Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Tuning the chaotropic effect as an assembly motif through one-electron transfer in a rhenium cluster. / Ivanov, Anton A.; Falaise, Clément; Landy, David и др.
в: Chemical Communications, Том 55, № 67, 28.08.2019, стр. 9951-9954.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Tuning the chaotropic effect as an assembly motif through one-electron transfer in a rhenium cluster
AU - Ivanov, Anton A.
AU - Falaise, Clément
AU - Landy, David
AU - Haouas, Mohamed
AU - Mironov, Yuri V.
AU - Shestopalov, Michael A.
AU - Cadot, Emmanuel
N1 - Publisher Copyright: © 2019 The Royal Society of Chemistry.
PY - 2019/8/28
Y1 - 2019/8/28
N2 - We report how only one electron transfer from the hydrophilic reduced cluster [{Re6Se8}(CN)6]4- induces both a dramatic increase of the host-guest affinity with γ-cyclodextrin and a drastic alteration of the supramolecular dynamics. This striking behaviour, underlined by its thermochemical fingerprint, indicates that the self-assembly process is driven by a chaotropic effect.
AB - We report how only one electron transfer from the hydrophilic reduced cluster [{Re6Se8}(CN)6]4- induces both a dramatic increase of the host-guest affinity with γ-cyclodextrin and a drastic alteration of the supramolecular dynamics. This striking behaviour, underlined by its thermochemical fingerprint, indicates that the self-assembly process is driven by a chaotropic effect.
KW - GAMMA-CYCLODEXTRIN
KW - RECOGNITION
KW - CHEMISTRY
KW - BINDING
KW - ANION
UR - http://www.scopus.com/inward/record.url?scp=85070830048&partnerID=8YFLogxK
U2 - 10.1039/c9cc05136h
DO - 10.1039/c9cc05136h
M3 - Article
C2 - 31360960
AN - SCOPUS:85070830048
VL - 55
SP - 9951
EP - 9954
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 67
ER -
ID: 21241098