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Theoretical Treatment of Pulsed DNP Experiments : Effects of Spectral Exchange. / Nasibulov, Egor A.; Ivanov, Konstantin L.; Sagdeev, Renad Z.

в: Applied Magnetic Resonance, Том 50, № 10, 01.10.2019, стр. 1233-1240.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Nasibulov, EA, Ivanov, KL & Sagdeev, RZ 2019, 'Theoretical Treatment of Pulsed DNP Experiments: Effects of Spectral Exchange', Applied Magnetic Resonance, Том. 50, № 10, стр. 1233-1240. https://doi.org/10.1007/s00723-019-01144-6

APA

Nasibulov, E. A., Ivanov, K. L., & Sagdeev, R. Z. (2019). Theoretical Treatment of Pulsed DNP Experiments: Effects of Spectral Exchange. Applied Magnetic Resonance, 50(10), 1233-1240. https://doi.org/10.1007/s00723-019-01144-6

Vancouver

Nasibulov EA, Ivanov KL, Sagdeev RZ. Theoretical Treatment of Pulsed DNP Experiments: Effects of Spectral Exchange. Applied Magnetic Resonance. 2019 окт. 1;50(10):1233-1240. doi: 10.1007/s00723-019-01144-6

Author

Nasibulov, Egor A. ; Ivanov, Konstantin L. ; Sagdeev, Renad Z. / Theoretical Treatment of Pulsed DNP Experiments : Effects of Spectral Exchange. в: Applied Magnetic Resonance. 2019 ; Том 50, № 10. стр. 1233-1240.

BibTeX

@article{cff435f57c9547c5a0d14cf6657a6884,
title = "Theoretical Treatment of Pulsed DNP Experiments: Effects of Spectral Exchange",
abstract = "In the present work, we provide a theoretical treatment of pulsed Overhauser-type dynamic nuclear polarization (DNP) in the presence of spectral exchange, namely, Heisenberg exchange. The expression for the DNP enhancement of a nuclear magnetic resonance (NMR) signal is generalized by redefining the “deviation factor”, expressing the deviation of the electron spin polarization from its equilibrium value, averaged over the period of the pulse sequence. We can demonstrate that spectral exchange significantly increases the deviation factor and, thus, the NMR enhancement. The present treatment allows one to determine the optimal pumping frequency at different exchange rates.",
keywords = "DYNAMIC NUCLEAR-POLARIZATION",
author = "Nasibulov, {Egor A.} and Ivanov, {Konstantin L.} and Sagdeev, {Renad Z.}",
note = "Publisher Copyright: {\textcopyright} 2019, Springer-Verlag GmbH Austria, part of Springer Nature. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.",
year = "2019",
month = oct,
day = "1",
doi = "10.1007/s00723-019-01144-6",
language = "English",
volume = "50",
pages = "1233--1240",
journal = "Applied Magnetic Resonance",
issn = "0937-9347",
publisher = "Springer-Verlag GmbH and Co. KG",
number = "10",

}

RIS

TY - JOUR

T1 - Theoretical Treatment of Pulsed DNP Experiments

T2 - Effects of Spectral Exchange

AU - Nasibulov, Egor A.

AU - Ivanov, Konstantin L.

AU - Sagdeev, Renad Z.

N1 - Publisher Copyright: © 2019, Springer-Verlag GmbH Austria, part of Springer Nature. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.

PY - 2019/10/1

Y1 - 2019/10/1

N2 - In the present work, we provide a theoretical treatment of pulsed Overhauser-type dynamic nuclear polarization (DNP) in the presence of spectral exchange, namely, Heisenberg exchange. The expression for the DNP enhancement of a nuclear magnetic resonance (NMR) signal is generalized by redefining the “deviation factor”, expressing the deviation of the electron spin polarization from its equilibrium value, averaged over the period of the pulse sequence. We can demonstrate that spectral exchange significantly increases the deviation factor and, thus, the NMR enhancement. The present treatment allows one to determine the optimal pumping frequency at different exchange rates.

AB - In the present work, we provide a theoretical treatment of pulsed Overhauser-type dynamic nuclear polarization (DNP) in the presence of spectral exchange, namely, Heisenberg exchange. The expression for the DNP enhancement of a nuclear magnetic resonance (NMR) signal is generalized by redefining the “deviation factor”, expressing the deviation of the electron spin polarization from its equilibrium value, averaged over the period of the pulse sequence. We can demonstrate that spectral exchange significantly increases the deviation factor and, thus, the NMR enhancement. The present treatment allows one to determine the optimal pumping frequency at different exchange rates.

KW - DYNAMIC NUCLEAR-POLARIZATION

UR - http://www.scopus.com/inward/record.url?scp=85069688631&partnerID=8YFLogxK

U2 - 10.1007/s00723-019-01144-6

DO - 10.1007/s00723-019-01144-6

M3 - Article

AN - SCOPUS:85069688631

VL - 50

SP - 1233

EP - 1240

JO - Applied Magnetic Resonance

JF - Applied Magnetic Resonance

SN - 0937-9347

IS - 10

ER -

ID: 21044972