Результаты исследований: Научные публикации в периодических изданиях › обзорная статья › Рецензирование
Valorization of biomass derived terpene compounds by catalytic amination. / Simakova, Irina L.; Simakov, Andrey V.; Murzin, Dmitry Yu.
в: Catalysts, Том 8, № 9, 365, 01.09.2018.Результаты исследований: Научные публикации в периодических изданиях › обзорная статья › Рецензирование
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TY - JOUR
T1 - Valorization of biomass derived terpene compounds by catalytic amination
AU - Simakova, Irina L.
AU - Simakov, Andrey V.
AU - Murzin, Dmitry Yu
N1 - Publisher Copyright: © 2018 by the authors. Licensee MDPI, Basel, Switzerland.
PY - 2018/9/1
Y1 - 2018/9/1
N2 - This review fills an apparent gap existing in the literature by providing an overview of the readily available terpenes and existing catalytic protocols for preparation of terpene-derived amines. To address the role of solid catalysts in amination of terpenes the same reactions with homogeneous counterparts are also discussed. Such catalysts can be considered as a benchmark, which solid catalysts should match. Although catalytic systems based on transition metal complexes have been developed for synthesis of amines to a larger extent, there is an apparent need to reduce the production costs. Subsequently, homogenous systems based on cheaper metals operating by nucleophilic substitution (e.g., Ni, Co, Cu, Fe) with a possibility of easy recycling, as well as metal nanoparticles (e.g., Pd, Au) supported on amphoteric oxides should be developed. These catalysts will allow synthesis of amine derivatives of terpenes which have a broad range of applications as specialty chemicals (e.g., pesticides, surfactants, etc.) and pharmaceuticals. The review will be useful in selection and design of appropriate solid materials with tailored properties as efficient catalysts for amination of terpenes.
AB - This review fills an apparent gap existing in the literature by providing an overview of the readily available terpenes and existing catalytic protocols for preparation of terpene-derived amines. To address the role of solid catalysts in amination of terpenes the same reactions with homogeneous counterparts are also discussed. Such catalysts can be considered as a benchmark, which solid catalysts should match. Although catalytic systems based on transition metal complexes have been developed for synthesis of amines to a larger extent, there is an apparent need to reduce the production costs. Subsequently, homogenous systems based on cheaper metals operating by nucleophilic substitution (e.g., Ni, Co, Cu, Fe) with a possibility of easy recycling, as well as metal nanoparticles (e.g., Pd, Au) supported on amphoteric oxides should be developed. These catalysts will allow synthesis of amine derivatives of terpenes which have a broad range of applications as specialty chemicals (e.g., pesticides, surfactants, etc.) and pharmaceuticals. The review will be useful in selection and design of appropriate solid materials with tailored properties as efficient catalysts for amination of terpenes.
KW - Amination
KW - Biomass
KW - Heterogeneous and homogeneous catalysts
KW - Supported metals
KW - Terpenes
KW - Terpenoids
KW - Transition metals
KW - biomass
KW - terpenoids
KW - terpenes
KW - BORROWING HYDROGEN
KW - transition metals
KW - ALLYLIC AMINATION
KW - HETEROGENEOUS CATALYSIS
KW - MAGNETIC NANOPARTICLES
KW - supported metals
KW - SECONDARY ALCOHOLS
KW - AMINO ALCOHOL DERIVATIVES
KW - MONOTERPENE FRAGMENTS
KW - NEUTRON-CAPTURE THERAPY
KW - POT MYRTENOL AMINATION
KW - N-ALKYLATION
KW - amination
KW - heterogeneous and homogeneous catalysts
UR - http://www.scopus.com/inward/record.url?scp=85052618689&partnerID=8YFLogxK
U2 - 10.3390/catal8090365
DO - 10.3390/catal8090365
M3 - Review article
AN - SCOPUS:85052618689
VL - 8
JO - Catalysts
JF - Catalysts
SN - 2073-4344
IS - 9
M1 - 365
ER -
ID: 16330533