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A near-infra-red emitting manganese(II) complex with a pyrimidine-based ligand. / Vinogradova, Katerina A.; Shekhovtsov, Nikita A.; Berezin, Alexey S. et al.

In: Inorganic Chemistry Communications, Vol. 100, 01.02.2019, p. 11-15.

Research output: Contribution to journal › Article › peer-review

Harvard

Vinogradova, KA, Shekhovtsov, NA, Berezin, AS, Sukhikh, TS, Krivopalov, VP, Nikolaenkova, EB, Plokhikh, IV & Bushuev, MB 2019, 'A near-infra-red emitting manganese(II) complex with a pyrimidine-based ligand', Inorganic Chemistry Communications, vol. 100, pp. 11-15. https://doi.org/10.1016/j.inoche.2018.12.002

APA

Vinogradova, K. A., Shekhovtsov, N. A., Berezin, A. S., Sukhikh, T. S., Krivopalov, V. P., Nikolaenkova, E. B., Plokhikh, I. V., & Bushuev, M. B. (2019). A near-infra-red emitting manganese(II) complex with a pyrimidine-based ligand. Inorganic Chemistry Communications, 100, 11-15. https://doi.org/10.1016/j.inoche.2018.12.002

Vancouver

Vinogradova KA, Shekhovtsov NA, Berezin AS, Sukhikh TS, Krivopalov VP, Nikolaenkova EB et al. A near-infra-red emitting manganese(II) complex with a pyrimidine-based ligand. Inorganic Chemistry Communications. 2019 Feb 1;100:11-15. doi: 10.1016/j.inoche.2018.12.002

Author

Vinogradova, Katerina A. ; Shekhovtsov, Nikita A. ; Berezin, Alexey S. et al. / A near-infra-red emitting manganese(II) complex with a pyrimidine-based ligand. In: Inorganic Chemistry Communications. 2019 ; Vol. 100. pp. 11-15.

BibTeX

@article{d78c0dcf9a1b4a88a67957ab632f8419,
title = "A near-infra-red emitting manganese(II) complex with a pyrimidine-based ligand",
abstract = "A polymeric manganese(II) complex, [MnL2Cl2]n (L = 2-amino-4-methylpyrimidine) has been synthesized by the reaction between MnCl2·4H2O and L in the 1:1 and 1:2 metal-to-ligand molar ratios. The Mn2+ ions adopt distorted octahedral environment formed by four Cl− ligands and two N1 atoms of the pyrimidine rings of two L molecules. The chlorido-ligands adopt a μ2-bridging coordination mode linking manganese atoms into the polymeric chain. The free ligand L shows excitation-wavelength-dependent emission originating from the π-π* and n-π* excited states with nanosecond lifetimes in the blue region of the spectrum. The complex [MnL2Cl2]n demonstrates photoluminescence with the maximum in the near-infrared region (λmax = 740 nm, φ = 1.7%) with microsecond lifetimes (τ = 124 μs).",
keywords = "RAY CRYSTAL-STRUCTURE, 2-AMINO-4-METHYLPYRIMIDINE SYNTHESIS, EMISSION, LUMINESCENCE, NANOPARTICLES, TEMPERATURE, CONVERSION",
author = "Vinogradova, {Katerina A.} and Shekhovtsov, {Nikita A.} and Berezin, {Alexey S.} and Sukhikh, {Taisiya S.} and Krivopalov, {Viktor P.} and Nikolaenkova, {Elena B.} and Plokhikh, {Igor V.} and Bushuev, {Mark B.}",
note = "Publisher Copyright: {\textcopyright} 2018 Elsevier B.V.",
year = "2019",
month = feb,
day = "1",
doi = "10.1016/j.inoche.2018.12.002",
language = "English",
volume = "100",
pages = "11--15",
journal = "Inorganic Chemistry Communication",
issn = "1387-7003",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - A near-infra-red emitting manganese(II) complex with a pyrimidine-based ligand

AU - Vinogradova, Katerina A.

AU - Shekhovtsov, Nikita A.

AU - Berezin, Alexey S.

AU - Sukhikh, Taisiya S.

AU - Krivopalov, Viktor P.

AU - Nikolaenkova, Elena B.

AU - Plokhikh, Igor V.

AU - Bushuev, Mark B.

N1 - Publisher Copyright: © 2018 Elsevier B.V.

PY - 2019/2/1

Y1 - 2019/2/1

N2 - A polymeric manganese(II) complex, [MnL2Cl2]n (L = 2-amino-4-methylpyrimidine) has been synthesized by the reaction between MnCl2·4H2O and L in the 1:1 and 1:2 metal-to-ligand molar ratios. The Mn2+ ions adopt distorted octahedral environment formed by four Cl− ligands and two N1 atoms of the pyrimidine rings of two L molecules. The chlorido-ligands adopt a μ2-bridging coordination mode linking manganese atoms into the polymeric chain. The free ligand L shows excitation-wavelength-dependent emission originating from the π-π* and n-π* excited states with nanosecond lifetimes in the blue region of the spectrum. The complex [MnL2Cl2]n demonstrates photoluminescence with the maximum in the near-infrared region (λmax = 740 nm, φ = 1.7%) with microsecond lifetimes (τ = 124 μs).

AB - A polymeric manganese(II) complex, [MnL2Cl2]n (L = 2-amino-4-methylpyrimidine) has been synthesized by the reaction between MnCl2·4H2O and L in the 1:1 and 1:2 metal-to-ligand molar ratios. The Mn2+ ions adopt distorted octahedral environment formed by four Cl− ligands and two N1 atoms of the pyrimidine rings of two L molecules. The chlorido-ligands adopt a μ2-bridging coordination mode linking manganese atoms into the polymeric chain. The free ligand L shows excitation-wavelength-dependent emission originating from the π-π* and n-π* excited states with nanosecond lifetimes in the blue region of the spectrum. The complex [MnL2Cl2]n demonstrates photoluminescence with the maximum in the near-infrared region (λmax = 740 nm, φ = 1.7%) with microsecond lifetimes (τ = 124 μs).

KW - RAY CRYSTAL-STRUCTURE

KW - 2-AMINO-4-METHYLPYRIMIDINE SYNTHESIS

KW - EMISSION

KW - LUMINESCENCE

KW - NANOPARTICLES

KW - TEMPERATURE

KW - CONVERSION

UR - http://www.scopus.com/inward/record.url?scp=85058697651&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2018.12.002

DO - 10.1016/j.inoche.2018.12.002

M3 - Article

AN - SCOPUS:85058697651

VL - 100

SP - 11

EP - 15

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

SN - 1387-7003

ER -

ID: 17879395