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[ZnEn3]CrO4 as a precursor of zinc chromite spinel. / Gromilov, S. A.; Gerasimov, E. Yu; Khranenko, S. P. и др.

в: Journal of Structural Chemistry, Том 58, № 7, 01.12.2017, стр. 1443-1447.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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Gromilov SA, Gerasimov EY, Khranenko SP, Komarov VY, Zadesenets AV. [ZnEn3]CrO4 as a precursor of zinc chromite spinel. Journal of Structural Chemistry. 2017 дек. 1;58(7):1443-1447. doi: 10.1134/S0022476617070253

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Gromilov, S. A. ; Gerasimov, E. Yu ; Khranenko, S. P. и др. / [ZnEn3]CrO4 as a precursor of zinc chromite spinel. в: Journal of Structural Chemistry. 2017 ; Том 58, № 7. стр. 1443-1447.

BibTeX

@article{185e7eba14ef45cd8d1e2cb724ebc4d2,
title = "[ZnEn3]CrO4 as a precursor of zinc chromite spinel",
abstract = "The structure of [ZnEn3]CrO4 (En is ethylendiamine) complex salt is determined. It is demonstrated that at room temperature the crystallographic characteristics are as follows: а = 9.0942(4) {\AA}, с = 9.7673(4) {\AA}, space group Р-31с (No. 163). Contrary to [ZnEn3]SO4, disordered chromate anions participate in its formation. When [ZnEn3]CrO4 is heated in a hydrogen atmosphere up to 700 °C, zinc chromite spinel is formed (а = 8.328 {\AA}, space group Fd-3m), which has a complex nanocrystalline structure.",
keywords = "chromate anion, complex salt, crystal chemistry, ethylendiamine, single crystal X-ray diffraction analysis, spinel, zinc, CRYSTAL-STRUCTURES",
author = "Gromilov, {S. A.} and Gerasimov, {E. Yu} and Khranenko, {S. P.} and Komarov, {V. Yu} and Zadesenets, {A. V.}",
year = "2017",
month = dec,
day = "1",
doi = "10.1134/S0022476617070253",
language = "English",
volume = "58",
pages = "1443--1447",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "7",

}

RIS

TY - JOUR

T1 - [ZnEn3]CrO4 as a precursor of zinc chromite spinel

AU - Gromilov, S. A.

AU - Gerasimov, E. Yu

AU - Khranenko, S. P.

AU - Komarov, V. Yu

AU - Zadesenets, A. V.

PY - 2017/12/1

Y1 - 2017/12/1

N2 - The structure of [ZnEn3]CrO4 (En is ethylendiamine) complex salt is determined. It is demonstrated that at room temperature the crystallographic characteristics are as follows: а = 9.0942(4) Å, с = 9.7673(4) Å, space group Р-31с (No. 163). Contrary to [ZnEn3]SO4, disordered chromate anions participate in its formation. When [ZnEn3]CrO4 is heated in a hydrogen atmosphere up to 700 °C, zinc chromite spinel is formed (а = 8.328 Å, space group Fd-3m), which has a complex nanocrystalline structure.

AB - The structure of [ZnEn3]CrO4 (En is ethylendiamine) complex salt is determined. It is demonstrated that at room temperature the crystallographic characteristics are as follows: а = 9.0942(4) Å, с = 9.7673(4) Å, space group Р-31с (No. 163). Contrary to [ZnEn3]SO4, disordered chromate anions participate in its formation. When [ZnEn3]CrO4 is heated in a hydrogen atmosphere up to 700 °C, zinc chromite spinel is formed (а = 8.328 Å, space group Fd-3m), which has a complex nanocrystalline structure.

KW - chromate anion

KW - complex salt

KW - crystal chemistry

KW - ethylendiamine

KW - single crystal X-ray diffraction analysis

KW - spinel

KW - zinc

KW - CRYSTAL-STRUCTURES

UR - http://www.scopus.com/inward/record.url?scp=85039840648&partnerID=8YFLogxK

U2 - 10.1134/S0022476617070253

DO - 10.1134/S0022476617070253

M3 - Article

AN - SCOPUS:85039840648

VL - 58

SP - 1443

EP - 1447

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 7

ER -

ID: 9056180