Результаты исследований: Научные публикации в периодических изданиях › обзорная статья › Рецензирование
Transition metal catalyzed aerobic asymmetric coupling of 2-naphthols. / Tkachenko, Nikolay V.; Bryliakov, Konstantin P.
в: Mini-Reviews in Organic Chemistry, Том 16, № 4, 01.01.2019, стр. 392-398.Результаты исследований: Научные публикации в периодических изданиях › обзорная статья › Рецензирование
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TY - JOUR
T1 - Transition metal catalyzed aerobic asymmetric coupling of 2-naphthols
AU - Tkachenko, Nikolay V.
AU - Bryliakov, Konstantin P.
N1 - Publisher Copyright: © 2019 Bentham Science Publishers.
PY - 2019/1/1
Y1 - 2019/1/1
N2 - Optically pure 1,1′-bi-2-naphthol (BINOL) and its derivatives are among the most widely used chiral ligands and auxiliaries for asymmetric synthesis. These molecules also occur as scaffolds for various biologically active compounds. Direct oxidative coupling of 2-naphthols in the presence of chiral catalysts provides a powerful strategy for the synthesis of optically pure 1,1′-bi-2-naphthols (BINOLS). In 1978, Wynberg with co-workers discovered that a copper salt with chiral auxiliary mediates the oxidative coupling of 2-naphthols, which can be taken as the starting point for further progress in this area. Over the last decades, a number of efficient and stereoselective catalyst systems have been developed. This mini-review surveys the aerobic asymmetric oxidative coupling of 2-naphthols catalyzed by transition metal complexes reported since 1995.
AB - Optically pure 1,1′-bi-2-naphthol (BINOL) and its derivatives are among the most widely used chiral ligands and auxiliaries for asymmetric synthesis. These molecules also occur as scaffolds for various biologically active compounds. Direct oxidative coupling of 2-naphthols in the presence of chiral catalysts provides a powerful strategy for the synthesis of optically pure 1,1′-bi-2-naphthols (BINOLS). In 1978, Wynberg with co-workers discovered that a copper salt with chiral auxiliary mediates the oxidative coupling of 2-naphthols, which can be taken as the starting point for further progress in this area. Over the last decades, a number of efficient and stereoselective catalyst systems have been developed. This mini-review surveys the aerobic asymmetric oxidative coupling of 2-naphthols catalyzed by transition metal complexes reported since 1995.
KW - 2-naphthol
KW - Aerobic oxidative coupling
KW - Asymmetric synthesis
KW - BINOL
KW - Mechanism
KW - Transition metals
UR - http://www.scopus.com/inward/record.url?scp=85063740892&partnerID=8YFLogxK
U2 - 10.2174/1570193X15666180418153713
DO - 10.2174/1570193X15666180418153713
M3 - Review article
AN - SCOPUS:85063740892
VL - 16
SP - 392
EP - 398
JO - Mini-Reviews in Organic Chemistry
JF - Mini-Reviews in Organic Chemistry
SN - 1570-193X
IS - 4
ER -
ID: 19355518