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Transformation of a Pt-CeO2 Mechanical Mixture of Pulsed-Laser-Ablated Nanoparticles to a Highly Active Catalyst for Carbon Monoxide Oxidation. / Slavinskaya, E. M.; Stadnichenko, A. I.; Muravyov, V. V. и др.

в: ChemCatChem, Том 10, № 10, 24.05.2018, стр. 2232-2247.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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APA

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Slavinskaya EM, Stadnichenko AI, Muravyov VV, Kardash TY, Derevyannikova EA, Zaikovskii VI и др. Transformation of a Pt-CeO2 Mechanical Mixture of Pulsed-Laser-Ablated Nanoparticles to a Highly Active Catalyst for Carbon Monoxide Oxidation. ChemCatChem. 2018 май 24;10(10):2232-2247. doi: 10.1002/cctc.201702050

Author

Slavinskaya, E. M. ; Stadnichenko, A. I. ; Muravyov, V. V. и др. / Transformation of a Pt-CeO2 Mechanical Mixture of Pulsed-Laser-Ablated Nanoparticles to a Highly Active Catalyst for Carbon Monoxide Oxidation. в: ChemCatChem. 2018 ; Том 10, № 10. стр. 2232-2247.

BibTeX

@article{337d01050d8c49ee83d37822aab07fab,
title = "Transformation of a Pt-CeO2 Mechanical Mixture of Pulsed-Laser-Ablated Nanoparticles to a Highly Active Catalyst for Carbon Monoxide Oxidation",
abstract = "The pulsed laser ablation (PLA) in alcohol and water media was employed to prepare Pt and CeO2 PLA-nanoparticles of different sizes and degrees of defectiveness. Interactions of metallic platinum and ceria particles were studied using the thermal activation of Pt-CeO2 mechanical mixtures in the CO+O2 reaction medium or O2 atmosphere. The thermal activation resulted in oxidized Pt2+/Pt4+ states of platinum in the surface solid solutions PtCeOx and/or PtOx clusters. Catalysts formed after calcination of the PLA-ablated Pt-CeO2 mixtures in oxygen at 450-600°C revealed CO conversion at very low temperatures up to 70% depending on the conditions of PLA particles preparation and thermal activation of Pt-CeO2 mechanical mixture.",
keywords = "Cerium, Laser chemistry, Nanoparticles, Oxidation, Platinum, cerium, GAS-SHIFT REACTION, oxidation, PT/CEO2 CATALYSTS, PREFERENTIAL OXIDATION, platinum, nanoparticles, METAL-SUPPORT INTERACTIONS, PLATINUM NANOPARTICLES, laser chemistry, TEMPERATURE CO OXIDATION, CERIA CATALYSTS, PROGRESSIVE OXIDATION, IN-SITU, CHEMICAL-PROPERTIES",
author = "Slavinskaya, {E. M.} and Stadnichenko, {A. I.} and Muravyov, {V. V.} and Kardash, {T. Y.} and Derevyannikova, {E. A.} and Zaikovskii, {V. I.} and Stonkus, {O. A.} and Lapin, {I. N.} and Svetlichnyi, {V. A.} and Boronin, {A. I.}",
year = "2018",
month = may,
day = "24",
doi = "10.1002/cctc.201702050",
language = "English",
volume = "10",
pages = "2232--2247",
journal = "ChemCatChem",
issn = "1867-3880",
publisher = "Wiley - VCH Verlag GmbH & CO. KGaA",
number = "10",

}

RIS

TY - JOUR

T1 - Transformation of a Pt-CeO2 Mechanical Mixture of Pulsed-Laser-Ablated Nanoparticles to a Highly Active Catalyst for Carbon Monoxide Oxidation

AU - Slavinskaya, E. M.

AU - Stadnichenko, A. I.

AU - Muravyov, V. V.

AU - Kardash, T. Y.

AU - Derevyannikova, E. A.

AU - Zaikovskii, V. I.

AU - Stonkus, O. A.

AU - Lapin, I. N.

AU - Svetlichnyi, V. A.

AU - Boronin, A. I.

PY - 2018/5/24

Y1 - 2018/5/24

N2 - The pulsed laser ablation (PLA) in alcohol and water media was employed to prepare Pt and CeO2 PLA-nanoparticles of different sizes and degrees of defectiveness. Interactions of metallic platinum and ceria particles were studied using the thermal activation of Pt-CeO2 mechanical mixtures in the CO+O2 reaction medium or O2 atmosphere. The thermal activation resulted in oxidized Pt2+/Pt4+ states of platinum in the surface solid solutions PtCeOx and/or PtOx clusters. Catalysts formed after calcination of the PLA-ablated Pt-CeO2 mixtures in oxygen at 450-600°C revealed CO conversion at very low temperatures up to 70% depending on the conditions of PLA particles preparation and thermal activation of Pt-CeO2 mechanical mixture.

AB - The pulsed laser ablation (PLA) in alcohol and water media was employed to prepare Pt and CeO2 PLA-nanoparticles of different sizes and degrees of defectiveness. Interactions of metallic platinum and ceria particles were studied using the thermal activation of Pt-CeO2 mechanical mixtures in the CO+O2 reaction medium or O2 atmosphere. The thermal activation resulted in oxidized Pt2+/Pt4+ states of platinum in the surface solid solutions PtCeOx and/or PtOx clusters. Catalysts formed after calcination of the PLA-ablated Pt-CeO2 mixtures in oxygen at 450-600°C revealed CO conversion at very low temperatures up to 70% depending on the conditions of PLA particles preparation and thermal activation of Pt-CeO2 mechanical mixture.

KW - Cerium

KW - Laser chemistry

KW - Nanoparticles

KW - Oxidation

KW - Platinum

KW - cerium

KW - GAS-SHIFT REACTION

KW - oxidation

KW - PT/CEO2 CATALYSTS

KW - PREFERENTIAL OXIDATION

KW - platinum

KW - nanoparticles

KW - METAL-SUPPORT INTERACTIONS

KW - PLATINUM NANOPARTICLES

KW - laser chemistry

KW - TEMPERATURE CO OXIDATION

KW - CERIA CATALYSTS

KW - PROGRESSIVE OXIDATION

KW - IN-SITU

KW - CHEMICAL-PROPERTIES

UR - http://www.scopus.com/inward/record.url?scp=85043535462&partnerID=8YFLogxK

U2 - 10.1002/cctc.201702050

DO - 10.1002/cctc.201702050

M3 - Article

AN - SCOPUS:85043535462

VL - 10

SP - 2232

EP - 2247

JO - ChemCatChem

JF - ChemCatChem

SN - 1867-3880

IS - 10

ER -

ID: 10416271