Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
The first non-symmetrically substituted conjugates of bispidine with monoterpenoids and amino acids. Synthesis and application for catalysis of addition of diethylzinc to aldehydes. / Ponomarev, K. Yu; Mozhaitsev, E. S.; Li-Zhulanov, N. S. и др.
в: Russian Chemical Bulletin, Том 73, № 8, 19.09.2024, стр. 2248-2260.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - The first non-symmetrically substituted conjugates of bispidine with monoterpenoids and amino acids. Synthesis and application for catalysis of addition of diethylzinc to aldehydes
AU - Ponomarev, K. Yu
AU - Mozhaitsev, E. S.
AU - Li-Zhulanov, N. S.
AU - Okhina, A. A.
AU - Nefedov, A. A.
AU - Rogachev, A. D.
AU - Suslov, E. V.
AU - Dalinger, A. I.
AU - Vatsadze, S. Z.
AU - Volcho, K. P.
AU - Salakhutdinov, N. F.
PY - 2024/9/19
Y1 - 2024/9/19
N2 - A series of bispidine conjugates bearing monoterpene moieties and either l-proline or l-phenylalanine residues was synthesized. The synthesized bispidines can catalyze asymmetric ethylation of benzaldehydes with diethylzinc. The highest enantioselectivity of the addition reaction (ee 24%) was achieved for bispidine with (–)-α-pinene and Boc-l-proline moieties.
AB - A series of bispidine conjugates bearing monoterpene moieties and either l-proline or l-phenylalanine residues was synthesized. The synthesized bispidines can catalyze asymmetric ethylation of benzaldehydes with diethylzinc. The highest enantioselectivity of the addition reaction (ee 24%) was achieved for bispidine with (–)-α-pinene and Boc-l-proline moieties.
KW - addition
KW - asymmetric organocatalysis
KW - benzaldehydes
KW - bispidine
KW - diethylzinc
KW - l-amino acids
KW - monoterpenoids
UR - https://www.mendeley.com/catalogue/ef89cd05-d2ca-3855-80ca-e7780e75a068/
UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85204462594&origin=inward&txGid=0035473206d8b5b21e924f10f34a66a0
U2 - 10.1007/s11172-024-4346-z
DO - 10.1007/s11172-024-4346-z
M3 - Article
VL - 73
SP - 2248
EP - 2260
JO - Russian Chemical Bulletin
JF - Russian Chemical Bulletin
SN - 1066-5285
IS - 8
ER -
ID: 60828528