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The insights into chlorine doping effect on performance of ceria supported nickel catalysts for selective CO methanation. / Konishcheva, M. V.; Potemkin, D. I.; Snytnikov, P. V. и др.

в: Applied Catalysis B: Environmental, Том 221, 02.2018, стр. 413-421.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

Harvard

Konishcheva, MV, Potemkin, DI, Snytnikov, PV, Stonkus, OA, Belyaev, VD & Sobyanin, VA 2018, 'The insights into chlorine doping effect on performance of ceria supported nickel catalysts for selective CO methanation', Applied Catalysis B: Environmental, Том. 221, стр. 413-421. https://doi.org/10.1016/j.apcatb.2017.09.038

APA

Konishcheva, M. V., Potemkin, D. I., Snytnikov, P. V., Stonkus, O. A., Belyaev, V. D., & Sobyanin, V. A. (2018). The insights into chlorine doping effect on performance of ceria supported nickel catalysts for selective CO methanation. Applied Catalysis B: Environmental, 221, 413-421. https://doi.org/10.1016/j.apcatb.2017.09.038

Vancouver

Konishcheva MV, Potemkin DI, Snytnikov PV, Stonkus OA, Belyaev VD, Sobyanin VA. The insights into chlorine doping effect on performance of ceria supported nickel catalysts for selective CO methanation. Applied Catalysis B: Environmental. 2018 февр.;221:413-421. doi: 10.1016/j.apcatb.2017.09.038

Author

Konishcheva, M. V. ; Potemkin, D. I. ; Snytnikov, P. V. и др. / The insights into chlorine doping effect on performance of ceria supported nickel catalysts for selective CO methanation. в: Applied Catalysis B: Environmental. 2018 ; Том 221. стр. 413-421.

BibTeX

@article{7982db9756d24de4b25782e90fe4142d,
title = "The insights into chlorine doping effect on performance of ceria supported nickel catalysts for selective CO methanation",
abstract = "Selective CO methanation (CO-SMET) in the reformate gas, containing (vol.%): 1.0 CO, 65H2, 10H2O, 20 CO2 with He as balance, was investigated over a number of nickel-ceria catalysts: treated with NH4Cl before (Ni/CeO2(Cl*)) and after (Ni(Cl*)/CeO2) Ni deposition, prepared by Cl-containing Ni precursor (Ni(Cl)/CeO2) and Cl-free one (Ni/CeO2). The effect of residual chlorine, originating from the catalyst preparation procedures, on the activity and CO selectivity of the samples was demonstrated. It was shown that all Cl-containing Ni/CeO2 catalysts provided efficient CO cleanup. They provided the removal of CO from reformate gas to the level below 10 ppm with a selectivity up to 90%. The catalyst characterization by BET, XRD, XPS, HAADF-STEM, EDX-mapping, FTIR in situ and CO chemisorption techniques revealed that the decrease in chlorine content in the order Ni(Cl)/CeO2 ≥ Ni(Cl*)/CeO2 > Ni/CeO2(Cl*) was accompanied by the increase of Ni dispersion that most likely provided high performance of Ni/CeO2(Cl*) in CO-SMET. The turnover frequencies of Ni surface atoms as well as activation energies in CO methanation were practically similar for all studied catalysts, indicating that Cl did not influence catalyst's activity and CO methanation proceeded by similar ways over Ni surface in both Cl-free and Cl-containing samples. The advanced performance of Cl-containing catalysts was associated with the inhibition of undesirable side reaction of CO2 methanation. The chlorine doping effect was attributed to the blockage of surface Ce3+-coupled oxygen vacancy sites by CeOCl species that inhibited ceria-assisted CO2 activation and hydrogenation. The CeO2 treatment with NH4Cl before Ni deposition allows to prepare highly active and selective CO-SMET catalyst with high nickel dispersion and Cl-modified ceria surface.",
keywords = "Cerium oxychloride, CO cleanup, Effect of chlorine doping, Hydrogen-rich gas, Nickel ceria catalysts, Reformate, Selective or preferential CO methanation, RATIOS, OXIDE, MECHANISM, METAL-CATALYSTS, H-2-RICH STREAM, HYDROGEN-RICH GAS, REMOVAL, KINETICS, CLEANUP, NI/CEO2 CATALYSTS",
author = "Konishcheva, {M. V.} and Potemkin, {D. I.} and Snytnikov, {P. V.} and Stonkus, {O. A.} and Belyaev, {V. D.} and Sobyanin, {V. A.}",
note = "Publisher Copyright: {\textcopyright} 2017 Elsevier B.V.",
year = "2018",
month = feb,
doi = "10.1016/j.apcatb.2017.09.038",
language = "English",
volume = "221",
pages = "413--421",
journal = "Applied Catalysis B: Environmental",
issn = "0926-3373",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - The insights into chlorine doping effect on performance of ceria supported nickel catalysts for selective CO methanation

AU - Konishcheva, M. V.

AU - Potemkin, D. I.

AU - Snytnikov, P. V.

AU - Stonkus, O. A.

AU - Belyaev, V. D.

AU - Sobyanin, V. A.

N1 - Publisher Copyright: © 2017 Elsevier B.V.

PY - 2018/2

Y1 - 2018/2

N2 - Selective CO methanation (CO-SMET) in the reformate gas, containing (vol.%): 1.0 CO, 65H2, 10H2O, 20 CO2 with He as balance, was investigated over a number of nickel-ceria catalysts: treated with NH4Cl before (Ni/CeO2(Cl*)) and after (Ni(Cl*)/CeO2) Ni deposition, prepared by Cl-containing Ni precursor (Ni(Cl)/CeO2) and Cl-free one (Ni/CeO2). The effect of residual chlorine, originating from the catalyst preparation procedures, on the activity and CO selectivity of the samples was demonstrated. It was shown that all Cl-containing Ni/CeO2 catalysts provided efficient CO cleanup. They provided the removal of CO from reformate gas to the level below 10 ppm with a selectivity up to 90%. The catalyst characterization by BET, XRD, XPS, HAADF-STEM, EDX-mapping, FTIR in situ and CO chemisorption techniques revealed that the decrease in chlorine content in the order Ni(Cl)/CeO2 ≥ Ni(Cl*)/CeO2 > Ni/CeO2(Cl*) was accompanied by the increase of Ni dispersion that most likely provided high performance of Ni/CeO2(Cl*) in CO-SMET. The turnover frequencies of Ni surface atoms as well as activation energies in CO methanation were practically similar for all studied catalysts, indicating that Cl did not influence catalyst's activity and CO methanation proceeded by similar ways over Ni surface in both Cl-free and Cl-containing samples. The advanced performance of Cl-containing catalysts was associated with the inhibition of undesirable side reaction of CO2 methanation. The chlorine doping effect was attributed to the blockage of surface Ce3+-coupled oxygen vacancy sites by CeOCl species that inhibited ceria-assisted CO2 activation and hydrogenation. The CeO2 treatment with NH4Cl before Ni deposition allows to prepare highly active and selective CO-SMET catalyst with high nickel dispersion and Cl-modified ceria surface.

AB - Selective CO methanation (CO-SMET) in the reformate gas, containing (vol.%): 1.0 CO, 65H2, 10H2O, 20 CO2 with He as balance, was investigated over a number of nickel-ceria catalysts: treated with NH4Cl before (Ni/CeO2(Cl*)) and after (Ni(Cl*)/CeO2) Ni deposition, prepared by Cl-containing Ni precursor (Ni(Cl)/CeO2) and Cl-free one (Ni/CeO2). The effect of residual chlorine, originating from the catalyst preparation procedures, on the activity and CO selectivity of the samples was demonstrated. It was shown that all Cl-containing Ni/CeO2 catalysts provided efficient CO cleanup. They provided the removal of CO from reformate gas to the level below 10 ppm with a selectivity up to 90%. The catalyst characterization by BET, XRD, XPS, HAADF-STEM, EDX-mapping, FTIR in situ and CO chemisorption techniques revealed that the decrease in chlorine content in the order Ni(Cl)/CeO2 ≥ Ni(Cl*)/CeO2 > Ni/CeO2(Cl*) was accompanied by the increase of Ni dispersion that most likely provided high performance of Ni/CeO2(Cl*) in CO-SMET. The turnover frequencies of Ni surface atoms as well as activation energies in CO methanation were practically similar for all studied catalysts, indicating that Cl did not influence catalyst's activity and CO methanation proceeded by similar ways over Ni surface in both Cl-free and Cl-containing samples. The advanced performance of Cl-containing catalysts was associated with the inhibition of undesirable side reaction of CO2 methanation. The chlorine doping effect was attributed to the blockage of surface Ce3+-coupled oxygen vacancy sites by CeOCl species that inhibited ceria-assisted CO2 activation and hydrogenation. The CeO2 treatment with NH4Cl before Ni deposition allows to prepare highly active and selective CO-SMET catalyst with high nickel dispersion and Cl-modified ceria surface.

KW - Cerium oxychloride

KW - CO cleanup

KW - Effect of chlorine doping

KW - Hydrogen-rich gas

KW - Nickel ceria catalysts

KW - Reformate

KW - Selective or preferential CO methanation

KW - RATIOS

KW - OXIDE

KW - MECHANISM

KW - METAL-CATALYSTS

KW - H-2-RICH STREAM

KW - HYDROGEN-RICH GAS

KW - REMOVAL

KW - KINETICS

KW - CLEANUP

KW - NI/CEO2 CATALYSTS

UR - http://www.scopus.com/inward/record.url?scp=85029677202&partnerID=8YFLogxK

U2 - 10.1016/j.apcatb.2017.09.038

DO - 10.1016/j.apcatb.2017.09.038

M3 - Article

AN - SCOPUS:85029677202

VL - 221

SP - 413

EP - 421

JO - Applied Catalysis B: Environmental

JF - Applied Catalysis B: Environmental

SN - 0926-3373

ER -

ID: 10415471