Standard

Tosylate cluster complexes (Bu4N)2[М6I8(O3SC6H4CH3)6] (M = Mo, W). / Mikhailov, M. A.; Gushchin, A. L.; Gallyamov, M. R. и др.

в: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Том 43, № 3, 01.03.2017, стр. 172-180.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Mikhailov, MA, Gushchin, AL, Gallyamov, MR, Virovets, AV, Sokolov, MN, Sheven’, DG & Pervukhin, VV 2017, 'Tosylate cluster complexes (Bu4N)2[М6I8(O3SC6H4CH3)6] (M = Mo, W)', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Том. 43, № 3, стр. 172-180. https://doi.org/10.1134/S107032841702004X

APA

Mikhailov, M. A., Gushchin, A. L., Gallyamov, M. R., Virovets, A. V., Sokolov, M. N., Sheven’, D. G., & Pervukhin, V. V. (2017). Tosylate cluster complexes (Bu4N)2[М6I8(O3SC6H4CH3)6] (M = Mo, W). Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 43(3), 172-180. https://doi.org/10.1134/S107032841702004X

Vancouver

Mikhailov MA, Gushchin AL, Gallyamov MR, Virovets AV, Sokolov MN, Sheven’ DG и др. Tosylate cluster complexes (Bu4N)2[М6I8(O3SC6H4CH3)6] (M = Mo, W). Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2017 март 1;43(3):172-180. doi: 10.1134/S107032841702004X

Author

Mikhailov, M. A. ; Gushchin, A. L. ; Gallyamov, M. R. и др. / Tosylate cluster complexes (Bu4N)2[М6I8(O3SC6H4CH3)6] (M = Mo, W). в: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2017 ; Том 43, № 3. стр. 172-180.

BibTeX

@article{0520384d5eaf45bd896feee44cd23e8c,
title = "Tosylate cluster complexes (Bu4N)2[М6I8(O3SC6H4CH3)6] (M = Mo, W)",
abstract = "The reaction of (Bu4N)2[М6I14] with silver p-toluenesulfonate (tosylate) AgO3SC6H4CH3 affords iodide cluster complexes (Bu4N)2[М6I8(Рts)6] (М = Mo (I), W (II); Рts is tosylate anion CH3C6H4SO3). According to the X-ray diffraction data (СIF file CCDC no. 1027969), the molybdenum atoms in (Bu4N)2[Мo6I8(Рts)6] · 2Et2O · 2MeCN (I′) are coordinated via the monodentate mode by the tosylate ligands. The 1H NMR and mass spectrometry data show that in donor solvents the complexes undergo solvolysis followed by the substitution of the tosylate ligands by the solvent molecules, which is accompanied by changes in the electrochemical properties, as shown by the cyclic voltammetry data.",
keywords = "clusters, crystal structure, iodides, molybdenum, p-toluenesulfonates, solvolysis, tungsten, CORE, HALIDES, PRECURSOR, CRYSTAL-STRUCTURES, CL, SUBSTITUTION CHEMISTRY, BR, HEXANUCLEAR MOLYBDENUM, LUMINESCENCE, I CLUSTERS",
author = "Mikhailov, {M. A.} and Gushchin, {A. L.} and Gallyamov, {M. R.} and Virovets, {A. V.} and Sokolov, {M. N.} and Sheven{\textquoteright}, {D. G.} and Pervukhin, {V. V.}",
year = "2017",
month = mar,
day = "1",
doi = "10.1134/S107032841702004X",
language = "English",
volume = "43",
pages = "172--180",
journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",
issn = "1070-3284",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "3",

}

RIS

TY - JOUR

T1 - Tosylate cluster complexes (Bu4N)2[М6I8(O3SC6H4CH3)6] (M = Mo, W)

AU - Mikhailov, M. A.

AU - Gushchin, A. L.

AU - Gallyamov, M. R.

AU - Virovets, A. V.

AU - Sokolov, M. N.

AU - Sheven’, D. G.

AU - Pervukhin, V. V.

PY - 2017/3/1

Y1 - 2017/3/1

N2 - The reaction of (Bu4N)2[М6I14] with silver p-toluenesulfonate (tosylate) AgO3SC6H4CH3 affords iodide cluster complexes (Bu4N)2[М6I8(Рts)6] (М = Mo (I), W (II); Рts is tosylate anion CH3C6H4SO3). According to the X-ray diffraction data (СIF file CCDC no. 1027969), the molybdenum atoms in (Bu4N)2[Мo6I8(Рts)6] · 2Et2O · 2MeCN (I′) are coordinated via the monodentate mode by the tosylate ligands. The 1H NMR and mass spectrometry data show that in donor solvents the complexes undergo solvolysis followed by the substitution of the tosylate ligands by the solvent molecules, which is accompanied by changes in the electrochemical properties, as shown by the cyclic voltammetry data.

AB - The reaction of (Bu4N)2[М6I14] with silver p-toluenesulfonate (tosylate) AgO3SC6H4CH3 affords iodide cluster complexes (Bu4N)2[М6I8(Рts)6] (М = Mo (I), W (II); Рts is tosylate anion CH3C6H4SO3). According to the X-ray diffraction data (СIF file CCDC no. 1027969), the molybdenum atoms in (Bu4N)2[Мo6I8(Рts)6] · 2Et2O · 2MeCN (I′) are coordinated via the monodentate mode by the tosylate ligands. The 1H NMR and mass spectrometry data show that in donor solvents the complexes undergo solvolysis followed by the substitution of the tosylate ligands by the solvent molecules, which is accompanied by changes in the electrochemical properties, as shown by the cyclic voltammetry data.

KW - clusters

KW - crystal structure

KW - iodides

KW - molybdenum

KW - p-toluenesulfonates

KW - solvolysis

KW - tungsten

KW - CORE

KW - HALIDES

KW - PRECURSOR

KW - CRYSTAL-STRUCTURES

KW - CL

KW - SUBSTITUTION CHEMISTRY

KW - BR

KW - HEXANUCLEAR MOLYBDENUM

KW - LUMINESCENCE

KW - I CLUSTERS

UR - http://www.scopus.com/inward/record.url?scp=85016076571&partnerID=8YFLogxK

U2 - 10.1134/S107032841702004X

DO - 10.1134/S107032841702004X

M3 - Article

AN - SCOPUS:85016076571

VL - 43

SP - 172

EP - 180

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 3

ER -

ID: 10269617