Thermal effects in guest–host systems › Обзор исследований

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Thermal effects in guest–host systems : [Zn₂(bdc)(S-lac)(dmf)]•PhEtOH: A DSC and NMR study. / Kozlova, Svetlana G.; Pishchur, Denis P.; Gallyamov, Marsel R.

в: Chirality, Том 29, № 3-4, 03.2017, стр. 130-133.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{9d5cb66647bb482b9a0b9f24adc0cb0e,

title = "Thermal effects in guest–host systems: [Zn2(bdc)(S-lac)(dmf)]•PhEtOH: A DSC and NMR study",

abstract = "Differential scanning calorimetry and nuclear magnetic resonance were used to investigate thermal effects in the guest–host systems where homochiral metal–organic sorbent [Zn2(bdc)(S-lac)(dmf)] is considered as a host while 1-phenylethanol enantiomers and their racemic mixture serve as guest molecules. A maximum energy gain from the guest–host interaction was observed in the system with the racemic mixture. The effect of host–guest recognition was revealed for the case of the host and guest having a similar type of chirality in the presence of antipode guest molecules.",

keywords = "1-phenylethanol, DSC, enantiomers, MOF, NMR, racemate, CATALYSIS, ENANTIOSELECTIVE SEPARATION, MOBILITY, PHASE-TRANSITIONS, MOLECULES",

author = "Kozlova, {Svetlana G.} and Pishchur, {Denis P.} and Gallyamov, {Marsel R.}",

note = "{\textcopyright} 2017 Wiley Periodicals, Inc.",

year = "2017",

month = mar,

doi = "10.1002/chir.22682",

language = "English",

volume = "29",

pages = "130--133",

journal = "Chirality",

issn = "0899-0042",

publisher = "Wiley-Liss Inc.",

number = "3-4",

}

RIS

TY - JOUR

T1 - Thermal effects in guest–host systems

T2 - [Zn2(bdc)(S-lac)(dmf)]•PhEtOH: A DSC and NMR study

AU - Kozlova, Svetlana G.

AU - Pishchur, Denis P.

AU - Gallyamov, Marsel R.

PY - 2017/3

Y1 - 2017/3

N2 - Differential scanning calorimetry and nuclear magnetic resonance were used to investigate thermal effects in the guest–host systems where homochiral metal–organic sorbent [Zn2(bdc)(S-lac)(dmf)] is considered as a host while 1-phenylethanol enantiomers and their racemic mixture serve as guest molecules. A maximum energy gain from the guest–host interaction was observed in the system with the racemic mixture. The effect of host–guest recognition was revealed for the case of the host and guest having a similar type of chirality in the presence of antipode guest molecules.

AB - Differential scanning calorimetry and nuclear magnetic resonance were used to investigate thermal effects in the guest–host systems where homochiral metal–organic sorbent [Zn2(bdc)(S-lac)(dmf)] is considered as a host while 1-phenylethanol enantiomers and their racemic mixture serve as guest molecules. A maximum energy gain from the guest–host interaction was observed in the system with the racemic mixture. The effect of host–guest recognition was revealed for the case of the host and guest having a similar type of chirality in the presence of antipode guest molecules.

KW - 1-phenylethanol

KW - DSC

KW - enantiomers

KW - MOF

KW - NMR

KW - racemate

KW - CATALYSIS

KW - ENANTIOSELECTIVE SEPARATION

KW - MOBILITY

KW - PHASE-TRANSITIONS

KW - MOLECULES

UR - http://www.scopus.com/inward/record.url?scp=85016751267&partnerID=8YFLogxK

U2 - 10.1002/chir.22682

DO - 10.1002/chir.22682

M3 - Article

C2 - 28370482

AN - SCOPUS:85016751267

VL - 29

SP - 130

EP - 133

JO - Chirality

JF - Chirality

SN - 0899-0042

IS - 3-4

ER -

ID: 10265735

Thermal effects in guest–host systems: [Zn2(bdc)(S-lac)(dmf)]•PhEtOH: A DSC and NMR study

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Thermal effects in guest–host systems: [Zn₂(bdc)(S-lac)(dmf)]•PhEtOH: A DSC and NMR study