Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
The first molybdenum oxo-iodide cluster – [mo4oi12]2–. / Mikhaylov, Maxim A.; Abramov, Pavel A.; Novozhilov, Igor N. и др.
в: Zeitschrift fur Anorganische und Allgemeine Chemie, Том 644, № 8-9, 17.05.2018, стр. 438-442.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - The first molybdenum oxo-iodide cluster – [mo4oi12]2–
AU - Mikhaylov, Maxim A.
AU - Abramov, Pavel A.
AU - Novozhilov, Igor N.
AU - Sokolov, Maxim N.
N1 - Publisher Copyright: © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
PY - 2018/5/17
Y1 - 2018/5/17
N2 - Reaction of Mo(CO)6 with Bu4NI and I2 in diglyme yielded a new butterfly MoIII cluster [Mo4OI12]2–. The structure of tetraphen-ylphosphonium salt was determined by X-ray single crystal diffraction. Ph4P+ and Bu4N+ salts were further characterized by elemental analy-sis, mass spectrometry, energy-dispersive X-ray (EDX), IR, Raman, and UV/Vis spectroscopy and CVA studies. The cluster anion has a butterfly array of molybdenum atoms and can be represented as [Mo4(μ4-O)(μ3-I)2(μ2-I4)I6]2–.
AB - Reaction of Mo(CO)6 with Bu4NI and I2 in diglyme yielded a new butterfly MoIII cluster [Mo4OI12]2–. The structure of tetraphen-ylphosphonium salt was determined by X-ray single crystal diffraction. Ph4P+ and Bu4N+ salts were further characterized by elemental analy-sis, mass spectrometry, energy-dispersive X-ray (EDX), IR, Raman, and UV/Vis spectroscopy and CVA studies. The cluster anion has a butterfly array of molybdenum atoms and can be represented as [Mo4(μ4-O)(μ3-I)2(μ2-I4)I6]2–.
KW - Butterfly-type core
KW - Electrochemistry
KW - Molybdenum
KW - Molybdenum iodide cluster
KW - Structure
KW - Synthesis
KW - ANTIBIOTICS
KW - COMPLEXES
KW - CELLULAR INTERNALIZATION
KW - SULFONATE
KW - CL
KW - BR
KW - LIGANDS
KW - REDOX
KW - TETRAHYDROFURAN
UR - http://www.scopus.com/inward/record.url?scp=85054688763&partnerID=8YFLogxK
U2 - 10.1002/zaac.201800053
DO - 10.1002/zaac.201800053
M3 - Article
AN - SCOPUS:85054688763
VL - 644
SP - 438
EP - 442
JO - Zeitschrift fur Anorganische und Allgemeine Chemie
JF - Zeitschrift fur Anorganische und Allgemeine Chemie
SN - 0044-2313
IS - 8-9
ER -
ID: 17083169