Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Transport of hyperpolarized samples in dissolution-DNP experiments. / Kiryutin, Alexey S.; Rodin, Bogdan A.; Yurkovskaya, Alexandra V. и др.
в: Physical Chemistry Chemical Physics, Том 21, № 25, 07.07.2019, стр. 13696-13705.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Transport of hyperpolarized samples in dissolution-DNP experiments
AU - Kiryutin, Alexey S.
AU - Rodin, Bogdan A.
AU - Yurkovskaya, Alexandra V.
AU - Ivanov, Konstantin L.
AU - Kurzbach, Dennis
AU - Jannin, Sami
AU - Guarin, David
AU - Abergel, Daniel
AU - Bodenhausen, Geoffrey
PY - 2019/7/7
Y1 - 2019/7/7
N2 - Dissolution dynamic nuclear polarization (D-DNP) experiments rely on the transfer of a sample between two high-field magnets. During this transfer, samples might experience passage through regions where the stray fields of the magnets are very weak, can approach zero, and even change their sign. This can lead to unexpected spectral features in spin systems that undergo transitions from weak- to strong-coupling regimes and vice versa, much like in field cycling nuclear magnetic resonance experiments. We herein demonstrate that the spectral features observed in D-DNP experiments can be rationalized, provided the time-dependence of the spin Hamiltonian upon field cycling is sufficiently adiabatic. Under such conditions, a passage through a weak static field can lead to the emergence of a long-lived state (LLS) based on an imbalance between the populations of singlet and triplet states in pairs of nuclei that are strongly coupled during the passage through low field. The LLS entails the appearance of anti-phase multiplet components upon transfer to a high-field magnet for observation of NMR signals.
AB - Dissolution dynamic nuclear polarization (D-DNP) experiments rely on the transfer of a sample between two high-field magnets. During this transfer, samples might experience passage through regions where the stray fields of the magnets are very weak, can approach zero, and even change their sign. This can lead to unexpected spectral features in spin systems that undergo transitions from weak- to strong-coupling regimes and vice versa, much like in field cycling nuclear magnetic resonance experiments. We herein demonstrate that the spectral features observed in D-DNP experiments can be rationalized, provided the time-dependence of the spin Hamiltonian upon field cycling is sufficiently adiabatic. Under such conditions, a passage through a weak static field can lead to the emergence of a long-lived state (LLS) based on an imbalance between the populations of singlet and triplet states in pairs of nuclei that are strongly coupled during the passage through low field. The LLS entails the appearance of anti-phase multiplet components upon transfer to a high-field magnet for observation of NMR signals.
KW - DYNAMIC NUCLEAR-POLARIZATION
KW - LIVED SPIN STATES
KW - PARA-HYDROGEN
KW - MAGNETIC-FIELD
KW - SINGLET
KW - NMR
KW - ENHANCEMENT
KW - ORDER
UR - http://www.scopus.com/inward/record.url?scp=85068369749&partnerID=8YFLogxK
U2 - 10.1039/c9cp02600b
DO - 10.1039/c9cp02600b
M3 - Article
C2 - 31198920
AN - SCOPUS:85068369749
VL - 21
SP - 13696
EP - 13705
JO - Physical Chemistry Chemical Physics
JF - Physical Chemistry Chemical Physics
SN - 1463-9076
IS - 25
ER -
ID: 20778013