Результаты исследований: Научные публикации в периодических изданиях › статья по материалам конференции › Рецензирование
Thermolysis of ferric oxalate in structured mesoporous silica. / Tyapkin, P. Yu.; Petrov, S. A.; Chernyshev, A. P. и др.
в: Materials Today: Proceedings, Том 12, 01.01.2019, стр. 17-20.Результаты исследований: Научные публикации в периодических изданиях › статья по материалам конференции › Рецензирование
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TY - JOUR
T1 - Thermolysis of ferric oxalate in structured mesoporous silica
AU - Tyapkin, P. Yu.
AU - Petrov, S. A.
AU - Chernyshev, A. P.
AU - Gerasimov, K. B.
AU - Uvarov, N. F.
PY - 2019/1/1
Y1 - 2019/1/1
N2 - The influence of mesoporous silica matrix on the thermolysis of ferric oxalate loaded into its pores was studied. A significant decrease in the onset of the thermal decomposition temperature of ferric oxalate was observed. The maximum of the second decomposition stage of ferric oxalate in argon atmosphere was also appeared to be shifted by 30-40°C when thermolysis occurred in pores. These effects were accounted for the amorphous state of ferric oxalate and enhanced reactivity of highly dispersed particles.
AB - The influence of mesoporous silica matrix on the thermolysis of ferric oxalate loaded into its pores was studied. A significant decrease in the onset of the thermal decomposition temperature of ferric oxalate was observed. The maximum of the second decomposition stage of ferric oxalate in argon atmosphere was also appeared to be shifted by 30-40°C when thermolysis occurred in pores. These effects were accounted for the amorphous state of ferric oxalate and enhanced reactivity of highly dispersed particles.
KW - Ferric oxalate
KW - mesoporous silica
KW - iron oxide
KW - nanocomposite
KW - Mossbauer spectroscopy
KW - synchronous thermal analysis
KW - thermolysis
KW - superparamagnetism
KW - THERMAL-DECOMPOSITION
KW - Synchronous thermal analysis
KW - Iron oxide
KW - Superparamagnetism
KW - Thermolysis
KW - Mesoporous silica
KW - Nanocomposite
UR - http://www.scopus.com/inward/record.url?scp=85080141589&partnerID=8YFLogxK
U2 - 10.1016/j.matpr.2019.02.207
DO - 10.1016/j.matpr.2019.02.207
M3 - Conference article
VL - 12
SP - 17
EP - 20
JO - Materials Today: Proceedings
JF - Materials Today: Proceedings
SN - 2214-7853
T2 - 5th International Conference on Fundamental Bases of Mechanochemical Technologies (FBMT)
Y2 - 25 June 2018 through 28 June 2018
ER -
ID: 23397833