Standard

Thermal Decomposition of [Ir(NH3)6][Fe(CN)6] in Various Atmospheres; Crystal Structures of [Ir(NH3)6][Fe(CN)6] and [Ir(NH3)6]X 3 (X = Cl, Br). / Varygin, A. D.; Popov, A. A.; Gromilov, S. A. и др.

в: Journal of Structural Chemistry, Том 64, № 7, 07.2023, стр. 1261-1274.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Varygin, AD, Popov, AA, Gromilov, SA, Plyusnin, PE & Korenev, SV 2023, 'Thermal Decomposition of [Ir(NH3)6][Fe(CN)6] in Various Atmospheres; Crystal Structures of [Ir(NH3)6][Fe(CN)6] and [Ir(NH3)6]X 3 (X = Cl, Br)', Journal of Structural Chemistry, Том. 64, № 7, стр. 1261-1274. https://doi.org/10.1134/S0022476623070107

APA

Varygin, A. D., Popov, A. A., Gromilov, S. A., Plyusnin, P. E., & Korenev, S. V. (2023). Thermal Decomposition of [Ir(NH3)6][Fe(CN)6] in Various Atmospheres; Crystal Structures of [Ir(NH3)6][Fe(CN)6] and [Ir(NH3)6]X 3 (X = Cl, Br). Journal of Structural Chemistry, 64(7), 1261-1274. https://doi.org/10.1134/S0022476623070107

Vancouver

Varygin AD, Popov AA, Gromilov SA, Plyusnin PE, Korenev SV. Thermal Decomposition of [Ir(NH3)6][Fe(CN)6] in Various Atmospheres; Crystal Structures of [Ir(NH3)6][Fe(CN)6] and [Ir(NH3)6]X 3 (X = Cl, Br). Journal of Structural Chemistry. 2023 июль;64(7):1261-1274. doi: 10.1134/S0022476623070107

Author

Varygin, A. D. ; Popov, A. A. ; Gromilov, S. A. и др. / Thermal Decomposition of [Ir(NH3)6][Fe(CN)6] in Various Atmospheres; Crystal Structures of [Ir(NH3)6][Fe(CN)6] and [Ir(NH3)6]X 3 (X = Cl, Br). в: Journal of Structural Chemistry. 2023 ; Том 64, № 7. стр. 1261-1274.

BibTeX

@article{f3fd12b72cfd4f2891d92734df39bf91,
title = "Thermal Decomposition of [Ir(NH3)6][Fe(CN)6] in Various Atmospheres; Crystal Structures of [Ir(NH3)6][Fe(CN)6] and [Ir(NH3)6]X 3 (X = Cl, Br)",
abstract = "A new double complex salt [Ir(NH3)6][Fe(CN)6] is synthesized and structurally characterized. The crystal structures of [Ir(NH3)6]Cl3 and [Ir(NH3)6]Br3 are determined. The process of thermal decomposition of [Ir(NH3)6][Fe(CN)6] in different atmospheres is studied. It is shown that the decomposition products in reducing (He/H2) and inert (Ar) atmospheres is a two-phase mixture of iridium–iron solid solutions with face-centered cubic and hexagonal close-packed crystal lattices. In the oxidizing atmosphere (Ar/O2), mainly IrO2 and Fe2O3 oxides are formed.",
keywords = "ammine complexes, double complex salts, iridium, iron, nanoalloys, thermal decomposition",
author = "Varygin, {A. D.} and Popov, {A. A.} and Gromilov, {S. A.} and Plyusnin, {P. E.} and Korenev, {S. V.}",
note = "This work was funded by the Ministry of Science and Higher Education of the Russian Federation (projects No. 121031700313-8 and 121031700315-2). Публикация для корректировки.",
year = "2023",
month = jul,
doi = "10.1134/S0022476623070107",
language = "English",
volume = "64",
pages = "1261--1274",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "7",

}

RIS

TY - JOUR

T1 - Thermal Decomposition of [Ir(NH3)6][Fe(CN)6] in Various Atmospheres; Crystal Structures of [Ir(NH3)6][Fe(CN)6] and [Ir(NH3)6]X 3 (X = Cl, Br)

AU - Varygin, A. D.

AU - Popov, A. A.

AU - Gromilov, S. A.

AU - Plyusnin, P. E.

AU - Korenev, S. V.

N1 - This work was funded by the Ministry of Science and Higher Education of the Russian Federation (projects No. 121031700313-8 and 121031700315-2). Публикация для корректировки.

PY - 2023/7

Y1 - 2023/7

N2 - A new double complex salt [Ir(NH3)6][Fe(CN)6] is synthesized and structurally characterized. The crystal structures of [Ir(NH3)6]Cl3 and [Ir(NH3)6]Br3 are determined. The process of thermal decomposition of [Ir(NH3)6][Fe(CN)6] in different atmospheres is studied. It is shown that the decomposition products in reducing (He/H2) and inert (Ar) atmospheres is a two-phase mixture of iridium–iron solid solutions with face-centered cubic and hexagonal close-packed crystal lattices. In the oxidizing atmosphere (Ar/O2), mainly IrO2 and Fe2O3 oxides are formed.

AB - A new double complex salt [Ir(NH3)6][Fe(CN)6] is synthesized and structurally characterized. The crystal structures of [Ir(NH3)6]Cl3 and [Ir(NH3)6]Br3 are determined. The process of thermal decomposition of [Ir(NH3)6][Fe(CN)6] in different atmospheres is studied. It is shown that the decomposition products in reducing (He/H2) and inert (Ar) atmospheres is a two-phase mixture of iridium–iron solid solutions with face-centered cubic and hexagonal close-packed crystal lattices. In the oxidizing atmosphere (Ar/O2), mainly IrO2 and Fe2O3 oxides are formed.

KW - ammine complexes

KW - double complex salts

KW - iridium

KW - iron

KW - nanoalloys

KW - thermal decomposition

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85166186907&origin=inward&txGid=41eecfc71fde32fa0665d6e8247afedd

UR - https://www.mendeley.com/catalogue/0596cd73-c638-3e8c-a743-8640fd9e35c4/

U2 - 10.1134/S0022476623070107

DO - 10.1134/S0022476623070107

M3 - Article

VL - 64

SP - 1261

EP - 1274

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 7

ER -

ID: 59578999