Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Thermodynamic Analysis of Reactions of CO2 Fluid with Garnet and Clinopyroxene at 3–6 GPa. / Vinogradova, Y. G.; Shatskiy, A. F.; Litasov, K. D.
в: Geochemistry International, Том 59, № 9, 09.2021, стр. 851-857.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
}
TY - JOUR
T1 - Thermodynamic Analysis of Reactions of CO2 Fluid with Garnet and Clinopyroxene at 3–6 GPa
AU - Vinogradova, Y. G.
AU - Shatskiy, A. F.
AU - Litasov, K. D.
N1 - Funding Information: This study was done on the state assignment for the Sobolev Institute of Geology and Mineralogy, Siberian Branch, Russian Academy of Sciences, and was supported by the Russian Foundation for Basic Research, project no. 21-55-14001. KDL was supported by the state assignment for the Institute for High Pressure Physics, Russian Academy of Sciences. Publisher Copyright: © 2021, Pleiades Publishing, Ltd.
PY - 2021/9
Y1 - 2021/9
N2 - Diamond-hosted inclusions provide information on the composition of the upper mantle. Many researchers found molecular CO2 inclusions, along with mineral and melt ones, in diamonds. Available experimental data on simplified systems suggest that CO2 fluid cannot occur in equilibrium with rock-forming mantle minerals. However, it was suggested that the complex composition of minerals contributes to their stabilization. This paper presents thermodynamic calculations for reactions of diopside–jadeite and pyrope–grossular solid solutions with CO2. It is shown that the formation of the solid solutions expands the stability field of CO2 fluid with eclogite minerals to lower temperatures, corresponding to the geothermal parameters of the continental lithosphere. The obtained relationships are confirmed by the results of preliminary experiments with model mixtures at high pressures and temperatures.
AB - Diamond-hosted inclusions provide information on the composition of the upper mantle. Many researchers found molecular CO2 inclusions, along with mineral and melt ones, in diamonds. Available experimental data on simplified systems suggest that CO2 fluid cannot occur in equilibrium with rock-forming mantle minerals. However, it was suggested that the complex composition of minerals contributes to their stabilization. This paper presents thermodynamic calculations for reactions of diopside–jadeite and pyrope–grossular solid solutions with CO2. It is shown that the formation of the solid solutions expands the stability field of CO2 fluid with eclogite minerals to lower temperatures, corresponding to the geothermal parameters of the continental lithosphere. The obtained relationships are confirmed by the results of preliminary experiments with model mixtures at high pressures and temperatures.
KW - CO fluid
KW - diamond
KW - diopside
KW - grossular
KW - jadeite
KW - pyrope
KW - thermodynamic calculations
KW - upper mantle
UR - http://www.scopus.com/inward/record.url?scp=85114270315&partnerID=8YFLogxK
U2 - 10.1134/S0016702921080103
DO - 10.1134/S0016702921080103
M3 - Article
AN - SCOPUS:85114270315
VL - 59
SP - 851
EP - 857
JO - Geochemistry International
JF - Geochemistry International
SN - 0016-7029
IS - 9
ER -
ID: 34160989