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An improved method for the synthesis of [ZnW12O40]6– and its reaction with [Pt(OH)4(H2O)2] : Crystal structures of (H2NMe2)5H[ZnW12O40] · 3.5H2O and K6Na2[PtW6O24] · 11H2O. / Anyushin, A. V.; Abramov, P. A.; Gushchin, A. L. et al.

In: Russian Journal of Inorganic Chemistry, Vol. 62, No. 4, 01.04.2017, p. 397-403.

Research output: Contribution to journal › Article › peer-review

Harvard

Anyushin, AV, Abramov, PA, Gushchin, AL, Vincent, C & Sokolov, MN 2017, 'An improved method for the synthesis of [ZnW12O40]6– and its reaction with [Pt(OH)4(H2O)2]: Crystal structures of (H2NMe2)5H[ZnW12O40] · 3.5H2O and K6Na2[PtW6O24] · 11H2O', Russian Journal of Inorganic Chemistry, vol. 62, no. 4, pp. 397-403. https://doi.org/10.1134/S0036023617040027

APA

Anyushin, A. V., Abramov, P. A., Gushchin, A. L., Vincent, C., & Sokolov, M. N. (2017). An improved method for the synthesis of [ZnW12O40]6– and its reaction with [Pt(OH)4(H2O)2]: Crystal structures of (H2NMe2)5H[ZnW12O40] · 3.5H2O and K6Na2[PtW6O24] · 11H2O. Russian Journal of Inorganic Chemistry, 62(4), 397-403. https://doi.org/10.1134/S0036023617040027

Vancouver

Anyushin AV, Abramov PA, Gushchin AL, Vincent C, Sokolov MN. An improved method for the synthesis of [ZnW12O40]6– and its reaction with [Pt(OH)4(H2O)2]: Crystal structures of (H2NMe2)5H[ZnW12O40] · 3.5H2O and K6Na2[PtW6O24] · 11H2O. Russian Journal of Inorganic Chemistry. 2017 Apr 1;62(4):397-403. doi: 10.1134/S0036023617040027

Author

Anyushin, A. V. ; Abramov, P. A. ; Gushchin, A. L. et al. / An improved method for the synthesis of [ZnW12O40]6– and its reaction with [Pt(OH)4(H2O)2] : Crystal structures of (H2NMe2)5H[ZnW12O40] · 3.5H2O and K6Na2[PtW6O24] · 11H2O. In: Russian Journal of Inorganic Chemistry. 2017 ; Vol. 62, No. 4. pp. 397-403.

BibTeX

@article{7cc978d2ec8e446c9ded7f4fca254495,
title = "An improved method for the synthesis of [ZnW12O40]6– and its reaction with [Pt(OH)4(H2O)2]: Crystal structures of (H2NMe2)5H[ZnW12O40] · 3.5H2O and K6Na2[PtW6O24] · 11H2O",
abstract = "(Me2NH2)5H[ZnW12O40] · 3.5H2O (I) has been synthesized by the reaction between Zn(NO3)2 · 4H2O, Na2WO4 · 2H2O and (Me2NH2)NO3 under hydrothermal conditions with a yield of 79%. The crystal structure of complex I has been characterized by single-crystal X-ray diffraction. Crystals of complex I are monoclinic, space group Cc, a = 13.165(1) {\AA}, b = 19.370(1) {\AA}, c = 20.987(2) {\AA}, α = 84.81°, V = 5145.9(0) {\AA}3, Z = 4, C10H48N5O43.5ZnW12. The Zn–O and W–O bond lengths are 1.86(2)–1.89(3) and 1.697(1)–2.030(2) {\AA}, respectively. Na2K6[PtW6O24] · 11H2O (II) has been synthesized by a slow reaction between (Me2NH2)5H[ZnW12O40] · 3.5H2O and [Pt(OH)4(H2O)2] in H2O at room temperature. Crystals of complex II are trigonal, space group R3 ¯ m, a = 13.138(1) {\AA}, c = 20.987(2) {\AA}, V = 2742.9(1) {\AA}3, Z = 3, H22O35Na2K6PtW6. The crystal structure of complex II contains [PtW6O24]6– anions linked to K+ cations via oxygen atoms. The Na+ cation is coordinated to water molecules. The Pt atom is in a standard octahedral surrounding (Pt–O and W–O are 2.018(6) and 1.762(5)–2.151(4) {\AA}, respectively).",
keywords = "CRYOSPRAY MASS-SPECTROMETRY, PHOTOCATALYTIC PROPERTIES, HYDROTHERMAL SYNTHESIS, ALPHA-KEGGIN, ANION, HETEROPOLYTUNGSTATES, POLYOXONIOBATES, COMPLEXITIES",
author = "Anyushin, {A. V.} and Abramov, {P. A.} and Gushchin, {A. L.} and C. Vincent and Sokolov, {M. N.}",
year = "2017",
month = apr,
day = "1",
doi = "10.1134/S0036023617040027",
language = "English",
volume = "62",
pages = "397--403",
journal = "Russian Journal of Inorganic Chemistry",
issn = "0036-0236",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "4",

}

RIS

TY - JOUR

T1 - An improved method for the synthesis of [ZnW12O40]6– and its reaction with [Pt(OH)4(H2O)2]

T2 - Crystal structures of (H2NMe2)5H[ZnW12O40] · 3.5H2O and K6Na2[PtW6O24] · 11H2O

AU - Anyushin, A. V.

AU - Abramov, P. A.

AU - Gushchin, A. L.

AU - Vincent, C.

AU - Sokolov, M. N.

PY - 2017/4/1

Y1 - 2017/4/1

N2 - (Me2NH2)5H[ZnW12O40] · 3.5H2O (I) has been synthesized by the reaction between Zn(NO3)2 · 4H2O, Na2WO4 · 2H2O and (Me2NH2)NO3 under hydrothermal conditions with a yield of 79%. The crystal structure of complex I has been characterized by single-crystal X-ray diffraction. Crystals of complex I are monoclinic, space group Cc, a = 13.165(1) Å, b = 19.370(1) Å, c = 20.987(2) Å, α = 84.81°, V = 5145.9(0) Å3, Z = 4, C10H48N5O43.5ZnW12. The Zn–O and W–O bond lengths are 1.86(2)–1.89(3) and 1.697(1)–2.030(2) Å, respectively. Na2K6[PtW6O24] · 11H2O (II) has been synthesized by a slow reaction between (Me2NH2)5H[ZnW12O40] · 3.5H2O and [Pt(OH)4(H2O)2] in H2O at room temperature. Crystals of complex II are trigonal, space group R3 ¯ m, a = 13.138(1) Å, c = 20.987(2) Å, V = 2742.9(1) Å3, Z = 3, H22O35Na2K6PtW6. The crystal structure of complex II contains [PtW6O24]6– anions linked to K+ cations via oxygen atoms. The Na+ cation is coordinated to water molecules. The Pt atom is in a standard octahedral surrounding (Pt–O and W–O are 2.018(6) and 1.762(5)–2.151(4) Å, respectively).

AB - (Me2NH2)5H[ZnW12O40] · 3.5H2O (I) has been synthesized by the reaction between Zn(NO3)2 · 4H2O, Na2WO4 · 2H2O and (Me2NH2)NO3 under hydrothermal conditions with a yield of 79%. The crystal structure of complex I has been characterized by single-crystal X-ray diffraction. Crystals of complex I are monoclinic, space group Cc, a = 13.165(1) Å, b = 19.370(1) Å, c = 20.987(2) Å, α = 84.81°, V = 5145.9(0) Å3, Z = 4, C10H48N5O43.5ZnW12. The Zn–O and W–O bond lengths are 1.86(2)–1.89(3) and 1.697(1)–2.030(2) Å, respectively. Na2K6[PtW6O24] · 11H2O (II) has been synthesized by a slow reaction between (Me2NH2)5H[ZnW12O40] · 3.5H2O and [Pt(OH)4(H2O)2] in H2O at room temperature. Crystals of complex II are trigonal, space group R3 ¯ m, a = 13.138(1) Å, c = 20.987(2) Å, V = 2742.9(1) Å3, Z = 3, H22O35Na2K6PtW6. The crystal structure of complex II contains [PtW6O24]6– anions linked to K+ cations via oxygen atoms. The Na+ cation is coordinated to water molecules. The Pt atom is in a standard octahedral surrounding (Pt–O and W–O are 2.018(6) and 1.762(5)–2.151(4) Å, respectively).

KW - CRYOSPRAY MASS-SPECTROMETRY

KW - PHOTOCATALYTIC PROPERTIES

KW - HYDROTHERMAL SYNTHESIS

KW - ALPHA-KEGGIN

KW - ANION

KW - HETEROPOLYTUNGSTATES

KW - POLYOXONIOBATES

KW - COMPLEXITIES

UR - http://www.scopus.com/inward/record.url?scp=85018372065&partnerID=8YFLogxK

U2 - 10.1134/S0036023617040027

DO - 10.1134/S0036023617040027

M3 - Article

AN - SCOPUS:85018372065

VL - 62

SP - 397

EP - 403

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

SN - 0036-0236

IS - 4

ER -

ID: 8967826