Antimony(V) Bromide and Polybromide Complexes with N-alkylated Quinolinium or Isoquinolinium Cations: Substituent-dependent Assembly of Polymeric Frameworks

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Antimony(V) Bromide and Polybromide Complexes with N-alkylated Quinolinium or Isoquinolinium Cations: Substituent-dependent Assembly of Polymeric Frameworks. / Adonin, Sergey A.; Bondarenko, Mikhail A.; Novikov, Alexander S. et al.

In: Zeitschrift fur Anorganische und Allgemeine Chemie, Vol. 645, No. 18-19, 14.10.2019, p. 1141-1145.

Research output: Contribution to journal › Article › peer-review

Author

Adonin, Sergey A. ; Bondarenko, Mikhail A. ; Novikov, Alexander S. et al. / Antimony(V) Bromide and Polybromide Complexes with N-alkylated Quinolinium or Isoquinolinium Cations: Substituent-dependent Assembly of Polymeric Frameworks. In: Zeitschrift fur Anorganische und Allgemeine Chemie. 2019 ; Vol. 645, No. 18-19. pp. 1141-1145.

BibTeX

@article{ad665cce24b84fb58b76f5ed7485e01d,

title = "Antimony(V) Bromide and Polybromide Complexes with N-alkylated Quinolinium or Isoquinolinium Cations: Substituent-dependent Assembly of Polymeric Frameworks",

abstract = "Reactions of [SbIIIBr6]3– with Br2 in HBr in the presence of N-substituted quinolinium or isoquinolinium cations result in new complexes of hexabromidoantimonates of SbV and their polybromide adducts: (N-MeQuin)2{[SbBr6](Br3)} (1), (N-MeIsoquin)2{[SbBr6](Br3)} (2), and (N-EtQuin)[SbBr6] (3). Thermal stability was studied; estimated energies of supramolecular Br···Br interactions were calculated.",

keywords = "Antimony, Halide complex, Halogen bonding, Polyhalogens, Supramolecular interactions, ANIONS, ELECTRON-DENSITY DISTRIBUTION, CRYSTAL-STRUCTURE, IODIDE, NONCOVALENT INTERACTIONS, HALIDE-COMPLEXES, HYDROGEN, FERROELECTRIC BIS(IMIDAZOLIUM) PENTACHLOROANTIMONATE(III), HALOGEN BOND",

author = "Adonin, {Sergey A.} and Bondarenko, {Mikhail A.} and Novikov, {Alexander S.} and Abramov, {Pavel A.} and Plyusnin, {Pavel E.} and Sokolov, {Maxim N.} and Fedin, {Vladimir P.}",

note = "Publisher Copyright: {\textcopyright} 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",

year = "2019",

month = oct,

day = "14",

doi = "10.1002/zaac.201900165",

language = "English",

volume = "645",

pages = "1141--1145",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley-VCH Verlag",

number = "18-19",

}

RIS

TY - JOUR

T1 - Antimony(V) Bromide and Polybromide Complexes with N-alkylated Quinolinium or Isoquinolinium Cations: Substituent-dependent Assembly of Polymeric Frameworks

AU - Adonin, Sergey A.

AU - Bondarenko, Mikhail A.

AU - Novikov, Alexander S.

AU - Abramov, Pavel A.

AU - Plyusnin, Pavel E.

AU - Sokolov, Maxim N.

AU - Fedin, Vladimir P.

PY - 2019/10/14

Y1 - 2019/10/14

N2 - Reactions of [SbIIIBr6]3– with Br2 in HBr in the presence of N-substituted quinolinium or isoquinolinium cations result in new complexes of hexabromidoantimonates of SbV and their polybromide adducts: (N-MeQuin)2{[SbBr6](Br3)} (1), (N-MeIsoquin)2{[SbBr6](Br3)} (2), and (N-EtQuin)[SbBr6] (3). Thermal stability was studied; estimated energies of supramolecular Br···Br interactions were calculated.

AB - Reactions of [SbIIIBr6]3– with Br2 in HBr in the presence of N-substituted quinolinium or isoquinolinium cations result in new complexes of hexabromidoantimonates of SbV and their polybromide adducts: (N-MeQuin)2{[SbBr6](Br3)} (1), (N-MeIsoquin)2{[SbBr6](Br3)} (2), and (N-EtQuin)[SbBr6] (3). Thermal stability was studied; estimated energies of supramolecular Br···Br interactions were calculated.

KW - Antimony

KW - Halide complex

KW - Halogen bonding

KW - Polyhalogens

KW - Supramolecular interactions

KW - ANIONS

KW - ELECTRON-DENSITY DISTRIBUTION

KW - CRYSTAL-STRUCTURE

KW - IODIDE

KW - NONCOVALENT INTERACTIONS

KW - HALIDE-COMPLEXES

KW - HYDROGEN

KW - FERROELECTRIC BIS(IMIDAZOLIUM) PENTACHLOROANTIMONATE(III)

KW - HALOGEN BOND

UR - http://www.scopus.com/inward/record.url?scp=85073521026&partnerID=8YFLogxK

U2 - 10.1002/zaac.201900165

DO - 10.1002/zaac.201900165

M3 - Article

AN - SCOPUS:85073521026

VL - 645

SP - 1141

EP - 1145

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

SN - 0044-2313

IS - 18-19

ER -

ID: 21935759