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A new access to tri(1-naphthyl)phosphine and its catalytically active palladacycles and luminescent Cu(I) complex. / Artem'ev, Alexander V.; Kuimov, Vladimir A.; Matveeva, Elena A. et al.

In: Inorganic Chemistry Communications, Vol. 86, 01.12.2017, p. 94-97.

Research output: Contribution to journal › Article › peer-review

Harvard

Artem'ev, AV, Kuimov, VA, Matveeva, EA, Bagryanskaya, IY, Govdi, AI, Vasilevsky, SF, Rakhmanova, MI, Samultsev, DO, Gusarova, NK & Trofimov, BA 2017, 'A new access to tri(1-naphthyl)phosphine and its catalytically active palladacycles and luminescent Cu(I) complex', Inorganic Chemistry Communications, vol. 86, pp. 94-97. https://doi.org/10.1016/j.inoche.2017.09.008

APA

Artem'ev, A. V., Kuimov, V. A., Matveeva, E. A., Bagryanskaya, I. Y., Govdi, A. I., Vasilevsky, S. F., Rakhmanova, M. I., Samultsev, D. O., Gusarova, N. K., & Trofimov, B. A. (2017). A new access to tri(1-naphthyl)phosphine and its catalytically active palladacycles and luminescent Cu(I) complex. Inorganic Chemistry Communications, 86, 94-97. https://doi.org/10.1016/j.inoche.2017.09.008

Vancouver

Artem'ev AV, Kuimov VA, Matveeva EA, Bagryanskaya IY, Govdi AI, Vasilevsky SF et al. A new access to tri(1-naphthyl)phosphine and its catalytically active palladacycles and luminescent Cu(I) complex. Inorganic Chemistry Communications. 2017 Dec 1;86:94-97. doi: 10.1016/j.inoche.2017.09.008

Author

Artem'ev, Alexander V. ; Kuimov, Vladimir A. ; Matveeva, Elena A. et al. / A new access to tri(1-naphthyl)phosphine and its catalytically active palladacycles and luminescent Cu(I) complex. In: Inorganic Chemistry Communications. 2017 ; Vol. 86. pp. 94-97.

BibTeX

@article{c708be031cbc4d54a39a93228945c06a,
title = "A new access to tri(1-naphthyl)phosphine and its catalytically active palladacycles and luminescent Cu(I) complex",
abstract = "New approach to synthesis of tri(1-naphthyl)phosphine (Np3P) and its application for design of new Pd(II) and Cu(I) complexes are reported. This phosphine has been prepared in 32% yield through exhaustive P–H arylation of РН3 with 1-chloronaphthalene in the superbasic t-BuOK/DMSO system at 70 °C. The Np3P was found to readily reacts with chloro-bridged dimers, [(κ2-C,N)Pd(μ-Cl)]2 (κ2-C,N = PhCH2NMe2 (2a) or FcCH2NMe2 (2b), to give new mononuclear palladacycles [(κ2-C,N)Pd(Np3P)Cl] (3, 4), in which metal has a square-planar geometry. These complexes show good catalytic activity in the Sonogashira reaction under low catalyst loadings (2 mol% Pd) and relatively mild conditions. We also synthesized and characterized first Cu(I) complex with Np3P, namely, [Cu(phen)(Np3P)I], that exhibits red emission (λmax = 650 nm) at room temperature.",
keywords = "Copper(I), Luminescence, Palladacycles, Phosphine, Sonogashira coupling, Tri(1-naphthyl)phosphine, SOLID-STATE LUMINESCENCE, CATALYZED SYNTHESIS, RHODIUM COMPLEX, CRYSTAL-STRUCTURES, BORONIC ACIDS, GOLD(I) COMPLEXES, PHOSPHITE LIGANDS, OLEFIN HYDROGENATION, BULKY PHOSPHINE, HECK REACTION",
author = "Artem'ev, {Alexander V.} and Kuimov, {Vladimir A.} and Matveeva, {Elena A.} and Bagryanskaya, {Irina Yu} and Govdi, {Anastasia I.} and Vasilevsky, {Sergey F.} and Rakhmanova, {Mariana I.} and Samultsev, {Dmitry O.} and Gusarova, {Nina K.} and Trofimov, {Boris A.}",
year = "2017",
month = dec,
day = "1",
doi = "10.1016/j.inoche.2017.09.008",
language = "English",
volume = "86",
pages = "94--97",
journal = "Inorganic Chemistry Communication",
issn = "1387-7003",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - A new access to tri(1-naphthyl)phosphine and its catalytically active palladacycles and luminescent Cu(I) complex

AU - Artem'ev, Alexander V.

AU - Kuimov, Vladimir A.

AU - Matveeva, Elena A.

AU - Bagryanskaya, Irina Yu

AU - Govdi, Anastasia I.

AU - Vasilevsky, Sergey F.

AU - Rakhmanova, Mariana I.

AU - Samultsev, Dmitry O.

AU - Gusarova, Nina K.

AU - Trofimov, Boris A.

PY - 2017/12/1

Y1 - 2017/12/1

N2 - New approach to synthesis of tri(1-naphthyl)phosphine (Np3P) and its application for design of new Pd(II) and Cu(I) complexes are reported. This phosphine has been prepared in 32% yield through exhaustive P–H arylation of РН3 with 1-chloronaphthalene in the superbasic t-BuOK/DMSO system at 70 °C. The Np3P was found to readily reacts with chloro-bridged dimers, [(κ2-C,N)Pd(μ-Cl)]2 (κ2-C,N = PhCH2NMe2 (2a) or FcCH2NMe2 (2b), to give new mononuclear palladacycles [(κ2-C,N)Pd(Np3P)Cl] (3, 4), in which metal has a square-planar geometry. These complexes show good catalytic activity in the Sonogashira reaction under low catalyst loadings (2 mol% Pd) and relatively mild conditions. We also synthesized and characterized first Cu(I) complex with Np3P, namely, [Cu(phen)(Np3P)I], that exhibits red emission (λmax = 650 nm) at room temperature.

AB - New approach to synthesis of tri(1-naphthyl)phosphine (Np3P) and its application for design of new Pd(II) and Cu(I) complexes are reported. This phosphine has been prepared in 32% yield through exhaustive P–H arylation of РН3 with 1-chloronaphthalene in the superbasic t-BuOK/DMSO system at 70 °C. The Np3P was found to readily reacts with chloro-bridged dimers, [(κ2-C,N)Pd(μ-Cl)]2 (κ2-C,N = PhCH2NMe2 (2a) or FcCH2NMe2 (2b), to give new mononuclear palladacycles [(κ2-C,N)Pd(Np3P)Cl] (3, 4), in which metal has a square-planar geometry. These complexes show good catalytic activity in the Sonogashira reaction under low catalyst loadings (2 mol% Pd) and relatively mild conditions. We also synthesized and characterized first Cu(I) complex with Np3P, namely, [Cu(phen)(Np3P)I], that exhibits red emission (λmax = 650 nm) at room temperature.

KW - Copper(I)

KW - Luminescence

KW - Palladacycles

KW - Phosphine

KW - Sonogashira coupling

KW - Tri(1-naphthyl)phosphine

KW - SOLID-STATE LUMINESCENCE

KW - CATALYZED SYNTHESIS

KW - RHODIUM COMPLEX

KW - CRYSTAL-STRUCTURES

KW - BORONIC ACIDS

KW - GOLD(I) COMPLEXES

KW - PHOSPHITE LIGANDS

KW - OLEFIN HYDROGENATION

KW - BULKY PHOSPHINE

KW - HECK REACTION

UR - http://www.scopus.com/inward/record.url?scp=85030321392&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2017.09.008

DO - 10.1016/j.inoche.2017.09.008

M3 - Article

AN - SCOPUS:85030321392

VL - 86

SP - 94

EP - 97

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

SN - 1387-7003

ER -

ID: 9866374