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X-ray study of [Cu(NH3)4](ReO4)2-[Cu(NH3)2(μ-ReO4)2]n transformation. / Gromilov, S. A.; Tyutyunnik, A. P.; Piryazev, D. A. и др.

в: Journal of Structural Chemistry, Том 57, № 1, 01.01.2016, стр. 140-145.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Gromilov, SA, Tyutyunnik, AP, Piryazev, DA, Plyusnin, PE & Korenev, SV 2016, 'X-ray study of [Cu(NH3)4](ReO4)2-[Cu(NH3)2(μ-ReO4)2]n transformation', Journal of Structural Chemistry, Том. 57, № 1, стр. 140-145. https://doi.org/10.1134/S0022476616010170

APA

Gromilov, S. A., Tyutyunnik, A. P., Piryazev, D. A., Plyusnin, P. E., & Korenev, S. V. (2016). X-ray study of [Cu(NH3)4](ReO4)2-[Cu(NH3)2(μ-ReO4)2]n transformation. Journal of Structural Chemistry, 57(1), 140-145. https://doi.org/10.1134/S0022476616010170

Vancouver

Gromilov SA, Tyutyunnik AP, Piryazev DA, Plyusnin PE, Korenev SV. X-ray study of [Cu(NH3)4](ReO4)2-[Cu(NH3)2(μ-ReO4)2]n transformation. Journal of Structural Chemistry. 2016 янв. 1;57(1):140-145. doi: 10.1134/S0022476616010170

Author

Gromilov, S. A. ; Tyutyunnik, A. P. ; Piryazev, D. A. и др. / X-ray study of [Cu(NH3)4](ReO4)2-[Cu(NH3)2(μ-ReO4)2]n transformation. в: Journal of Structural Chemistry. 2016 ; Том 57, № 1. стр. 140-145.

BibTeX

@article{eb2be33d978d409fb29593194be42306,
title = "X-ray study of [Cu(NH3)4](ReO4)2-[Cu(NH3)2(μ-ReO4)2]n transformation",
abstract = "The X-ray in-situ study of [Cu(NH3)4](ReO4)2 complex salt is carried out on heating up to 500 K. The product obtained at this temperature is a new crystalline phase [Cu(NH3)2(μ-ReO4)2]n with the following unit cell parameters: a = 14.7523(3) {\AA}, b = 5.8559(1) {\AA}, c = 5.6290(1) {\AA}, β = 111.387(1)°, V = = 452.799(2) {\AA}3, space group C2/m, Z = 2, dx = 4.386 g/cm3. The coordination polyhedron of the Cu atom is a distorted octahedron formed by two nitrogen atoms (Cu-N 2.195 {\AA}), and four oxygen atoms (Cu-O 2.306 {\AA}). The structure consists of infinite [Cu(NH3)2(μ-ReO4)2]n chains, the shortest N(H)...O distances between the chains being 2.82 {\AA}.",
keywords = "copper, crystal chemistry, perrhenate, powder X-ray diffraction analysis, single crystal X-ray diffraction analysis, thermolysis",
author = "Gromilov, {S. A.} and Tyutyunnik, {A. P.} and Piryazev, {D. A.} and Plyusnin, {P. E.} and Korenev, {S. V.}",
year = "2016",
month = jan,
day = "1",
doi = "10.1134/S0022476616010170",
language = "English",
volume = "57",
pages = "140--145",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "1",

}

RIS

TY - JOUR

T1 - X-ray study of [Cu(NH3)4](ReO4)2-[Cu(NH3)2(μ-ReO4)2]n transformation

AU - Gromilov, S. A.

AU - Tyutyunnik, A. P.

AU - Piryazev, D. A.

AU - Plyusnin, P. E.

AU - Korenev, S. V.

PY - 2016/1/1

Y1 - 2016/1/1

N2 - The X-ray in-situ study of [Cu(NH3)4](ReO4)2 complex salt is carried out on heating up to 500 K. The product obtained at this temperature is a new crystalline phase [Cu(NH3)2(μ-ReO4)2]n with the following unit cell parameters: a = 14.7523(3) Å, b = 5.8559(1) Å, c = 5.6290(1) Å, β = 111.387(1)°, V = = 452.799(2) Å3, space group C2/m, Z = 2, dx = 4.386 g/cm3. The coordination polyhedron of the Cu atom is a distorted octahedron formed by two nitrogen atoms (Cu-N 2.195 Å), and four oxygen atoms (Cu-O 2.306 Å). The structure consists of infinite [Cu(NH3)2(μ-ReO4)2]n chains, the shortest N(H)...O distances between the chains being 2.82 Å.

AB - The X-ray in-situ study of [Cu(NH3)4](ReO4)2 complex salt is carried out on heating up to 500 K. The product obtained at this temperature is a new crystalline phase [Cu(NH3)2(μ-ReO4)2]n with the following unit cell parameters: a = 14.7523(3) Å, b = 5.8559(1) Å, c = 5.6290(1) Å, β = 111.387(1)°, V = = 452.799(2) Å3, space group C2/m, Z = 2, dx = 4.386 g/cm3. The coordination polyhedron of the Cu atom is a distorted octahedron formed by two nitrogen atoms (Cu-N 2.195 Å), and four oxygen atoms (Cu-O 2.306 Å). The structure consists of infinite [Cu(NH3)2(μ-ReO4)2]n chains, the shortest N(H)...O distances between the chains being 2.82 Å.

KW - copper

KW - crystal chemistry

KW - perrhenate

KW - powder X-ray diffraction analysis

KW - single crystal X-ray diffraction analysis

KW - thermolysis

UR - http://www.scopus.com/inward/record.url?scp=84962422579&partnerID=8YFLogxK

U2 - 10.1134/S0022476616010170

DO - 10.1134/S0022476616010170

M3 - Article

AN - SCOPUS:84962422579

VL - 57

SP - 140

EP - 145

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 1

ER -

ID: 25401817