Standard

Binuclear Oxidovanadium(IV) Complex with the Bridging Chloranilate Ligand : Synthesis and Magnetic Properties. / Fomenko, I. S.; Nadolinnyi, V. A.; Efimov, N. N. et al.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 45, No. 11, 01.11.2019, p. 776-781.

Research output: Contribution to journal › Article › peer-review

Harvard

Fomenko, IS, Nadolinnyi, VA, Efimov, NN, Kokovkin, VV & Gushchin, AL 2019, 'Binuclear Oxidovanadium(IV) Complex with the Bridging Chloranilate Ligand: Synthesis and Magnetic Properties', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 45, no. 11, pp. 776-781. https://doi.org/10.1134/S1070328419110022

APA

Fomenko, I. S., Nadolinnyi, V. A., Efimov, N. N., Kokovkin, V. V., & Gushchin, A. L. (2019). Binuclear Oxidovanadium(IV) Complex with the Bridging Chloranilate Ligand: Synthesis and Magnetic Properties. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 45(11), 776-781. https://doi.org/10.1134/S1070328419110022

Vancouver

Fomenko IS, Nadolinnyi VA, Efimov NN, Kokovkin VV, Gushchin AL. Binuclear Oxidovanadium(IV) Complex with the Bridging Chloranilate Ligand: Synthesis and Magnetic Properties. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2019 Nov 1;45(11):776-781. doi: 10.1134/S1070328419110022

Author

Fomenko, I. S. ; Nadolinnyi, V. A. ; Efimov, N. N. et al. / Binuclear Oxidovanadium(IV) Complex with the Bridging Chloranilate Ligand : Synthesis and Magnetic Properties. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2019 ; Vol. 45, No. 11. pp. 776-781.

BibTeX

@article{fedef3b9ae5e411290e4449a6e8b62ba,
title = "Binuclear Oxidovanadium(IV) Complex with the Bridging Chloranilate Ligand: Synthesis and Magnetic Properties",
abstract = "Abstract: The binuclear oxidovanadium(IV) complex [VO(Dbbpy)Cl(Ca)Cl(Dbbpy)VO] (I) is synthesized by the reaction of [VO(Dbbpy)(H2O)Cl2] (Dbbpy is 4,4'-di-tert-butyl-2,2'-bipyridyl) with chloranilic acid H2Ca in acetonitrile in the presence of Et3N in a yield of 79%. Complex I is reduced at Е1/2 = –842 mV (vs. Ag/AgCl), which is shown by cyclic voltammetry for a solid sample using the paste electrode. The EPR spectra and magnetochemical measurements for complex I confirm the existence of two paramagnetic vanadium(IV) centers with the total spin S = 1 and the antiferromagnetic character of the exchange interaction between the centers.",
keywords = "chloranilic acid, EPR spectroscopy, magnetic susceptibility, oxidovanadium(IV), voltammetry, ELECTROCHEMISTRY, NITROGENASE, ACID, CRYSTAL-STRUCTURE, VANADIUM COMPLEXES, OXIDATIVE BROMINATION, HYDROGEN-PEROXIDE, CATALYTIC-ACTIVITY, DERIVATIVES, OXOVANADIUM(IV) COMPLEXES",
author = "Fomenko, {I. S.} and Nadolinnyi, {V. A.} and Efimov, {N. N.} and Kokovkin, {V. V.} and Gushchin, {A. L.}",
year = "2019",
month = nov,
day = "1",
doi = "10.1134/S1070328419110022",
language = "English",
volume = "45",
pages = "776--781",
journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",
issn = "1070-3284",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "11",

}

RIS

TY - JOUR

T1 - Binuclear Oxidovanadium(IV) Complex with the Bridging Chloranilate Ligand

T2 - Synthesis and Magnetic Properties

AU - Fomenko, I. S.

AU - Nadolinnyi, V. A.

AU - Efimov, N. N.

AU - Kokovkin, V. V.

AU - Gushchin, A. L.

PY - 2019/11/1

Y1 - 2019/11/1

N2 - Abstract: The binuclear oxidovanadium(IV) complex [VO(Dbbpy)Cl(Ca)Cl(Dbbpy)VO] (I) is synthesized by the reaction of [VO(Dbbpy)(H2O)Cl2] (Dbbpy is 4,4'-di-tert-butyl-2,2'-bipyridyl) with chloranilic acid H2Ca in acetonitrile in the presence of Et3N in a yield of 79%. Complex I is reduced at Е1/2 = –842 mV (vs. Ag/AgCl), which is shown by cyclic voltammetry for a solid sample using the paste electrode. The EPR spectra and magnetochemical measurements for complex I confirm the existence of two paramagnetic vanadium(IV) centers with the total spin S = 1 and the antiferromagnetic character of the exchange interaction between the centers.

AB - Abstract: The binuclear oxidovanadium(IV) complex [VO(Dbbpy)Cl(Ca)Cl(Dbbpy)VO] (I) is synthesized by the reaction of [VO(Dbbpy)(H2O)Cl2] (Dbbpy is 4,4'-di-tert-butyl-2,2'-bipyridyl) with chloranilic acid H2Ca in acetonitrile in the presence of Et3N in a yield of 79%. Complex I is reduced at Е1/2 = –842 mV (vs. Ag/AgCl), which is shown by cyclic voltammetry for a solid sample using the paste electrode. The EPR spectra and magnetochemical measurements for complex I confirm the existence of two paramagnetic vanadium(IV) centers with the total spin S = 1 and the antiferromagnetic character of the exchange interaction between the centers.

KW - chloranilic acid

KW - EPR spectroscopy

KW - magnetic susceptibility

KW - oxidovanadium(IV)

KW - voltammetry

KW - ELECTROCHEMISTRY

KW - NITROGENASE

KW - ACID

KW - CRYSTAL-STRUCTURE

KW - VANADIUM COMPLEXES

KW - OXIDATIVE BROMINATION

KW - HYDROGEN-PEROXIDE

KW - CATALYTIC-ACTIVITY

KW - DERIVATIVES

KW - OXOVANADIUM(IV) COMPLEXES

UR - http://www.scopus.com/inward/record.url?scp=85074255846&partnerID=8YFLogxK

U2 - 10.1134/S1070328419110022

DO - 10.1134/S1070328419110022

M3 - Article

AN - SCOPUS:85074255846

VL - 45

SP - 776

EP - 781

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 11

ER -

ID: 22087643