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The synthesis and crystal structure of the molecular complexes trans-[TiIVX4(OPPh3)2] (X = Cl, Br, I). / Krupenko, N. R.; Poltarak, P. A.; Artemkina, S. B. и др.

в: Inorganica Chimica Acta, Том 574, 122356, 01.01.2025.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Krupenko, NR, Poltarak, PA, Artemkina, SB, Grayfer, ED & Brylev, KA 2025, 'The synthesis and crystal structure of the molecular complexes trans-[TiIVX4(OPPh3)2] (X = Cl, Br, I)', Inorganica Chimica Acta, Том. 574, 122356. https://doi.org/10.1016/j.ica.2024.122356

APA

Krupenko, N. R., Poltarak, P. A., Artemkina, S. B., Grayfer, E. D., & Brylev, K. A. (2025). The synthesis and crystal structure of the molecular complexes trans-[TiIVX4(OPPh3)2] (X = Cl, Br, I). Inorganica Chimica Acta, 574, [122356]. https://doi.org/10.1016/j.ica.2024.122356

Vancouver

Krupenko NR, Poltarak PA, Artemkina SB, Grayfer ED, Brylev KA. The synthesis and crystal structure of the molecular complexes trans-[TiIVX4(OPPh3)2] (X = Cl, Br, I). Inorganica Chimica Acta. 2025 янв. 1;574:122356. doi: 10.1016/j.ica.2024.122356

Author

Krupenko, N. R. ; Poltarak, P. A. ; Artemkina, S. B. и др. / The synthesis and crystal structure of the molecular complexes trans-[TiIVX4(OPPh3)2] (X = Cl, Br, I). в: Inorganica Chimica Acta. 2025 ; Том 574.

BibTeX

@article{a6c5cecc379643c986b4263f463b7274,
title = "The synthesis and crystal structure of the molecular complexes trans-[TiIVX4(OPPh3)2] (X = Cl, Br, I)",
abstract = "The series of titanium (IV) complexes trans-[TiCl4(OPPh3)2] (1), trans-[TiBr4(OPPh3)2] (2) and trans-[TiI4(OPPh3)2] (3) were obtained as polycrystalline powders by heating the corresponding metal tetrahalides with triphenylphosphine oxide in evacuated sealed glass ampoules. The crystal structures were determined by single crystal X-ray diffraction. Compounds 1 and 2 were isolated as yellow and brown crystalline powders, with yields 70 and 75%, respectively. This paper discusses the synthesis of these coordination compounds 1–3 and their crystal structures, and analyzes the geometric parameters of the related molecular complexes of niobium and rhenium for use in the design of magnetically diluted systems.",
keywords = "Bromide, Chloride, Crystal structure, Iodide, Magnetically diluted systems, Molecular complex, Synthesis, Titanium, Triphenylphosphine oxide",
author = "Krupenko, {N. R.} and Poltarak, {P. A.} and Artemkina, {S. B.} and Grayfer, {E. D.} and Brylev, {K. A.}",
note = "Финансирующий спонсор Ministry of Education and Science of the Russian Federation 121031700321-3, 121031700313-8",
year = "2025",
month = jan,
day = "1",
doi = "10.1016/j.ica.2024.122356",
language = "English",
volume = "574",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - The synthesis and crystal structure of the molecular complexes trans-[TiIVX4(OPPh3)2] (X = Cl, Br, I)

AU - Krupenko, N. R.

AU - Poltarak, P. A.

AU - Artemkina, S. B.

AU - Grayfer, E. D.

AU - Brylev, K. A.

N1 - Финансирующий спонсор Ministry of Education and Science of the Russian Federation 121031700321-3, 121031700313-8

PY - 2025/1/1

Y1 - 2025/1/1

N2 - The series of titanium (IV) complexes trans-[TiCl4(OPPh3)2] (1), trans-[TiBr4(OPPh3)2] (2) and trans-[TiI4(OPPh3)2] (3) were obtained as polycrystalline powders by heating the corresponding metal tetrahalides with triphenylphosphine oxide in evacuated sealed glass ampoules. The crystal structures were determined by single crystal X-ray diffraction. Compounds 1 and 2 were isolated as yellow and brown crystalline powders, with yields 70 and 75%, respectively. This paper discusses the synthesis of these coordination compounds 1–3 and their crystal structures, and analyzes the geometric parameters of the related molecular complexes of niobium and rhenium for use in the design of magnetically diluted systems.

AB - The series of titanium (IV) complexes trans-[TiCl4(OPPh3)2] (1), trans-[TiBr4(OPPh3)2] (2) and trans-[TiI4(OPPh3)2] (3) were obtained as polycrystalline powders by heating the corresponding metal tetrahalides with triphenylphosphine oxide in evacuated sealed glass ampoules. The crystal structures were determined by single crystal X-ray diffraction. Compounds 1 and 2 were isolated as yellow and brown crystalline powders, with yields 70 and 75%, respectively. This paper discusses the synthesis of these coordination compounds 1–3 and their crystal structures, and analyzes the geometric parameters of the related molecular complexes of niobium and rhenium for use in the design of magnetically diluted systems.

KW - Bromide

KW - Chloride

KW - Crystal structure

KW - Iodide

KW - Magnetically diluted systems

KW - Molecular complex

KW - Synthesis

KW - Titanium

KW - Triphenylphosphine oxide

UR - https://www.mendeley.com/catalogue/4044ee72-33b6-3404-816a-dacccc7b4330/

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85203417376&origin=inward&txGid=2910c62ca1d47455a061519098e4bac4

U2 - 10.1016/j.ica.2024.122356

DO - 10.1016/j.ica.2024.122356

M3 - Article

VL - 574

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

M1 - 122356

ER -

ID: 62768790