Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Thin Films of Unsubstituted and Fluorinated Palladium Phthalocyanines : Structure and Sensor Response toward Ammonia and Hydrogen. / Parkhomenko, Roman G.; Sukhikh, Aleksandr S.; Klyamer, Darya D. и др.
в: Journal of Physical Chemistry C, Том 121, № 2, 19.01.2017, стр. 1200-1209.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Thin Films of Unsubstituted and Fluorinated Palladium Phthalocyanines
T2 - Structure and Sensor Response toward Ammonia and Hydrogen
AU - Parkhomenko, Roman G.
AU - Sukhikh, Aleksandr S.
AU - Klyamer, Darya D.
AU - Krasnov, Pavel O.
AU - Gromilov, Sergey
AU - Kadem, Burak
AU - Hassan, Aseel K.
AU - Basova, Tamara V.
PY - 2017/1/19
Y1 - 2017/1/19
N2 - In the present work, we study and compare the structure and sensing properties of thin films of unsubstituted palladium phthalocyanine (PdPc) and hexadecafluorosubstituted palladium phthalocyanine (PdPcF16). Thin films of PdPc and PdPcF16 were obtained by the method of organic molecular beam deposition, and their structure was studied using UV-visible spectroscopy, X-ray diffraction, and atomic force microscopy techniques. The electrical sensor response of PdPc films toward ammonia and hydrogen was investigated and compared with that of PdPcF16 films. The nature of interaction between the phthalocyanines films and some gaseous analyte molecules has been clarified using quantum chemical (DFT) calculations. (Graph Presented).
AB - In the present work, we study and compare the structure and sensing properties of thin films of unsubstituted palladium phthalocyanine (PdPc) and hexadecafluorosubstituted palladium phthalocyanine (PdPcF16). Thin films of PdPc and PdPcF16 were obtained by the method of organic molecular beam deposition, and their structure was studied using UV-visible spectroscopy, X-ray diffraction, and atomic force microscopy techniques. The electrical sensor response of PdPc films toward ammonia and hydrogen was investigated and compared with that of PdPcF16 films. The nature of interaction between the phthalocyanines films and some gaseous analyte molecules has been clarified using quantum chemical (DFT) calculations. (Graph Presented).
KW - GAUSSIAN-BASIS SETS
KW - MOLECULAR-ORIENTATION
KW - ATOMS LI
KW - HEXADECAFLUOROPHTHALOCYANINATOZINC
KW - GROWTH
KW - APPROXIMATION
KW - MORPHOLOGY
KW - ENERGY
KW - LAYERS
KW - AL
UR - http://www.scopus.com/inward/record.url?scp=85020040572&partnerID=8YFLogxK
U2 - 10.1021/acs.jpcc.6b10817
DO - 10.1021/acs.jpcc.6b10817
M3 - Article
AN - SCOPUS:85020040572
VL - 121
SP - 1200
EP - 1209
JO - Journal of Physical Chemistry C
JF - Journal of Physical Chemistry C
SN - 1932-7447
IS - 2
ER -
ID: 10187611