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BaO−B2O3 system and its mysterious member Ba3B2O6. / Bekker, Tatyana B.; Rashchenko, Sergey V.; Seryotkin, Yurii V. et al.

In: Journal of the American Ceramic Society, Vol. 101, No. 1, 01.01.2018, p. 450-457.

Research output: Contribution to journal › Article › peer-review

Harvard

Bekker, TB, Rashchenko, SV, Seryotkin, YV, Kokh, AE, Davydov, AV & Fedorov, PP 2018, 'BaO−B2O3 system and its mysterious member Ba3B2O6', Journal of the American Ceramic Society, vol. 101, no. 1, pp. 450-457. https://doi.org/10.1111/jace.15194

APA

Bekker, T. B., Rashchenko, S. V., Seryotkin, Y. V., Kokh, A. E., Davydov, A. V., & Fedorov, P. P. (2018). BaO−B2O3 system and its mysterious member Ba3B2O6. Journal of the American Ceramic Society, 101(1), 450-457. https://doi.org/10.1111/jace.15194

Vancouver

Bekker TB, Rashchenko SV, Seryotkin YV, Kokh AE, Davydov AV, Fedorov PP. BaO−B2O3 system and its mysterious member Ba3B2O6. Journal of the American Ceramic Society. 2018 Jan 1;101(1):450-457. doi: 10.1111/jace.15194

Author

Bekker, Tatyana B. ; Rashchenko, Sergey V. ; Seryotkin, Yurii V. et al. / BaO−B2O3 system and its mysterious member Ba3B2O6. In: Journal of the American Ceramic Society. 2018 ; Vol. 101, No. 1. pp. 450-457.

BibTeX

@article{dbd05172b6984d4990563de90ec9dcd5,
title = "BaO−B2O3 system and its mysterious member Ba3B2O6",
abstract = "The first systematic study of the BaO–B2O3 system and barium orthoborate Ba3B2O6 (3BaO·B2O3) was reported in 1949. Thereafter, the system was repeatedly refined but the structure of Ba3B2O6 compound has not been adequately studied yet. In our study we have, for the first time, obtained the crystalline samples of Ba3B2O6. The solved structure (Pbam, a = 13.5923(4) {\AA}, b = 13.6702(4) {\AA}, c = 14.8894(3) {\AA}) belongs to the class of {\textquoteleft}anti-zeolite{\textquoteright} borates with a pseudotetragonal [Ba12(BO3)6]6+ cation pattern which contains channels along the c axis filled with anionic clusters. The Ba3B2O6 compound may be regarded as a fluorine-free end-member of the Ba3(BO3)2– xF3x solid solution. The BaO–B2O3 phase diagram presented in our study is based on our research and literature data.",
keywords = "Borates, boron oxide, crystals/crystallization, phase diagrams, structure, LIQUID IMMISCIBILITY, crystals, BARIUM TETRABORATE, FORM, CRYSTAL-STRUCTURE, BORATE, LUMINESCENCE, GROWTH, crystallization, BETA-BAB2O4",
author = "Bekker, {Tatyana B.} and Rashchenko, {Sergey V.} and Seryotkin, {Yurii V.} and Kokh, {Alexander E.} and Davydov, {Aleksey V.} and Fedorov, {Pavel P.}",
year = "2018",
month = jan,
day = "1",
doi = "10.1111/jace.15194",
language = "English",
volume = "101",
pages = "450--457",
journal = "Journal of the American Ceramic Society",
issn = "0002-7820",
publisher = "Wiley-Blackwell",
number = "1",

}

RIS

TY - JOUR

T1 - BaO−B2O3 system and its mysterious member Ba3B2O6

AU - Bekker, Tatyana B.

AU - Rashchenko, Sergey V.

AU - Seryotkin, Yurii V.

AU - Kokh, Alexander E.

AU - Davydov, Aleksey V.

AU - Fedorov, Pavel P.

PY - 2018/1/1

Y1 - 2018/1/1

N2 - The first systematic study of the BaO–B2O3 system and barium orthoborate Ba3B2O6 (3BaO·B2O3) was reported in 1949. Thereafter, the system was repeatedly refined but the structure of Ba3B2O6 compound has not been adequately studied yet. In our study we have, for the first time, obtained the crystalline samples of Ba3B2O6. The solved structure (Pbam, a = 13.5923(4) Å, b = 13.6702(4) Å, c = 14.8894(3) Å) belongs to the class of ‘anti-zeolite’ borates with a pseudotetragonal [Ba12(BO3)6]6+ cation pattern which contains channels along the c axis filled with anionic clusters. The Ba3B2O6 compound may be regarded as a fluorine-free end-member of the Ba3(BO3)2– xF3x solid solution. The BaO–B2O3 phase diagram presented in our study is based on our research and literature data.

AB - The first systematic study of the BaO–B2O3 system and barium orthoborate Ba3B2O6 (3BaO·B2O3) was reported in 1949. Thereafter, the system was repeatedly refined but the structure of Ba3B2O6 compound has not been adequately studied yet. In our study we have, for the first time, obtained the crystalline samples of Ba3B2O6. The solved structure (Pbam, a = 13.5923(4) Å, b = 13.6702(4) Å, c = 14.8894(3) Å) belongs to the class of ‘anti-zeolite’ borates with a pseudotetragonal [Ba12(BO3)6]6+ cation pattern which contains channels along the c axis filled with anionic clusters. The Ba3B2O6 compound may be regarded as a fluorine-free end-member of the Ba3(BO3)2– xF3x solid solution. The BaO–B2O3 phase diagram presented in our study is based on our research and literature data.

KW - Borates

KW - boron oxide

KW - crystals/crystallization

KW - phase diagrams

KW - structure

KW - LIQUID IMMISCIBILITY

KW - crystals

KW - BARIUM TETRABORATE

KW - FORM

KW - CRYSTAL-STRUCTURE

KW - BORATE

KW - LUMINESCENCE

KW - GROWTH

KW - crystallization

KW - BETA-BAB2O4

UR - http://www.scopus.com/inward/record.url?scp=85029217791&partnerID=8YFLogxK

U2 - 10.1111/jace.15194

DO - 10.1111/jace.15194

M3 - Article

AN - SCOPUS:85029217791

VL - 101

SP - 450

EP - 457

JO - Journal of the American Ceramic Society

JF - Journal of the American Ceramic Society

SN - 0002-7820

IS - 1

ER -

ID: 12101841