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An X-ray Spectral Study of the Electronic Structure of Non-Innocent Mono- and Binuclear Platinum Complexes with N-Phenyl-o-Benzosemiquinonediimine. / Ivanova, T. M.; Sidorov, A. A.; Mazalov, L. N. et al.

In: Journal of Structural Chemistry, Vol. 60, No. 6, 01.06.2019, p. 909-918.

Research output: Contribution to journal › Article › peer-review

Harvard

Ivanova, TM, Sidorov, AA, Mazalov, LN, Fedorenko, AD, Kiskin, MA, Savilov, SV, Lunin, VV, Novotortsev, VM, Eremenko, IL, Kalinkin, AV, Fedoseeva, YV & Okotrub, AV 2019, 'An X-ray Spectral Study of the Electronic Structure of Non-Innocent Mono- and Binuclear Platinum Complexes with N-Phenyl-o-Benzosemiquinonediimine', Journal of Structural Chemistry, vol. 60, no. 6, pp. 909-918. https://doi.org/10.1134/S0022476619060052

APA

Ivanova, T. M., Sidorov, A. A., Mazalov, L. N., Fedorenko, A. D., Kiskin, M. A., Savilov, S. V., Lunin, V. V., Novotortsev, V. M., Eremenko, I. L., Kalinkin, A. V., Fedoseeva, Y. V., & Okotrub, A. V. (2019). An X-ray Spectral Study of the Electronic Structure of Non-Innocent Mono- and Binuclear Platinum Complexes with N-Phenyl-o-Benzosemiquinonediimine. Journal of Structural Chemistry, 60(6), 909-918. https://doi.org/10.1134/S0022476619060052

Vancouver

Ivanova TM, Sidorov AA, Mazalov LN, Fedorenko AD, Kiskin MA, Savilov SV et al. An X-ray Spectral Study of the Electronic Structure of Non-Innocent Mono- and Binuclear Platinum Complexes with N-Phenyl-o-Benzosemiquinonediimine. Journal of Structural Chemistry. 2019 Jun 1;60(6):909-918. doi: 10.1134/S0022476619060052

Author

Ivanova, T. M. ; Sidorov, A. A. ; Mazalov, L. N. et al. / An X-ray Spectral Study of the Electronic Structure of Non-Innocent Mono- and Binuclear Platinum Complexes with N-Phenyl-o-Benzosemiquinonediimine. In: Journal of Structural Chemistry. 2019 ; Vol. 60, No. 6. pp. 909-918.

BibTeX

@article{1660b88c35c44d27a012c87f260c8ff2,
title = "An X-ray Spectral Study of the Electronic Structure of Non-Innocent Mono- and Binuclear Platinum Complexes with N-Phenyl-o-Benzosemiquinonediimine",
abstract = "The electronic structure of mono- and binuclear platinum complexes with N-phenyl-o benzosemiquinondiimine ligands was studied using X-ray photoelectron spectroscopy, X-ray absorption spectroscopy, and the density functional theory. The oxidation state of the central platinum ion corresponds to that of Pt(II). Upon the transition from the trans-complex 1 to the cis-complex 2 and to the binuclear complex 3, the electron density on platinum and nitrogen atoms decreases thus testifying the participation of platinum and nitrogen atoms in the oxidation processes and in the formation of binuclear complex 3.",
keywords = "DFT, electronic structure, NEXAFS, platinum(II) complexes, radical anion N-phenyl-obenzosemiquinondiimine, redox-active ligands, XPS",
author = "Ivanova, {T. M.} and Sidorov, {A. A.} and Mazalov, {L. N.} and Fedorenko, {A. D.} and Kiskin, {M. A.} and Savilov, {S. V.} and Lunin, {V. V.} and Novotortsev, {V. M.} and Eremenko, {I. L.} and Kalinkin, {A. V.} and Fedoseeva, {Yu V.} and Okotrub, {A. V.}",
year = "2019",
month = jun,
day = "1",
doi = "10.1134/S0022476619060052",
language = "English",
volume = "60",
pages = "909--918",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "6",

}

RIS

TY - JOUR

T1 - An X-ray Spectral Study of the Electronic Structure of Non-Innocent Mono- and Binuclear Platinum Complexes with N-Phenyl-o-Benzosemiquinonediimine

AU - Ivanova, T. M.

AU - Sidorov, A. A.

AU - Mazalov, L. N.

AU - Fedorenko, A. D.

AU - Kiskin, M. A.

AU - Savilov, S. V.

AU - Lunin, V. V.

AU - Novotortsev, V. M.

AU - Eremenko, I. L.

AU - Kalinkin, A. V.

AU - Fedoseeva, Yu V.

AU - Okotrub, A. V.

PY - 2019/6/1

Y1 - 2019/6/1

N2 - The electronic structure of mono- and binuclear platinum complexes with N-phenyl-o benzosemiquinondiimine ligands was studied using X-ray photoelectron spectroscopy, X-ray absorption spectroscopy, and the density functional theory. The oxidation state of the central platinum ion corresponds to that of Pt(II). Upon the transition from the trans-complex 1 to the cis-complex 2 and to the binuclear complex 3, the electron density on platinum and nitrogen atoms decreases thus testifying the participation of platinum and nitrogen atoms in the oxidation processes and in the formation of binuclear complex 3.

AB - The electronic structure of mono- and binuclear platinum complexes with N-phenyl-o benzosemiquinondiimine ligands was studied using X-ray photoelectron spectroscopy, X-ray absorption spectroscopy, and the density functional theory. The oxidation state of the central platinum ion corresponds to that of Pt(II). Upon the transition from the trans-complex 1 to the cis-complex 2 and to the binuclear complex 3, the electron density on platinum and nitrogen atoms decreases thus testifying the participation of platinum and nitrogen atoms in the oxidation processes and in the formation of binuclear complex 3.

KW - DFT

KW - electronic structure

KW - NEXAFS

KW - platinum(II) complexes

KW - radical anion N-phenyl-obenzosemiquinondiimine

KW - redox-active ligands

KW - XPS

UR - http://www.scopus.com/inward/record.url?scp=85068776766&partnerID=8YFLogxK

U2 - 10.1134/S0022476619060052

DO - 10.1134/S0022476619060052

M3 - Article

AN - SCOPUS:85068776766

VL - 60

SP - 909

EP - 918

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 6

ER -

ID: 20838007