywords = "HETEROPOLYTUNGSTATES, SILICOTUNGSTATES, DERIVATIVES, REACTIVITY, COMPLEXES, RUTHENIUM",
author = "Mukhacheva, {Anna A.} and Volchek, {Victoria V.} and Abramov, {Pavel A.} and Sokolov, {Maxim N.}",
note = "Publisher Copyright: {\textcopyright} 2018 Elsevier B.V.",
year = "2018",
month = mar,
day = "1",
doi = "10.1016/j.inoche.2018.01.001",
language = "English",
volume = "89",
pages = "10--12",
journal = "Inorganic Chemistry Communication",
issn = "1387-7003",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Blocking {RhCl}2+ disorder in the crystal structure of a [SiW11O39{RhCl}]6− salt

T2 - Direct localization of the heterometal in a monosubstituted Keggin anion

AU - Mukhacheva, Anna A.

AU - Volchek, Victoria V.

AU - Abramov, Pavel A.

AU - Sokolov, Maxim N.

N1 - Publisher Copyright: © 2018 Elsevier B.V.

PY - 2018/3/1

Y1 - 2018/3/1

N2 - Heating [γ-SiW10O36]8− with rhodium (II) acetate at 60 °C results in the formation of [SiW11O39{RhCl}]6−, isolated as K8[SiW11O39{RhCl}][Rh2(CH3COO)4Cl2]·8H2O (1). Unique feature of the crystal structure of 1 is fully ordered Keggin anion, allowing localization of the {RhCl}2+ fragment directly from X-ray diffraction data (Rh-Cl 2.212(5) Å Rh-O 1.96–2.13 Å). The product was also characterized by XRPD, IR and elemental analysis. According to coupled HPLC-ICP-AES technique the [SiW11O39{RhCl}]6− anion selectively forms in the reaction.

AB - Heating [γ-SiW10O36]8− with rhodium (II) acetate at 60 °C results in the formation of [SiW11O39{RhCl}]6−, isolated as K8[SiW11O39{RhCl}][Rh2(CH3COO)4Cl2]·8H2O (1). Unique feature of the crystal structure of 1 is fully ordered Keggin anion, allowing localization of the {RhCl}2+ fragment directly from X-ray diffraction data (Rh-Cl 2.212(5) Å Rh-O 1.96–2.13 Å). The product was also characterized by XRPD, IR and elemental analysis. According to coupled HPLC-ICP-AES technique the [SiW11O39{RhCl}]6− anion selectively forms in the reaction.

KW - HETEROPOLYTUNGSTATES

KW - SILICOTUNGSTATES

KW - DERIVATIVES

KW - REACTIVITY

KW - COMPLEXES

KW - RUTHENIUM

UR - http://www.scopus.com/inward/record.url?scp=85040696768&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2018.01.001

DO - 10.1016/j.inoche.2018.01.001

M3 - Article

AN - SCOPUS:85040696768

VL - 89

SP - 10

EP - 12

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

SN - 1387-7003

ER -

ID: 9254229