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Thermal Decomposition in Systems of Acid Zn(II), Co(II), and Ni(II) Maleates with the Formation of Metallic Nanoparticles. / Yudanova, L. I.; Logvinenko, V. A.; Korol’kov, I. V. и др.
в: Russian Journal of Physical Chemistry A, Том 92, № 11, 01.11.2018, стр. 2247-2252.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Thermal Decomposition in Systems of Acid Zn(II), Co(II), and Ni(II) Maleates with the Formation of Metallic Nanoparticles
AU - Yudanova, L. I.
AU - Logvinenko, V. A.
AU - Korol’kov, I. V.
AU - Ishchenko, A. V.
AU - Rudina, N. A.
PY - 2018/11/1
Y1 - 2018/11/1
N2 - Abstract: Conditions of synthesis are optimized and XRD and thermoanalytical studies are performed for normal maleate [Zn(H2O)2(C4H2O4)] and acid maleate [Zn(H2O)4(C4H3O4)2], along with acid Co(II)–Zn(II), Ni(II)–Zn(II) maleates. It is shown that when solid solutions thermally decompose in acidic maleate systems, the kinetically less stable component causes the temperature of decomposition of the more stable component to fall. It is established that the solid residue of Zn(II) maleate after heating to 500°C in a He atmosphere is a composite containing Zn oxide whose reduction to metal begins at 675°C. The decomposition of [(Co0.1Zn0.9)(H2O)4(С4H3O4)2] leads to the oozing of metallic cobalt atoms embedded in the channels of the ZnO structure that act as a catalyst for the spontaneous growth of uniform carbon nanotubes on the surface of the composite. After thermal decomposition of the samples in a system of acid Ni(II) maleate–acid Zn(II) maleate, only the bimetallic phase is observed in the composites, and there is no zinc oxide.
AB - Abstract: Conditions of synthesis are optimized and XRD and thermoanalytical studies are performed for normal maleate [Zn(H2O)2(C4H2O4)] and acid maleate [Zn(H2O)4(C4H3O4)2], along with acid Co(II)–Zn(II), Ni(II)–Zn(II) maleates. It is shown that when solid solutions thermally decompose in acidic maleate systems, the kinetically less stable component causes the temperature of decomposition of the more stable component to fall. It is established that the solid residue of Zn(II) maleate after heating to 500°C in a He atmosphere is a composite containing Zn oxide whose reduction to metal begins at 675°C. The decomposition of [(Co0.1Zn0.9)(H2O)4(С4H3O4)2] leads to the oozing of metallic cobalt atoms embedded in the channels of the ZnO structure that act as a catalyst for the spontaneous growth of uniform carbon nanotubes on the surface of the composite. After thermal decomposition of the samples in a system of acid Ni(II) maleate–acid Zn(II) maleate, only the bimetallic phase is observed in the composites, and there is no zinc oxide.
KW - catalysts
KW - maleate
KW - metal/polymer composites
KW - nanoparticles
KW - nanotubes
KW - quantum-size effect
KW - thermal decomposition
KW - transition metals
KW - FE(II)
KW - polymer composites
KW - metal
KW - OXIDE CATALYSTS
UR - http://www.scopus.com/inward/record.url?scp=85055094474&partnerID=8YFLogxK
U2 - 10.1134/S003602441811047X
DO - 10.1134/S003602441811047X
M3 - Article
AN - SCOPUS:85055094474
VL - 92
SP - 2247
EP - 2252
JO - Russian Journal of Physical Chemistry A
JF - Russian Journal of Physical Chemistry A
SN - 0036-0244
IS - 11
ER -
ID: 17179661