Standard

Trimethylamine sorption into thin layers of fluoroalkyloxy and alkyloxy substituted phthalocyanines : Optical detection and DFT calculations. / Basova, Tamara V.; Hassan, Aseel; Krasnov, Pavel O. и др.

в: Sensors and Actuators, B: Chemical, Том 216, 01.09.2015, стр. 204-211.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Basova, TV, Hassan, A, Krasnov, PO, Gürol, I & Ahsen, V 2015, 'Trimethylamine sorption into thin layers of fluoroalkyloxy and alkyloxy substituted phthalocyanines: Optical detection and DFT calculations', Sensors and Actuators, B: Chemical, Том. 216, стр. 204-211. https://doi.org/10.1016/j.snb.2015.04.032

APA

Basova, T. V., Hassan, A., Krasnov, P. O., Gürol, I., & Ahsen, V. (2015). Trimethylamine sorption into thin layers of fluoroalkyloxy and alkyloxy substituted phthalocyanines: Optical detection and DFT calculations. Sensors and Actuators, B: Chemical, 216, 204-211. https://doi.org/10.1016/j.snb.2015.04.032

Vancouver

Basova TV, Hassan A, Krasnov PO, Gürol I, Ahsen V. Trimethylamine sorption into thin layers of fluoroalkyloxy and alkyloxy substituted phthalocyanines: Optical detection and DFT calculations. Sensors and Actuators, B: Chemical. 2015 сент. 1;216:204-211. doi: 10.1016/j.snb.2015.04.032

Author

Basova, Tamara V. ; Hassan, Aseel ; Krasnov, Pavel O. и др. / Trimethylamine sorption into thin layers of fluoroalkyloxy and alkyloxy substituted phthalocyanines : Optical detection and DFT calculations. в: Sensors and Actuators, B: Chemical. 2015 ; Том 216. стр. 204-211.

BibTeX

@article{ac5f433870e8409d9a3bf1b9ed45ebdf,
title = "Trimethylamine sorption into thin layers of fluoroalkyloxy and alkyloxy substituted phthalocyanines: Optical detection and DFT calculations",
abstract = "Octa-substituted zinc(II) phthalocyanines with nonfluorinated (ZnPc1) and fluorinated (ZnPc2) n-propanol in peripheral positions have been prepared as thin films by spin coating and examined for their potential as an optical membrane to detect trimethylamine. In this work, the method of spectroscopic ellipsometry in total internal reflection configuration has been used as the optical transduction method to study the interaction between trimethylamine and the ZnPc spun films. ZnPc2 has exhibited larger changes in the film's optical parameters compared to ZnPc1 with detection limit of 20 ppm of trimethylamine. The possible structure of the analyte/ZnPc complexes and their bond formation energies have been further analyzed using quantum chemical calculations in order to explain the different sensor responses of octa-substituted zinc(II) phthalocyanines with nonfluorinated and fluorinated substituents.",
keywords = "Chemical detection, Quantum chemical calculation, Spin coating, Substituted zinc phthalocyanine, TIRE",
author = "Basova, {Tamara V.} and Aseel Hassan and Krasnov, {Pavel O.} and Ilke G{\"u}rol and Vefa Ahsen",
year = "2015",
month = sep,
day = "1",
doi = "10.1016/j.snb.2015.04.032",
language = "English",
volume = "216",
pages = "204--211",
journal = "Sensors and Actuators, B: Chemical",
issn = "0925-4005",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Trimethylamine sorption into thin layers of fluoroalkyloxy and alkyloxy substituted phthalocyanines

T2 - Optical detection and DFT calculations

AU - Basova, Tamara V.

AU - Hassan, Aseel

AU - Krasnov, Pavel O.

AU - Gürol, Ilke

AU - Ahsen, Vefa

PY - 2015/9/1

Y1 - 2015/9/1

N2 - Octa-substituted zinc(II) phthalocyanines with nonfluorinated (ZnPc1) and fluorinated (ZnPc2) n-propanol in peripheral positions have been prepared as thin films by spin coating and examined for their potential as an optical membrane to detect trimethylamine. In this work, the method of spectroscopic ellipsometry in total internal reflection configuration has been used as the optical transduction method to study the interaction between trimethylamine and the ZnPc spun films. ZnPc2 has exhibited larger changes in the film's optical parameters compared to ZnPc1 with detection limit of 20 ppm of trimethylamine. The possible structure of the analyte/ZnPc complexes and their bond formation energies have been further analyzed using quantum chemical calculations in order to explain the different sensor responses of octa-substituted zinc(II) phthalocyanines with nonfluorinated and fluorinated substituents.

AB - Octa-substituted zinc(II) phthalocyanines with nonfluorinated (ZnPc1) and fluorinated (ZnPc2) n-propanol in peripheral positions have been prepared as thin films by spin coating and examined for their potential as an optical membrane to detect trimethylamine. In this work, the method of spectroscopic ellipsometry in total internal reflection configuration has been used as the optical transduction method to study the interaction between trimethylamine and the ZnPc spun films. ZnPc2 has exhibited larger changes in the film's optical parameters compared to ZnPc1 with detection limit of 20 ppm of trimethylamine. The possible structure of the analyte/ZnPc complexes and their bond formation energies have been further analyzed using quantum chemical calculations in order to explain the different sensor responses of octa-substituted zinc(II) phthalocyanines with nonfluorinated and fluorinated substituents.

KW - Chemical detection

KW - Quantum chemical calculation

KW - Spin coating

KW - Substituted zinc phthalocyanine

KW - TIRE

UR - http://www.scopus.com/inward/record.url?scp=84928948507&partnerID=8YFLogxK

U2 - 10.1016/j.snb.2015.04.032

DO - 10.1016/j.snb.2015.04.032

M3 - Article

AN - SCOPUS:84928948507

VL - 216

SP - 204

EP - 211

JO - Sensors and Actuators, B: Chemical

JF - Sensors and Actuators, B: Chemical

SN - 0925-4005

ER -

ID: 25436145