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An oxidovanadium(IV) complex with 4,4′-di-tert-butyl-2,2′-bipyridine ligand : Synthesis, structure and catalyzed cyclooctene epoxidation. / Fomenko, Iakov S.; Vincendeau, Sandrine; Manoury, Eric et al.

In: Polyhedron, Vol. 177, 114305, 01.02.2020.

Research output: Contribution to journal › Article › peer-review

Harvard

Fomenko, IS, Vincendeau, S, Manoury, E, Poli, R, Abramov, PA, Nadolinny, VA, Sokolov, MN & Gushchin, AL 2020, 'An oxidovanadium(IV) complex with 4,4′-di-tert-butyl-2,2′-bipyridine ligand: Synthesis, structure and catalyzed cyclooctene epoxidation', Polyhedron, vol. 177, 114305. https://doi.org/10.1016/j.poly.2019.114305

APA

Fomenko, I. S., Vincendeau, S., Manoury, E., Poli, R., Abramov, P. A., Nadolinny, V. A., Sokolov, M. N., & Gushchin, A. L. (2020). An oxidovanadium(IV) complex with 4,4′-di-tert-butyl-2,2′-bipyridine ligand: Synthesis, structure and catalyzed cyclooctene epoxidation. Polyhedron, 177, [114305]. https://doi.org/10.1016/j.poly.2019.114305

Vancouver

Fomenko IS, Vincendeau S, Manoury E, Poli R, Abramov PA, Nadolinny VA et al. An oxidovanadium(IV) complex with 4,4′-di-tert-butyl-2,2′-bipyridine ligand: Synthesis, structure and catalyzed cyclooctene epoxidation. Polyhedron. 2020 Feb 1;177:114305. doi: 10.1016/j.poly.2019.114305

Author

Fomenko, Iakov S. ; Vincendeau, Sandrine ; Manoury, Eric et al. / An oxidovanadium(IV) complex with 4,4′-di-tert-butyl-2,2′-bipyridine ligand : Synthesis, structure and catalyzed cyclooctene epoxidation. In: Polyhedron. 2020 ; Vol. 177.

BibTeX

@article{b567c281ebf946a3ab2a91e68066a9e9,
title = "An oxidovanadium(IV) complex with 4,4′-di-tert-butyl-2,2′-bipyridine ligand: Synthesis, structure and catalyzed cyclooctene epoxidation",
abstract = "The interaction of vanadium(III) chloride (VCl3) with 4,4′-di-tert-butyl-2,2′-bipyridine (dbbpy) in air resulted in the monomeric oxidovanadium(IV) complex [VOCl2(dbbpy)(H2O)] (1) in high yield. The complex was characterized by IR and EPR spectroscopies, by elemental analysis, and by single crystal X-ray diffraction analysis. The vanadium atom has a distorted octahedral coordination environment. The EPR spectrum of 1 in CH2Cl2 demonstrates an eight-line signal typical of vanadium(IV) with a d1 electronic configuration. Complex 1 exhibits catalytic activity in the cyclooctene oxidation with tert-butyl hydroperoxide (TBHP) in CHCl3. Detailed EPR, NMR and GC–MS studies of the reaction revealed a few mechanistic details and the nature of by-products that are generated by involvement of the chloroform solvent.",
keywords = "2-2′-Bipyridine ligands, Crystal structure, Cyclooctene epoxidation, EPR spectroscopy, Oxidovanadium(IV) complexes, 2-2 '-Bipyridine ligands, CRYSTAL-STRUCTURE, VANADIUM COMPLEXES, REACTIVITY, AROMATIZATION, ALCOHOLS, ALKENES, SCHIFF-BASE COMPLEX, AEROBIC OXIDATION, OLEFINS, DERIVATIVES",
author = "Fomenko, {Iakov S.} and Sandrine Vincendeau and Eric Manoury and Rinaldo Poli and Abramov, {Pavel A.} and Nadolinny, {Vladimir A.} and Sokolov, {Maxim N.} and Gushchin, {Artem L.}",
year = "2020",
month = feb,
day = "1",
doi = "10.1016/j.poly.2019.114305",
language = "English",
volume = "177",
journal = "Polyhedron",
issn = "0277-5387",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - An oxidovanadium(IV) complex with 4,4′-di-tert-butyl-2,2′-bipyridine ligand

T2 - Synthesis, structure and catalyzed cyclooctene epoxidation

AU - Fomenko, Iakov S.

AU - Vincendeau, Sandrine

AU - Manoury, Eric

AU - Poli, Rinaldo

AU - Abramov, Pavel A.

AU - Nadolinny, Vladimir A.

AU - Sokolov, Maxim N.

AU - Gushchin, Artem L.

PY - 2020/2/1

Y1 - 2020/2/1

N2 - The interaction of vanadium(III) chloride (VCl3) with 4,4′-di-tert-butyl-2,2′-bipyridine (dbbpy) in air resulted in the monomeric oxidovanadium(IV) complex [VOCl2(dbbpy)(H2O)] (1) in high yield. The complex was characterized by IR and EPR spectroscopies, by elemental analysis, and by single crystal X-ray diffraction analysis. The vanadium atom has a distorted octahedral coordination environment. The EPR spectrum of 1 in CH2Cl2 demonstrates an eight-line signal typical of vanadium(IV) with a d1 electronic configuration. Complex 1 exhibits catalytic activity in the cyclooctene oxidation with tert-butyl hydroperoxide (TBHP) in CHCl3. Detailed EPR, NMR and GC–MS studies of the reaction revealed a few mechanistic details and the nature of by-products that are generated by involvement of the chloroform solvent.

AB - The interaction of vanadium(III) chloride (VCl3) with 4,4′-di-tert-butyl-2,2′-bipyridine (dbbpy) in air resulted in the monomeric oxidovanadium(IV) complex [VOCl2(dbbpy)(H2O)] (1) in high yield. The complex was characterized by IR and EPR spectroscopies, by elemental analysis, and by single crystal X-ray diffraction analysis. The vanadium atom has a distorted octahedral coordination environment. The EPR spectrum of 1 in CH2Cl2 demonstrates an eight-line signal typical of vanadium(IV) with a d1 electronic configuration. Complex 1 exhibits catalytic activity in the cyclooctene oxidation with tert-butyl hydroperoxide (TBHP) in CHCl3. Detailed EPR, NMR and GC–MS studies of the reaction revealed a few mechanistic details and the nature of by-products that are generated by involvement of the chloroform solvent.

KW - 2-2′-Bipyridine ligands

KW - Crystal structure

KW - Cyclooctene epoxidation

KW - EPR spectroscopy

KW - Oxidovanadium(IV) complexes

KW - 2-2 '-Bipyridine ligands

KW - CRYSTAL-STRUCTURE

KW - VANADIUM COMPLEXES

KW - REACTIVITY

KW - AROMATIZATION

KW - ALCOHOLS

KW - ALKENES

KW - SCHIFF-BASE COMPLEX

KW - AEROBIC OXIDATION

KW - OLEFINS

KW - DERIVATIVES

UR - http://www.scopus.com/inward/record.url?scp=85076847276&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2019.114305

DO - 10.1016/j.poly.2019.114305

M3 - Article

AN - SCOPUS:85076847276

VL - 177

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

M1 - 114305

ER -

ID: 22977472