Using Current-Voltage Characteristics to Control the Structure of Contacts in Polyethylene Based Composites Modified by Multiwalled Carbon Nanotubes

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Using Current-Voltage Characteristics to Control the Structure of Contacts in Polyethylene Based Composites Modified by Multiwalled Carbon Nanotubes. / Moseenkov, S. I.; Zavorin, A. V.; Ishchenko, A. V. и др.

в: Journal of Structural Chemistry, Том 61, № 4, 01.04.2020, стр. 628-639.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{95cad15c11e547b0a5aa25ad552e9528,

title = "Using Current-Voltage Characteristics to Control the Structure of Contacts in Polyethylene Based Composites Modified by Multiwalled Carbon Nanotubes",

abstract = "The conductivity of three types of composites prepared by mechanical melt mixing from polyethylene (PE) and multi-walled carbon nanotubes (MWCNTs) with an average diameter of 9.8 nm and an aspect ratio of ∼3000, 112, 36 is studied. The structure of these composites is investigated by optical and scanning electron microscopies and powder X-ray analysis. Cyclic measurements of current-voltage (I–V) characteristics and the use of a 3-point measurement scheme showed that the current density through the composite is nonlinearly increasing with increasing voltage or upon sequential measurements of I–V characteristics with the same voltage. The results of I–V measurements were used to determine concentration dependences of conductivity and their changes for each type of MWCNTs. It is shown that the percolation threshold determined from the third I–V measurement for MWCNTs in composites prepared by mechanical melt mixing decreases with decreasing aspect ratio of nanotubes from 3000 to 36.",

keywords = "composites, contacts between nanotubes, current-voltage characteristics, mechanical melt mixing, multiwalled carbon nanotubes, percolation, ACTIVATION, ELECTRICAL-CONDUCTIVITY, POLYMER COMPOSITES, IN-SITU",

author = "Moseenkov, {S. I.} and Zavorin, {A. V.} and Ishchenko, {A. V.} and Serkova, {A. N.} and Selyutin, {A. G.} and Kuznetsov, {V. L.}",

year = "2020",

month = apr,

day = "1",

doi = "10.1134/S0022476620040174",

language = "English",

volume = "61",

pages = "628--639",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "4",

}

RIS

TY - JOUR

T1 - Using Current-Voltage Characteristics to Control the Structure of Contacts in Polyethylene Based Composites Modified by Multiwalled Carbon Nanotubes

AU - Moseenkov, S. I.

AU - Zavorin, A. V.

AU - Ishchenko, A. V.

AU - Serkova, A. N.

AU - Selyutin, A. G.

AU - Kuznetsov, V. L.

PY - 2020/4/1

Y1 - 2020/4/1

N2 - The conductivity of three types of composites prepared by mechanical melt mixing from polyethylene (PE) and multi-walled carbon nanotubes (MWCNTs) with an average diameter of 9.8 nm and an aspect ratio of ∼3000, 112, 36 is studied. The structure of these composites is investigated by optical and scanning electron microscopies and powder X-ray analysis. Cyclic measurements of current-voltage (I–V) characteristics and the use of a 3-point measurement scheme showed that the current density through the composite is nonlinearly increasing with increasing voltage or upon sequential measurements of I–V characteristics with the same voltage. The results of I–V measurements were used to determine concentration dependences of conductivity and their changes for each type of MWCNTs. It is shown that the percolation threshold determined from the third I–V measurement for MWCNTs in composites prepared by mechanical melt mixing decreases with decreasing aspect ratio of nanotubes from 3000 to 36.

AB - The conductivity of three types of composites prepared by mechanical melt mixing from polyethylene (PE) and multi-walled carbon nanotubes (MWCNTs) with an average diameter of 9.8 nm and an aspect ratio of ∼3000, 112, 36 is studied. The structure of these composites is investigated by optical and scanning electron microscopies and powder X-ray analysis. Cyclic measurements of current-voltage (I–V) characteristics and the use of a 3-point measurement scheme showed that the current density through the composite is nonlinearly increasing with increasing voltage or upon sequential measurements of I–V characteristics with the same voltage. The results of I–V measurements were used to determine concentration dependences of conductivity and their changes for each type of MWCNTs. It is shown that the percolation threshold determined from the third I–V measurement for MWCNTs in composites prepared by mechanical melt mixing decreases with decreasing aspect ratio of nanotubes from 3000 to 36.

KW - composites

KW - contacts between nanotubes

KW - current-voltage characteristics

KW - mechanical melt mixing

KW - multiwalled carbon nanotubes

KW - percolation

KW - ACTIVATION

KW - ELECTRICAL-CONDUCTIVITY

KW - POLYMER COMPOSITES

KW - IN-SITU

UR - http://www.scopus.com/inward/record.url?scp=85088626806&partnerID=8YFLogxK

U2 - 10.1134/S0022476620040174

DO - 10.1134/S0022476620040174

M3 - Article

AN - SCOPUS:85088626806

VL - 61

SP - 628

EP - 639

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 4

ER -

ID: 24831072