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1-Isothiocyanatosilatrane derived from trisisopropanolamine : Synthesis, characterization, reactivity and theoretical studies. / Singh, Gurjaspreet; Saroa, Amandeep; Garg, Mridula et al.

In: Journal of Organometallic Chemistry, Vol. 719, 15.11.2012, p. 21-25.

Research output: Contribution to journal › Article › peer-review

Harvard

Singh, G, Saroa, A, Garg, M, Sharma, RP, Gubanov, AI & Smolentsev, AI 2012, '1-Isothiocyanatosilatrane derived from trisisopropanolamine: Synthesis, characterization, reactivity and theoretical studies', Journal of Organometallic Chemistry, vol. 719, pp. 21-25. https://doi.org/10.1016/j.jorganchem.2012.07.034

APA

Singh, G., Saroa, A., Garg, M., Sharma, R. P., Gubanov, A. I., & Smolentsev, A. I. (2012). 1-Isothiocyanatosilatrane derived from trisisopropanolamine: Synthesis, characterization, reactivity and theoretical studies. Journal of Organometallic Chemistry, 719, 21-25. https://doi.org/10.1016/j.jorganchem.2012.07.034

Vancouver

Singh G, Saroa A, Garg M, Sharma RP, Gubanov AI, Smolentsev AI. 1-Isothiocyanatosilatrane derived from trisisopropanolamine: Synthesis, characterization, reactivity and theoretical studies. Journal of Organometallic Chemistry. 2012 Nov 15;719:21-25. doi: 10.1016/j.jorganchem.2012.07.034

Author

Singh, Gurjaspreet ; Saroa, Amandeep ; Garg, Mridula et al. / 1-Isothiocyanatosilatrane derived from trisisopropanolamine : Synthesis, characterization, reactivity and theoretical studies. In: Journal of Organometallic Chemistry. 2012 ; Vol. 719. pp. 21-25.

BibTeX

@article{9e91d81dfec04212aec2f3e6cc804adc,
title = "1-Isothiocyanatosilatrane derived from trisisopropanolamine: Synthesis, characterization, reactivity and theoretical studies",
abstract = "1-Isothiocyanato-3,7,10-trimethyl-5-aza-2,8,9-trioxa-1-silabicyclo[3.3.3.0]undecane 3, containing transannular N → Si bond, has been synthesized by transesterification reaction of trisisopropanolamine and triethoxyisothiocyanato silane. To study the reactivity of exocyclic NCS group, 3 was treated with methyliodide, triethylsilane and aniline. All synthetic compounds have been characterized by spectroscopic methods and elemental analysis and by an X-ray crystal structure determination in the case of 3. Single crystal X-ray studies have shown that the asymmetric unit contains two crystallographically independent molecules. It has depicted the distorted trigonal bipyramidal coordination at the silicon atom with N → Siav. bond distance of 2.0385 {\aa}. The structural investigations were complemented by quantum chemical studies of the structure.",
keywords = "1-Isothiocyanatosilatrane, Pentacoordinate silicon compound, Triethoxyisothiocyanato silane, Trisisopropanolamine, SILICON, PENTACOORDINATE, DERIVATIVES, SILATRANE",
author = "Gurjaspreet Singh and Amandeep Saroa and Mridula Garg and Sharma, {Raj Pal} and Gubanov, {A. I.} and Smolentsev, {A. I.}",
year = "2012",
month = nov,
day = "15",
doi = "10.1016/j.jorganchem.2012.07.034",
language = "English",
volume = "719",
pages = "21--25",
journal = "Journal of Organometallic Chemistry",
issn = "0022-328X",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - 1-Isothiocyanatosilatrane derived from trisisopropanolamine

T2 - Synthesis, characterization, reactivity and theoretical studies

AU - Singh, Gurjaspreet

AU - Saroa, Amandeep

AU - Garg, Mridula

AU - Sharma, Raj Pal

AU - Gubanov, A. I.

AU - Smolentsev, A. I.

PY - 2012/11/15

Y1 - 2012/11/15

N2 - 1-Isothiocyanato-3,7,10-trimethyl-5-aza-2,8,9-trioxa-1-silabicyclo[3.3.3.0]undecane 3, containing transannular N → Si bond, has been synthesized by transesterification reaction of trisisopropanolamine and triethoxyisothiocyanato silane. To study the reactivity of exocyclic NCS group, 3 was treated with methyliodide, triethylsilane and aniline. All synthetic compounds have been characterized by spectroscopic methods and elemental analysis and by an X-ray crystal structure determination in the case of 3. Single crystal X-ray studies have shown that the asymmetric unit contains two crystallographically independent molecules. It has depicted the distorted trigonal bipyramidal coordination at the silicon atom with N → Siav. bond distance of 2.0385 å. The structural investigations were complemented by quantum chemical studies of the structure.

AB - 1-Isothiocyanato-3,7,10-trimethyl-5-aza-2,8,9-trioxa-1-silabicyclo[3.3.3.0]undecane 3, containing transannular N → Si bond, has been synthesized by transesterification reaction of trisisopropanolamine and triethoxyisothiocyanato silane. To study the reactivity of exocyclic NCS group, 3 was treated with methyliodide, triethylsilane and aniline. All synthetic compounds have been characterized by spectroscopic methods and elemental analysis and by an X-ray crystal structure determination in the case of 3. Single crystal X-ray studies have shown that the asymmetric unit contains two crystallographically independent molecules. It has depicted the distorted trigonal bipyramidal coordination at the silicon atom with N → Siav. bond distance of 2.0385 å. The structural investigations were complemented by quantum chemical studies of the structure.

KW - 1-Isothiocyanatosilatrane

KW - Pentacoordinate silicon compound

KW - Triethoxyisothiocyanato silane

KW - Trisisopropanolamine

KW - SILICON

KW - PENTACOORDINATE

KW - DERIVATIVES

KW - SILATRANE

UR - http://www.scopus.com/inward/record.url?scp=84995355510&partnerID=8YFLogxK

U2 - 10.1016/j.jorganchem.2012.07.034

DO - 10.1016/j.jorganchem.2012.07.034

M3 - Article

AN - SCOPUS:84995355510

VL - 719

SP - 21

EP - 25

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

ER -

ID: 17927770