Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Thermodynamics and Magnetic Characteristics of Mixed Oxides on the Basis of Bismuth, Erbium, and Cobalt. / Matskevich, N. I.; Kellerman, D. G.; Gelfond, N. V. и др.
в: Russian Journal of Inorganic Chemistry, Том 65, № 5, 01.05.2020, стр. 720-724.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Thermodynamics and Magnetic Characteristics of Mixed Oxides on the Basis of Bismuth, Erbium, and Cobalt
AU - Matskevich, N. I.
AU - Kellerman, D. G.
AU - Gelfond, N. V.
AU - Zaitsev, V. P.
AU - Martynetz, V. G.
PY - 2020/5/1
Y1 - 2020/5/1
N2 - The standard formation enthalpy of the Bi12.5Er1.5CoO22.3 phase has been determined as following: ΔfH0(Bi12.5Er1.5CoO22.3, s, 298.15 K) = −5203.9 ± 14.5 kJ mol–1. Solution calorimetry, using 1 mol dm–3 HCl as a solvent, has been used to study the thermochemistry of Bi12.5Er1.5CoO22.3. The lattice energy for Bi12.5Er1.5CoO22.3 has been calculated on the basis of Born-Haber cycle using the standard formation enthalpy of the phase and literature data. For the first time, we measured the magnetic characteristics of Bi12.5Er1.5CoO22.3 and established that the Bi12.5Er1.5CoO22.3 phase has paramagnetic properties.
AB - The standard formation enthalpy of the Bi12.5Er1.5CoO22.3 phase has been determined as following: ΔfH0(Bi12.5Er1.5CoO22.3, s, 298.15 K) = −5203.9 ± 14.5 kJ mol–1. Solution calorimetry, using 1 mol dm–3 HCl as a solvent, has been used to study the thermochemistry of Bi12.5Er1.5CoO22.3. The lattice energy for Bi12.5Er1.5CoO22.3 has been calculated on the basis of Born-Haber cycle using the standard formation enthalpy of the phase and literature data. For the first time, we measured the magnetic characteristics of Bi12.5Er1.5CoO22.3 and established that the Bi12.5Er1.5CoO22.3 phase has paramagnetic properties.
KW - doped BiO
KW - formation enthalpy
KW - lattice energy
KW - doped Bi2O3
KW - RE
KW - TEMPERATURE HEAT-CAPACITY
KW - LATTICE ENERGY
KW - ION CONDUCTIVITY
UR - http://www.scopus.com/inward/record.url?scp=85085998520&partnerID=8YFLogxK
U2 - 10.1134/S0036023620050150
DO - 10.1134/S0036023620050150
M3 - Article
AN - SCOPUS:85085998520
VL - 65
SP - 720
EP - 724
JO - Russian Journal of Inorganic Chemistry
JF - Russian Journal of Inorganic Chemistry
SN - 0036-0236
IS - 5
ER -
ID: 24516996