Research output: Contribution to journal › Article › peer-review
Binding of gold(iii) with silver(i) dipropyldithiocarbamate : supramolecular self-assembly (role of secondary Au…S and Ag…S bonds) and thermal behavior of the ionic-polymer complex ([Au(S 2 CNPr 2 ) 2 ][AgCl 2 ]) n. / Korneeva, E. V.; Smolentsev, A. I.; Antzutkin, O. N. et al.
In: Russian Chemical Bulletin, Vol. 68, No. 1, 01.01.2019, p. 40-47.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Binding of gold(iii) with silver(i) dipropyldithiocarbamate
T2 - supramolecular self-assembly (role of secondary Au…S and Ag…S bonds) and thermal behavior of the ionic-polymer complex ([Au(S 2 CNPr 2 ) 2 ][AgCl 2 ]) n
AU - Korneeva, E. V.
AU - Smolentsev, A. I.
AU - Antzutkin, O. N.
AU - Ivanov, A. V.
PY - 2019/1/1
Y1 - 2019/1/1
N2 - The double ionic-polymer complex ([Au(S 2 CNPr 2 ) 2 ][AgCl 2 ]) n (1) was prepared as an individual fixation form of gold(III) from NaCl solutions with silver(I) dipropyldithiocarbamate and was characterized by single-crystal X-ray diffraction and 13 C magic-angle spinning (MAS) NMR spectroscopy. The structure of 1 comprises two nonequivalent centrosymmetric complex cations [Au(S 2 CNPr 2 ) 2 ] + (A and B) and the discrete linear anion [AgCl 2 ] – . Gold(III) cations are linked by pairs of unsymmetrical secondary Au…S bonds to form linear supramolecular chains (…A…B…)n. Neighboring cations are additionally linked by [AgCl 2 ] – anions via secondary Ag…S and Cl…S bonds, the anions being involved in the overall stabilization of the supramolecular structure. The cation–anion interactions lead to a distortion of the linear configuration of the [AgCl 2 ] – anion. The character of thermolysis of 1 accompanied by quantitative regeneration of bound Au and Ag was established by simultaneous thermal analysis.
AB - The double ionic-polymer complex ([Au(S 2 CNPr 2 ) 2 ][AgCl 2 ]) n (1) was prepared as an individual fixation form of gold(III) from NaCl solutions with silver(I) dipropyldithiocarbamate and was characterized by single-crystal X-ray diffraction and 13 C magic-angle spinning (MAS) NMR spectroscopy. The structure of 1 comprises two nonequivalent centrosymmetric complex cations [Au(S 2 CNPr 2 ) 2 ] + (A and B) and the discrete linear anion [AgCl 2 ] – . Gold(III) cations are linked by pairs of unsymmetrical secondary Au…S bonds to form linear supramolecular chains (…A…B…)n. Neighboring cations are additionally linked by [AgCl 2 ] – anions via secondary Ag…S and Cl…S bonds, the anions being involved in the overall stabilization of the supramolecular structure. The cation–anion interactions lead to a distortion of the linear configuration of the [AgCl 2 ] – anion. The character of thermolysis of 1 accompanied by quantitative regeneration of bound Au and Ag was established by simultaneous thermal analysis.
KW - C MAS NMR spectroscopy
KW - binary complexes
KW - dialkyldithiocarbamates
KW - gold silver compounds
KW - noble metals
KW - secondary interactions
KW - supramolecular self-assembly
KW - thermal behavior
KW - THIN-FILMS
KW - C3H7
KW - MOLECULAR-STRUCTURE
KW - DEPOSITION
KW - CRYSTAL
KW - STRUCTURAL ORGANIZATION
KW - C-13 MAS NMR spectroscopy
KW - POLYNUCLEAR
KW - C-13 NMR
UR - http://www.scopus.com/inward/record.url?scp=85064434277&partnerID=8YFLogxK
U2 - 10.1007/s11172-019-2413-7
DO - 10.1007/s11172-019-2413-7
M3 - Article
AN - SCOPUS:85064434277
VL - 68
SP - 40
EP - 47
JO - Russian Chemical Bulletin
JF - Russian Chemical Bulletin
SN - 1066-5285
IS - 1
ER -
ID: 19622844